- Tytuł:
- Nuclear Quadrupole Coupling Tensor of Ch$\text{}_{2}$Cl$\text{}_{2}$: Comparison of Quadrupolar and Structural Angles in Methylene Halides
- Autorzy:
-
Kisiel, Z.
Kosarzewski, J.
Pszczółkowski, L. - Powiązania:
- https://bibliotekanauki.pl/articles/1967844.pdf
- Data publikacji:
- 1997-09
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
33.15.Dj
33.15.Pw
33.20.Bx - Opis:
- Nuclear quadrupole hyperfine structure in 2$\text{}_{1,2}$ ← 3$\text{}_{0,3}$ and 1$\text{}_{1,1}$ ← 2$\text{}_{0,2}$ rotational transitions of CH$\text{}_{2}^{35}$Cl$\text{}_{2}$ at 9.2 and 15.9 GHz, respectively, was measured with a newly constructed pulsed supersonic beam, cavity Fourier transform microwave spectrometer. All components of nuclear quadrupole splitting tensors of the chlorine nuclei in inertial and in principal quadrupole axes were determined. It is shown that in methylene halide molecules nuclear quadrupole information leads to a value for ∠(XCX) which is systematically larger than ∠(XCX) defined by the positions of the nuclei. Some novel features of the spectrometer are also described.
- Źródło:
-
Acta Physica Polonica A; 1997, 92, 3; 507-516
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł