- Tytuł:
- Vibronic Transitions in Centrosymmetric [Eu$\text{}_{x}$La$\text{}_{1-x}$(AP)$\text{}_{6}$](ClO$\text{}_{4}$)$\text{}_{3}$ Crystals
- Autorzy:
-
Stręk, W.
Legendziewicz, J.
Huskowska, E.
Lukowiak, E.
Hanuza, J. - Powiązania:
- https://bibliotekanauki.pl/articles/1929804.pdf
- Data publikacji:
- 1993-11
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
78.20.Wc
78.55.Hx - Opis:
- The optical excitation and emission spectra of Eu(III) in [Eu$\text{}_{x}$La$\text{}_{1-x}$(AP)$\text{}_{6}$](ClO$\text{}_{4}$)$\text{}_{3}$ centrosymmetric complex were measured. The vibronic transitions were observed in excitation and emission spectra. Following the vibrational analysis' of the infrared and Raman spectra of [Pr$\text{}_{x}$La$\text{}_{1-x}$(AP)$\text{}_{6}$](ClO$\text{}_{4}$)$\text{}_{3}$, the assignment of [Eu$\text{}_{x}$La$\text{}_{1-x}$(AP)$\text{}_{6}$](ClO$\text{}_{4}$)$\text{}_{3}$ vibronics was given The concentration effect on excitation and emission spectra was investigated. It was found that the vibronic intensities were changed upon the concentration effect. The intensive charge transfer bands were observed in blue region. Their intensities decreased with increasing concentration.
- Źródło:
-
Acta Physica Polonica A; 1993, 84, 5; 979-984
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł