- Tytuł:
- Behavior and mechanism of collophane and dolomite separation using alkyl hydroxamic acid as a flotation collector
- Autorzy:
-
Yu, J.
Ge, Y.
Hou, J. - Powiązania:
- https://bibliotekanauki.pl/articles/110455.pdf
- Data publikacji:
- 2016
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
hydroxamic acid
collophane
dolomite
separation mechanism - Opis:
- Flotation response of collophane and dolomite using alkyl hydroxamic acid (AH) (chelating collector) was investigated in the paper. The experiments were performed using pure and artificially mixed minerals as well as a real phosphate ore. Their separation mechanisms were studied by means of zeta potential measurements, infrared analysis, adsorption measurements, thermodynamics, and quantum chemical calculations. The results indicated that AH exhibited an excellent performance in the flotation separation of collophane from dolomite in neutral medium. The P2O5 grade of the concentrate increased from 19.84% to 30.51% without any other reagents when the pH value was about 7. The zeta potential and adsorption studies showed that the adsorption of AH at the cellophane/aqueous interface was greater than that at dolomite surface, which was the essential reason that separation of collophane from dolomite. The results of Fourier Transform Infrared (FTIR) spectrum and thermodynamics calculation indicated that the adsorption of AH at collophane was attributed to the chemical bonding. Moreover, AH molecule formed O-O five-membered ring with calcium ion on the collophane surface.
- Źródło:
-
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 155-169
1643-1049
2084-4735 - Pojawia się w:
- Physicochemical Problems of Mineral Processing
- Dostawca treści:
- Biblioteka Nauki
Artykuł