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Wyświetlanie 1-4 z 4
Tytuł:
Self-Plasticization of PVC via click reaction of a monooctyl phthalate derivative
Autorzy:
Jia, P.
Wang, R.
Hu, L.
Zhang, M.
Zhou, Y.
Powiązania:
https://bibliotekanauki.pl/articles/779324.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
poly(vinyl chloride)
plasticization
migration
TGA
Opis:
Modified PVC (M-PVC) material with suppressed migration and low glass transition temperature was prepared via click reaction of a monooctyl phthalate derivative. Chemical structure and composition of M-PVC were characterized by FT-IR, 1H NMR and element analysis. Thermal stability, glass transition temperature and migration stability of M-PVC were studied with TGA, DSC and migration tests, respectively. The study showed that M-PVC exhibited poor thermal stability, and low glass transition temperature of 66.0°C. No migration was found in distilled water, 10% (v/v) ethanol, 30% (w/v)acetic acid and petroleum ether. The PVC material is expected to preparing PVC products in the areas with high migration resistance requirement.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 3; 16-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The plasticizing effect of properties of manganous chloride and glycerin on poly(vinyl alcohol)
Autorzy:
Jia, P.
Zhang, M.
Bo, C.
Hu, L.
Zhou, Y.
Powiązania:
https://bibliotekanauki.pl/articles/778667.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
poly(vinyl alcohol)
glycerin
manganous chloride
blend
film
Opis:
Poly(vinyl alcohol) films were prepared with manganous chloride (MnCl2 · 4H2O) and glycerin as complex plasticizer. The micro morphology of pure PVA film and complex plasticizer plasticized PVA films was observed by scanning electron microscope (SEM). The interaction between complex plasticizer and PVA molecules was investigated by Fourier transform infrared spectroscopy (FT-IR). The influence of complex plasticizer on crystalline, thermal and mechanical properties of PVA films was studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TG), and tensile testing, respectively. The results showed that the complex plasticizer of MnCl2 · 4H2O/glycerin could interacted with PVA molecular and then effectively destroy the crystals of PVA. PVA films plasticized with complex plasticizer of MnCl2 · 4H2O/glycerin became soft and ductile, with lower tensile strength and higher elongation at break compared with PVA films. This is an important cause of plasticization of the complex plasticizer of MnCl2 · 4H2O/glycerin on PVA films.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 29-33
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A novel biobased polyester plasticizer prepared from palm oil and its plasticizing effect on poly (vinyl chloride)
Autorzy:
Jia, P.
Zhang, M.
Hu, L.
Zhou, Y.
Powiązania:
https://bibliotekanauki.pl/articles/779512.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
palm oil
polyester
plasticizer
polyvinyl chloride
blend
Opis:
In this study, palm oil was the first time to convert into a novel polyester plasticizer for polyvinyl chloride (PVC). In the first stage, palm oil was converted into palm oil monoglyceride (POM) by alcoholysis with glycerol. Next, a novel palm oil monoglycerides based polyester plasticizer (POMP) was synthesized from POM and maleic anhydride through esterification and condensation reaction. The structure of POMP was characterized with FTIR, 1H NMR and GPC. Then PVC blends were prepared using POMP as a plasticizer, melting behavior, thermal property, compatibility, mechanical properties and mechanism of plasticization of PVC blends were systematically studied. Melting behavior indicated that POMP could decrease the torque and the melt viscosity of PVC blends that was conducive to process. With the content of POMP increasing from 5 g to 15 g in PVC blends, the plasticized PVC blends demonstrated better compatibility, the degradation temperature (Td) increased from 252.6°C to 257.0°C, the glass transition temperature (Tg) decreased from 55°C to 49.5°C. Plasticization was put into effect by interaction of the electron cloud between the PVC chain and POMP molecule. This study may lead to the development of new type of PVC plasticizer based on vegetable oil.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 1; 9-14
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer
Autorzy:
Song, F.
Xia, H.
Jia, P.
Zhang, M.
Hu, L.
Zhou, Y.
Powiązania:
https://bibliotekanauki.pl/articles/777906.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Castor Oil
Poly(vinyl chloride)
Epoxy Plasticizer
Thermal Property
Migration Resistance
Opis:
In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FTIR and  1H-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with DOP. The results showed that EACO improved polyvinyl-chloride (PVC) plasticization performance and reduced Tg from 81.06°C to 1.40°C. Plasticized PVC materials with EACO showed similar mechanical properties and better thermal stability than DOP. EACO had better volatility stabilities, migration and solvent extraction in PVC than DOP. EACO can be used to replace DOP to prepare soft films.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 4; 13-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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