- Tytuł:
- Anchoring tri(8-quinolinolato)iron onto SBA-15 for partial oxidation of benzyl alcohol using water as the solvent
- Autorzy:
-
Yang, X.
Liu, J.
Kan, Q
Guan, J. - Powiązania:
- https://bibliotekanauki.pl/articles/779135.pdf
- Data publikacji:
- 2014
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
SBA-15
8-quinolinol
iron
benzyl alcohol
benzaldehyde - Opis:
- Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.
- Źródło:
-
Polish Journal of Chemical Technology; 2014, 16, 3; 12-17
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł