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Wyszukujesz frazę "Halas, J." wg kryterium: Autor


Wyświetlanie 1-5 z 5
Tytuł:
Analiza izotopowa litu w wodach i osadach
Lithium isotope analysis in waters and sediments
Autorzy:
Hałas, S.
Dąbek, J.
Pacek, A.
Powiązania:
https://bibliotekanauki.pl/articles/2063006.pdf
Data publikacji:
2011
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
geochemia litu
frakcjonowanie
izotopy litu
żywice kationowymienne
spektrometria mas
jonizacja termiczna
lithium geochemistry
fractionation
lithium isotopes
cation-exchange resins
mass spectrometry
thermal ionization
Opis:
Celem badań opisanych w niniejszym artykule było opracowanie metody wydzielania litu z roztworów wodnych na kolumnie kationowymiennej oraz pomiar stosunku izotopowego litu 7Li/6Li w uzyskanych próbkach metodą TIMS (Thermal Ionisation Mass Spectrometry). Opracowana metoda pomiaru stosunku izotopowego litu nie wymaga skomplikowanej obróbki chemicznej badanych próbek, jak również dużych ilości badanej substancji, co sprawia, że należy do najprostszych spośród wszystkich metod analizy izotopowej litu. Metodą tą zostały przebadane próbki wody morskiej pochodzącej z Morza Śródziemnego, próbki wody mineralnej pochodzącej z otworu Zuber I w Krynicy-Zdroju oraz próbka osadu z tej wody. Wartości δ7Li w badanych próbkach uzyskano z powtarzalnością rzędu jednego promila. Wynik uzyskany dla wody morskiej (32,2 ±1,9‰) mieści się w ramach niepewności pomiarowych w zakresie aktualnych danych literaturowych. Wartości δ7Li w wodzie mineralnej Zuber I (–17,3‰) oraz w osadzie wytworzonym w tej wodzie (–1,5‰), według wiedzy autorów, są publikowane i dyskutowane po raz pierwszy.
The purpose of the present study was to develop a method of lithium extraction from water solutions on a cation exchange column and to determine its isotope ratio by thermal ionization mass spectrometry. This method of lithium isotope determination requires neither complicated chemical preparation of the investigated samples, nor large quantities of material, thus being one of the simplest methods. The following samples have been investigated using this method: seawater from the Mediterranean Sea, mineral water from the Zuber I borehole in Krynica-Zdrój, and a sediment sample from this water. The values of δ7Li for all the samples were achieved with reproducibility of the order of 1‰. The result obtained for seawater (32.2 ±1.9‰) falls into the range known from literature. The delta values for the Zuber I mineral water (–17.3‰) and the sediment precipitated from this water (–1.5‰) are, according to the best knowledge of the authors, published and discussed for the first time.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2011, 444; 65--72
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sulphur, oxygen and strontium isotope compositions of Middle Miocene (Badenian) calcium sulphates from the Carpathian Foredeep, Poland: palaeoenvironmental implications
Autorzy:
Kasprzyk, A.
Pueyo, J.J.
Hałas, S.
Fuenlabrada, J.M.
Powiązania:
https://bibliotekanauki.pl/articles/2059523.pdf
Data publikacji:
2007
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Carpathian Foredeep
Badenian
sulphur
oxygen and strontium isotopes
sulphate deposits
Opis:
Sulphur, oxygen and strontium isotope compositions have been measured in sulphate (gypsum and anhydrite) sam ples from the Badenian evaporite complex in the Carpathian Foredeep Basin (Poland) to determine the origin of brines from which these sulphates were formed. Studied samples display the d values from +22.68 to +24.91‰ CDT for sulphur (ten samples) and from +12.26 to +13.63‰ SMOW for oxygen (ten samples), and 87Sr/86Sr ratios from 0.708915 to 0.716329 (six samples). Most samples show isotopic values (both d34S and 87Sr/86Sr) higher than contem poraneous (Badenian) sea water, and thus suggest that these sulphates were formed (i) from brines with a significant component of non-marine waters, (ii) in a restricted system, where an important role was played by meteoric water inputs as well as by bacterial sulphate reduction. The results of this study show clear differences in the isotopic signatures between sedimen tary (gypsum) and diagenetic (anhydrite) lithofacies. While sedimentary gypsum displays sulphur, oxygen and strontium isotope ratios close to contemporaneous (Badenian) sea water, diagenetic anhydrite values are largely elevated. The higher isotopic values (d34S, d18O and 87Sr/86Sr) for anhydrite when compared to gypsum are interpreted as reflecting different hydrological provenances of sulphate in the Badenian basin. Gypsum was formed from brines marine in origin that were subject to an important in flow of continental waters and a local bacterial sulphate reduction in arestricted, and there fore sulphate-limited basin, which is consistent with earlier interpre tations based on sedimentological and geochemical studies. Our study shows that brines from which anhydrite was formed had a highly-radiogenic non-marine (riverine, ground water) strontium component, which is a new contribution to the knowledge on the Badenian sulphate formation. The results reflect a lateral compositional evolution of parent waters during sulphate deposition and diagenesis in the Carpathian Foredeep Basin.
Źródło:
Geological Quarterly; 2007, 51, 3; 285-294
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Diurnal variations and vertical distribution of δ13C, and concentration of atmospheric and soil CO2 in a meadow site, SE Poland
Autorzy:
Szaran, J.
Dudziak, A.
Trembaczowski, A.
Niezgoda, H.
Hałas, S.
Powiązania:
https://bibliotekanauki.pl/articles/2058901.pdf
Data publikacji:
2005
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
SE Poland
atmospheric CO2
carbon dioxide concentration
diurnal observations
delta 13C
soil CO2
Opis:
We provide the results of 24-hour observations made in a meadow site located in a small river valley in Central Europe. Samples of atmospheric air were taken from three horizons: near the soil (0.05 m), in the grass (0.5 m) and above the meadow (2 m) at two-hour intervals. At the same time, samples of soil air were collected from two horizons: -0.1 and -0.5 m. We have found a variation of δ13C above the ground from -6‰ during the day to -20‰ late at night accompanied by variations in CO2 concentration from 270 ppm during the day, to various levels late at night at different heights above the ground. The maximum concentration was 1430 ppm at the ground level. The correlation coefficient between δ 13C and reciprocal of concentration was the highest (R2 = 0.984) for the samples collected 2 m above the ground, the regression line clearly indicating CO2 mixing from the two sources: atmospheric and biogenic reservoirs. The intercept of the mixing line yields δC = -23.0‰ for the biogenic CO2. In contrast, the diurnal variations in the soil were relatively small, δ13C varied from -21.6 to -23.4‰, while CO2 concentration from 4300 to 8200 and from 24 700 to 34 500 ppm at depths of 0.1 m and 0.5 m respectively, which is less than 2-fold. Small diurnal variations are characteristic of dry soils, where δ13C is weakly correlated with CO2 concentration (in our case R2 was 0.30 and 0.54, respectively).
Źródło:
Geological Quarterly; 2005, 49, 2; 135--144
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anomalia hydrogeochemiczna w Tatrach : źródło z wodami siarczanowymi
Hydrogeochemical anomaly in the Tatra Mountains : a spring with sulphate water
Autorzy:
Wolanin, A..
Chmiel, S.
Żelazny, M.
Jelonkiewicz, Ł.
Janusz, J.
Hałas, S.
Trembaczowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2075753.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
hydrogeochemiczne anomalia
źródło
chemizm
izotopy
metale śladowe
hydrogeochemical anomaly
spring
chemistry
isotopes
trace metals
Opis:
The paper contains the results of analysis of chemical, isotopic and trace metal composition of anomalous spring water in the Tatra Mts. Obtained data were the basis for an attempt to determine the origin of this hydrogeochemical anomaly. The spring is located in the Tomanowa Valley in the Western Tatra Mts. The spring water is characterized by the mineralization (TDS) above 500 mg/dm3. As regards the chemical composition of the water, Ca2+ ions show the highest concentration among cations, while HCO- among anions. The spring water has been assigned to the: SO —HCO—Ca-Mg hydrochemical type. Among trace metals, Sr, Ba, B, Li and Al. reveal The highest concentrations. The oxygen and hydrogen isotopic composition(δ18O and δ2H) indicates that this is infiltration water. Delta values of oxygen and sulphur isotopes (δ18OS and δ34S) of the sulphate ion indicate that SO4 of this spring water is likely derived from leaching of gypsum or anhydrite evaporites.
Źródło:
Przegląd Geologiczny; 2017, 65, 11/1; 1025--1028
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin and Neoholocene evolution of spring-fed fens in Wardzyń, Łódź Upland, central Poland
Autorzy:
Dobrowolski, R.
Ziułkiewicz, M.
Okupny, D.
Forysiak, J.
Bałaga, K.
Alexandrowicz, W. P.
Buczek, A.
Hałas, S.
Powiązania:
https://bibliotekanauki.pl/articles/2060368.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
spring-fed fen
calcareous tufa
peatland
Neoholocene
Łódź Upland
Central Poland
Opis:
Spring-fed fens in Wardzyń represent the rare group of alkaline mires supplied by artesian groundwater. Using multidisciplinary methods (including sedimentological, hydrometric and hydrochemical, pollen, macrofossil, malacological, geochemical, radiocarbon dating, and stable oxygen and carbon isotope analyses) we have been able to (1) reconstruct the main phases of spring-fed fen development, and to (2) determine the cause of Neoholocene groundwater ascension responsible for the mire inception. These phases are characterized by cyclic organic (peat) and carbonate (tufa) sedimentation associated with the Holocene fluctuations in humidity and temperature. The beginning of the activation of hydrological systems (involving the flow of confined groundwater of the Cretaceous aquifer) at Wardzyń occurred in the Subboreal period of the Holocene, after a long episode of decreased humidity initiated ca. 4.2 ka cal BP.
Źródło:
Geological Quarterly; 2017, 61, 2; 413--434
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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