- Tytuł:
- The influence of the catalyst on the kinetics of ethyl metacrylate synthesis
- Autorzy:
-
Grzesik, M.
Witczak, T. - Powiązania:
- https://bibliotekanauki.pl/articles/778457.pdf
- Data publikacji:
- 2007
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
estryfikacja
heteropolikwasy
kinetyka
esterification
heteropoliacids
kinetics - Opis:
- The synthesis of ethyl metacrylate in the liquid phase was studied. Tungstophosphoric and molybdophosphoric acids, which belong to heteropolyacids group, were used as a catalyst. The chemical compounds from this group are often utilized in the catalysis with regard to their activity and selectivity. The rate equations, reaction rate constants and equilibrium constants have been determined. The reaction order and the kinetic parameters of the kinetic relations were determined by the integral method. All rate equations are formulated with activities taking the non ideal effects of the compounds into consideration. It was found that the kinetics of the esterification of the presented reactions was non-elementary.
- Źródło:
-
Polish Journal of Chemical Technology; 2007, 9, 1; 7-9
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł