- Tytuł:
- Chiral pyrrolidinium salts derived from menthol as precursor – synthesis and properties
- Autorzy:
-
Janus, E.
Gano, M. - Powiązania:
- https://bibliotekanauki.pl/articles/778746.pdf
- Data publikacji:
- 2017
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
pyrrolidinium chiral salts
chiral ionic liquids
menthol
Diels-Alder reaction - Opis:
- Six new chiral pyrolidinium salts with chiral substituent at quaternary nitrogen atom were synthesized with high overall yields from (-)-menthol as cheap chiral precursor and were identified by NMR and HRMS spectroscopy. It was shown that anion type had the effect on chemical shift of protons adjacent to quaternary nitrogen atom and physical properties of these salts. Salts with NTf2 or NPf2 were in a liquid state at room temperature and characterized with the highest thermal stability among others. Furthermore, chiral ionic liquid with NTf2 anion was used as solvent in Diels-Alder reaction and gave higher yield and stereoselectivity than in ionic liquids with achiral cations. Synthesized chiral salts have the potential as chiral solvents in synthesis and auxiliaries in analytical methods to improve chiral recognition.
- Źródło:
-
Polish Journal of Chemical Technology; 2017, 19, 3; 92-98
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł