Temat: inhibition - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Experimental and computational study of levofloxacin as corrosion inhibitor for carbon steel in acidic media
Autorzy:: Ikpi, M. E.
Abeng, F. E.
Okonkwo, B. O.
Powiązania:: https://bibliotekanauki.pl/articles/1118353.pdf
Data publikacji:: 2017
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: Corrosion Inhibition
Polarization
levofloxacin and Adsorption
Opis:: The corrosion inhibition behaviour of levofloxacin was investigated on carbon steel by means of a 2 M HCl solution, using potentiodynamic polarization measurement and Quantum chemical studies. The inhibitive effect of the studied compound was found to increase with increasing concentration and to increase with increasing temperature. The study reveals that levofloxacin is a mixed-type corrosion inhibitor. The adsorption of levofloxacin on carbon steel surface obeys the Langmuir adsorption isotherm and involves physical adsorption mechanisms. Quantum chemical studies corroborate experimental results.
Źródło:: World News of Natural Sciences; 2017, 9; 79-90
2543-5426
Pojawia się w:: World News of Natural Sciences
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: Electrochemical and Quantum Chemical Investigation on Adsorption of Nifedipine as Corrosion Inhibitor at API 5L X-52 Steel / HCl Acid Interface
Autorzy:: Ikpi, M. E.
Abeng, F. E.
Powiązania:: https://bibliotekanauki.pl/articles/356191.pdf
Data publikacji:: 2020
Wydawca:: Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:: nifedipine
corrosion inhibition
electrochemical impedance
carbon steel
quantum chemical study
Opis:: Nifedipine, a pyridine derivative was investigated as corrosion inhibitor for API 5L X-52 steel in 2 M HCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy and quantum chemical calculations. Statistical tools were used to compare results of the experimental methods. The results showed that nifedipine is capable of inhibiting the corrosion of API 5L X-52 steel in 2 M HCl solution. Potentiodynamic polarization results reveal that nifedipine functions as a mixed-type inhibitor and presents an inhibition efficiency of about 78% at 500 ppm. Impedance data reveal an increasing charge transfer resistance with increasing inhibitor concentration and also shows comparable inhibition efficiency of about 89-94% at 500 ppm. Thermodynamic parameters imply that nifedipine is adsorbed on the steel surface by a physiochemical process and obeys Langmuir adsorption isotherm. The calculated molecular properties namely the highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy, chemical hardness, energy gap, dipole moment, electronegativity and global nucleophilicity index all show a positive relationship to the observed corrosion inhibition efficiency.
Źródło:: Archives of Metallurgy and Materials; 2020, 65, 1; 125-131
1733-3490
Pojawia się w:: Archives of Metallurgy and Materials
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 3.

Tytuł:: Adsorption and Thermodynamic Studies for Corrosion Inhibition of API 5L X-52 Steel in 2 M HCl Solution by Moxifloxacin
Autorzy:: Ikpi, M. E.
Abeng, F. E.
Obono, O. E.
Powiązania:: https://bibliotekanauki.pl/articles/1118241.pdf
Data publikacji:: 2017
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: API 5L X-52 steel
corrosion inhibition
moxifloxacin and adsorption
thermodynamic
Opis:: The inhibition of API 5L X-52 steel corrosion in an acidic medium by moxifloxacin at 303 K, 313 K and 323 K was monitored by potentiodynamic polarization measurement. The concentration of acid medium was maintained throughout the experiment. The inhibition efficiency was found to increased with increase in concentration of moxifloxacin and temperature. Activation energy, adsorption and thermodynamic parameters were evaluated from the study temperature. Herein, moxifloxacin brought about a decrease in activation energy Ea that reflects chemisorption. The adsorption of the moxifloxacin on the steel surface was found to obeyed Langmuir adsorption isotherm ΔGads values, indicating strong and spontaneous adsorption of the moxifloxacin on the surface of API 5L X-52 steel.
Źródło:: World News of Natural Sciences; 2017, 9; 52-61
2543-5426
Pojawia się w:: World News of Natural Sciences
Dostawca treści:: Biblioteka Nauki

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