- Tytuł:
- Tryptophan-Based Organoclay for Aqueous Naphthol Blue Black Removal – Preparation, Characterization, and Batch Adsorption Studies
- Autorzy:
-
Julinawati, Julinawati
Febriani, Febriani
Mustafa, Irfan
Fathurrahmi, Fathurrahmi
Rahmi, Rahmi
Sheilatina, Sheilatina
Ahmad, Khairunnas
Puspita, Kana
Iqhrammullah, Muhammad - Powiązania:
- https://bibliotekanauki.pl/articles/27323827.pdf
- Data publikacji:
- 2023
- Wydawca:
- Polskie Towarzystwo Inżynierii Ekologicznej
- Tematy:
-
amino acids
bentonite
diazo dye
freundlich
Sips isotherm model
montmorillonite
textile wastewater - Opis:
- To prevent the serious threat of textile wastewater, researchers have developed adsorption-based wastewater treatment using cheap, yet effective, adsorbent materials. Of which is natural bentonite, that has the advantages for adsorption due to its porous structure and functional groups but still suffers from its low affinity against anionic and hydrophilic azo dyes. Herein, we aimed of improving the affinity by amino acid tryptophan embedment into the locally isolated natural bentonite collected from Aceh Province, Indonesia. The prepared bentonite samples were characterized using Fourier transform infrared, X-ray diffraction, and scanning electron microscopy. Adsorptive removal was performed on naphthol blue black (NBB) in a batch system with variations of contact time, pH, and adsorbent dosage. The isotherm studies were carried out at optimum conditions (contact time=15 minutes; pH 1; adsorbent dosage=0.2 g) with several models including Langmuir, Freundlich, Sips, and Redlich-Peterson isotherm models. The characterization results revealed that the modification altered its functional group, crystallinity, and micro-surface morphology that add more benefits for adsorption. At optimum conditions, 99.2% NBB has been successfully removed from the aqueous solution. The isotherm studies suggested that the NBB adsorption onto the tryptophane-modified natural bentonite was dependent on Sips isotherm model (R2=0.999; root-mean-square-errors=1.11×10-4 mg/g).
- Źródło:
-
Journal of Ecological Engineering; 2023, 24, 7; 274--284
2299-8993 - Pojawia się w:
- Journal of Ecological Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł