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Wyszukujesz frazę "biomarkery" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Dystrybucja biomarkerów i dojrzałość termiczna materii organicznej w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka (Lubelskie Zagłębie Węglowe)
Biomarkers distribution and thermal maturity of organic matter w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka "Bogdanka" mine (Lublin Coal Basin)
Autorzy:
Gola, M. R.
Karger, M.
Gazda, L.
Powiązania:
https://bibliotekanauki.pl/articles/2074840.pdf
Data publikacji:
2011
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Lubelskie Zagłębie Węglowe
tonstein
biomarkery
dojrzałość termiczna materii organicznej
Lublin Coal Basin
biomarkers
thermal maturity of organic matter
Opis:
The paper presents results of geochemical analyses of organic matter (OM) in a tonstein bed and surrounding bituminous coal from the Upper Carboniferous (Westphalian B) coal seam no. 385/2 from the Bogdanka mine, Lublin Coal Basin. In all studied samples, including those of tonstein and bituminous coal, OM was found to be very similar in composition. Distribution of hydrocarbons in investigated rocks is characterized by strong predominance with odd-number carbon-atom of the long-chain n-alkanes in comparison to the even-number and high concentration of C29 steranes, what implies relatively high input of higher-plant OM in these samples. Minor concentration of C28 steranes and perylene points at presence of fungi. In all extracts, the tri- and tetracyclic diterpanes co-occur with their aromatized derivatives, what suggests presence of the tap resin species - precursors of the conifer families in the plant community. The abundance of sesquiterpanes, pentacyclic triterpanes and benzohopanes indicates a significant bacterial input, most possibly connected with bacterial activity after deposition of terrestrial OM. The original material of tonstein was pyroclastic in orgin, and deposited directly on plants living at the surface of a mire. That material hadn’t had any direct influence on chemicalOMtransformation. The biomarker data, both for coals and tonstein, reveals that sedimentary organic matter was heated up to a temperature corresponding to the level of immature/start of oil window. On the other hand, the increase in thermal maturity value, based on distribution of the aromatic hydrocarbons in organic matter in tonstein (theoretical vitrinite values - Rc, Rcs) are probably due to the presence of incompletely burned organic remains (charcoals), transported to the sedimentary basin along with volcanic ashes.
Źródło:
Przegląd Geologiczny; 2011, 59, 12; 777-784
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Organic geochemistry of Upper Carboniferous bituminous coals and clastic sediments from the Lublin Coal Basin (Poland)
Autorzy:
Karger, M.
Gazda, L.
Grafka, O.
Powiązania:
https://bibliotekanauki.pl/articles/139223.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Lublin Coal Basin
bituminous coal
gas chromatography-mass spectrometry
biomarkers
terrigenous organic matter
Lubelskie Zagłębie Węglowe
chromatografia gazowa ze spektrometrią mas
biomarkery
materia organiczna
Opis:
Bituminous coals and clastic rocks from the Lublin Formation (Pennsylvanian, Westphalian B) were subjected to detailed biomarker and Rock-Eval analyses. The investigation of aliphatic and aromatic fractions and Rock-Eval Tmax suggests that the Carboniferous deposits attained relatively low levels of thermal maturity, at the end of the microbial processes/initial phase of the oil window. Somewhat higher values of maturity in the clastic sediments were caused by postdiagenetic biodegradation of organic matter. The dominance of the odd carbon-numbered n-alkanes in the range n-C25 to n-C31 , high concentrations of moretanes and a predominance of C28 and C29 steranes are indicative of a terrigenous origin of the organic matter in the study material. This is supported by the presence of eudesmane, bisabolane, dihydro-ar-curcumene and cadalene, found mainly in the coal samples. In addition, tri- and tetracyclic diterpanes, e. g. 16β(H)-kaurane, 16β(H)-phyllocladane, 16α(H)-kaurane and norisopimarane, were identified, suggesting an admixture of conifer ancestors among the deposited higher plants. Parameters Pr/n-C17and Rdit in the coal samples show deposition of organic matter from peat swamp environments, with the water levels varying from high (water-logged swamp) to very low (ephemeral swamp). Clastic deposits were accumulated in a flood plain environment with local small ponds/lakes. In pond/lake sediments, apart from the dominant terrigenous organic matter, research also revealed a certain quantity of algal matter, indicated, i.a., by the presence of tricyclic triterpanes C28 and C29 and elevated concentrations of steranes. The Paq parameter can prove to be a useful tool in the identification of organic matter, but the processes of organic matter biodegradation observed in clastic rocks most likely influence the value of the parameter, at the same time lowering the interpretation potential of these compounds. The value of Pr/Ph varies from 0.93 to 5.24 and from 3.49 to 22.57 in the clastic sediments and coals respectively. The microbial degradation of organic matter in both type of rocks and during early stages of diagenesis is confirmed by a high concentration of hopanes, the presence of drimane homologues, bicyclic alkanes and benzohopanes. Moreover, bacteria could also have been connected with the primary input of organic matter, which is shown by the presence of e.g. C30 neohop-13(18)-ene.
Źródło:
Acta Geologica Polonica; 2013, 63, 3; 425-442
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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