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Wyświetlanie 1-6 z 6
Tytuł:
Assessment of Harmfulness of Phenolic Resins Hardened by CO2 in an Aspect of Emission of Substances from BTEX and PAH Groups
Autorzy:
Holtzer, M.
Żymankowska-Kumon, S.
Bobrowski, A.
Dańko, R.
Kmita, A.
Powiązania:
https://bibliotekanauki.pl/articles/380226.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
phenolic resin
BTEX
PAH
foundry
ochrona środowiska
żywica fenolowa
odlewnia
Opis:
Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. If in the initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylobenzene, xylenes), and also polycyclic aromatic hydrocarbons (PAHs) can be formed and released.
Źródło:
Archives of Foundry Engineering; 2013, 13, 1 spec.; 39-43
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Influence of Reclaim Addition on the Emission of PAHs and BTEX from Moulding Sands with Furfuryl Resin with the Average Amount of Furfuryl Alcohol
Autorzy:
Holtzer, M.
Żymankowska-Kumon, S.
Bobrowski, A.
Dańko, R.
Kmita, A.
Powiązania:
https://bibliotekanauki.pl/articles/383161.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
foundry
moulding sands
BTEX
PAHs
reclaim
ochrona środowiska
odlewnia
masa formierska
odzysk
Opis:
In this paper, the results of decomposition of the moulding sand with furan-formaldehyde resin (with middle content of furfuryl alcohol about 50 %) also on a quartz matrix and with additions of a reclaimed material, under industrial conditions, are presented. Investigations of the gases emission in the test foundry plant were performed according to the original method developed in the Faculty of Foundry Engineering, AGH UST. The dependence of the emitted PAHs and BTEX group substances and ignition losses on the reclaim fraction in a moulding sand are of a linear character of a very high correlation coefficient R2. On the bases of the derived equations, it is possible to determine the amount of the emitted hazardous substances from the moulding sand containing the known fraction of the reclaim.
Źródło:
Archives of Foundry Engineering; 2014, 14, 1 spec.; 37-42
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elution of mixed moulding sands with the GEOPOL binder and core sands with the phenolic resin
Autorzy:
Holtzer, M.
Żymankowska-Kumon, S.
Dańko, R.
Kmita, A.
Powiązania:
https://bibliotekanauki.pl/articles/380919.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
phenolic resin
moulding sand
core sand
BTEX
PAHs
ochrona środowiska
żywica fenolowa
masa formierska
masa rdzeniowa
Opis:
Out of moulding and core sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. Depending on the kind of the applied resin under an influence of a temperature such compounds as for example BTEX group and polycyclic aromatic hydrocarbons (PAHs) can be formed and released. During storing or economic utilization of used sand is possibility of eluting harmful substances into the environment. Therefore at assessing an influence of the used sand on the environment two above elements should be taken into consideration. Only such investigations provide the complete assessment of the given sand harmfulness.
Źródło:
Archives of Foundry Engineering; 2013, 13, 4; 53-56
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research of Emission of Commercial Binders Used in ALPHASET Technology - Estimated Quantitative Analysis
Autorzy:
Roczniak, A.
Holtzer, M.
Kmita, A.
Powiązania:
https://bibliotekanauki.pl/articles/383333.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
foundry engineering
ALPHASET technology
Py-GC/MS
BTEX emission
ochrona środowiska
inżynieria odlewnicza
technologia ALPHASET
emisja BTEX
Opis:
The results of investigations of three commercial binders applied in the Alphaset technology marked as: Sample E , Sample T and Sample S are presented in the hereby paper. These samples were subjected to the pyrolysis process at a temperature of 900°C (inert atmosphere, He 99.9999). The gas chromatograph coupled with the mass spectrometer and pyrolizer (Py-GC/MS) were used in the study. The identification of gases emitted during the thermal decomposition was performed on the basis of the mass spectral library. The obtained results indicate a certain diversification of emitted gases. Among the pyrolysis products the following harmful substances were identified: furfuryl alcohol, formaldehyde, phenol and also substances from the BTEX (benzene, toluene and ethylobezneze and xylenes) PAHs (Polycyclic Aromatic Hydrocarbons) and VOC groups (Volatile Organic Compounds). Therefore, from the environment protection point of view performing systematic investigations concerning the harmfulness of binders applied in the moulding and core sands technology, is essential.
