- Tytuł:
- Formation of Br2 '-, BrSCN'- and (SCN)2'-intermediates in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide. Pulse radiolysis study
- Autorzy:
-
Grodkowski, J.
Nyga, M.
Mirkowski, J. - Powiązania:
- https://bibliotekanauki.pl/articles/147848.pdf
- Data publikacji:
- 2005
- Wydawca:
- Instytut Chemii i Techniki Jądrowej
- Tematy:
-
ionic liquids
pulse radiolysis
Br2 - Opis:
- The reactions of Br2 '- anion radicals with thiocyanate anions in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide (R4NNTf2) were studied by pulse radiolysis. Reaction of solvated electrons with BrCH2CH2Br (DBE), k = (1 2)×108 L.mol 1.s 1, leads to the production of Br2'- anion radicals. The intermediate absorption spectra following pulse radiolysis of DBE/SCN-/Br-/ solutions in R4NNTf2 correspond to Br2 '-, BrSCNo- and (SCN)2'- anion radicals. The participation of these radicals in the spectra changes with progressing reactions and depends on the concentration Br- and SCN- in the solution.
- Źródło:
-
Nukleonika; 2005, 50,suppl.2; 35-38
0029-5922
1508-5791 - Pojawia się w:
- Nukleonika
- Dostawca treści:
- Biblioteka Nauki
Artykuł