Źródło:
Archives of Foundry Engineering; 2018, 18, 1; 109-114
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Reclamation Process on the Ecological Quality of Reclaim Sand
Autorzy:
Dereń, M.
Łucarz, M.
Roczniak, A.
Kmita, A.
Powiązania:
https://bibliotekanauki.pl/articles/380811.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermal reclamation
loss of ignition
molding sand
elution analysis
environment protection
regeneracja termiczna
strata prażenia
masa formierska
ochrona środowiska
Opis:
In this article, there were presented results of research on influence of reclamation process on the ecological quality of reclaim sand with furan resin used in nonferrous foundry. The quality of reclaimed sand is mainly define by two group of chemical substances from elution of reclaimed sand: Dissolves Organic Carbon (DOC) and Total Dissolves Solids (TDS). Reclaimed sand used in test was prepared in experimental thermal reclaimer and mechanical vibration reclaimer REGMAS installed in Faculty of Foundry Engineering at University of Science and Technology in Krakow. The reference point is molding sand shaking out and crumble in jaw crusher. Test of elution was made in acreditation laboratory in Center For Research and Environmental Control in Katowice up to the standard with Dissolves Organic Carbon (DOC) - PN-EN 1484:1999; Total Dissolves Solids (TDS) - PN-EN 15216:2010. The standard for elution test is PN-EN 12457- 4:2006. Except that we were made loss of ignition test, to check how many resin was rest on sand grains.
Źródło:
Archives of Foundry Engineering; 2017, 17, 4; 43-46
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Piroliza utwardzonej żywicy fenolowo-formaldehydowej typu rezolowego - identyfikacja produktów metodą GC/MS
Pyrolysis of the Cured Phenol-Formaldehyde Resole Resin - Identification of the Products by GC/MS
Autorzy:
Kmita, A.
Roczniak, A.
Holtzer, M.
Powiązania:
https://bibliotekanauki.pl/articles/382923.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ochrona środowiska
lotne związki organiczne
niebezpieczne zanieczyszczenia powietrza
technologia Alphaset
technika Py-GC/MS
technologia odlewnicza
environment protection
volatile organic compounds
hazardous air pollutants
alpha-set technology
Py-GC/MS
foundry technology
Opis:
Celem badań była identyfikacja głównych produktów pirolizy utwardzonego spoiwa stosowanego w technologii ALPHASET w zależności od temperatury rozkładu. Rozkład termiczny próbek prowadzono przy użyciu pirolizera w temperaturze: 700, 900 i 1100 °C w atmosferze helu o czystości 99,9999. Identyfikację produktów pirolizy prowadzono z wykorzystaniem techniki GC/MS. Okazało się, że temperatura 900 °C jest tą, w której powstaje najwięcej produktów pirolizy. W temperaturze 700 i 900 °C znaczny udział wśród produktów pirolizy ma dwutlenek węgla, który powstaje w wyniku rozkładu węglanu propylenu, będącego prawdopodobnie składnikiem mieszaniny estrów.
The aim of the investigations was the identification of the main products of the pyrolysis of the hardened binder - applied in the ALPHASET technology - in dependence on the decomposition temperature. The thermal decomposition of samples was performed by means of the pyrolyzer at temperatures: 700, 900 and 1100°C in the atmosphere of helium (He) of the purity: 99.9999. This identification was performed by means of the GC/MS technique. It occurred that the temperature of 900°C is the one at which the highest amount of the pyrolysis products is formed. At temperatures of 700 and 900°C among the pyrolysis products there is a significant fraction of carbon dioxide, which is formed as the result of the decomposition of propylene carbonate, which is probably the component of the esters mixture.
Źródło:
Archives of Foundry Engineering; 2015, 15, 4 spec.; 67-72
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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