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Wyświetlanie 1-2 z 2
Tytuł:
Chemofitostabilizacja gleby zanieczyszczonej kadmem, cynkiem i ołowiem
Chemophytostabilisation of Soil Contaminated with Cadmium, Lead and Zinc
Autorzy:
Grobelak, A.
Kacprzak, M.
Grosser, A.
Napora, A.
Powiązania:
https://bibliotekanauki.pl/articles/1819023.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
chemofitostabilizacja
gleba
metale ciężkie
heavy metals
amendments
bioavailability
biosolids
immobilization
stabilization
remediation
mobility
compost
zn
Opis:
Assisted phytostabilisation involves the use of plants and soil additives for physical stabilization of the soil and chemical immobilization of contaminants. This technique aims to establish a vegetation cover with metal-tolerant plants and thus reduce leaching of metals. The main aim is to reduce the risk of incorporation of metal into the food chain. In the conducted experiment contaminated soil was collected from the area surrounding a zinc smelter in Miasteczko Slaskie, in the Silesia region of Poland. Soil in the study area has been contaminated with metals, especially Cd, Pb and Zn. Moreover, soils of the study area are also acidified. The role of sewage sludge and inorganic amendments as an immobilising agents in the attenuating phytostabilisation of metal-contaminated soil was evaluated using grass species Festucaarundinacea Schreb. The biosolid used was anaerobically digested sewage sludge, collected from the industrial waste water treatment plant and juices manufacturer (food industry). The soil was mixed with sewage sludge (sewage sludge accounted for 1and 3% of dry weight), lime and inorganic fertilizers (potassium phosphate, TSP at 0.8% each). A plant growth experiment was conducted in a growth chamber for 10 weeks. The plants were grown under artificial conditions, suitable for proper growth of plants. Plants growing on amended soil were devoid of any macroscopic symptoms of metal toxicity or nutrient deficiency, in contrast to plants grown on non-amended soil, where growth was inhibited and some phytotoxic effects were observed. For amended soil, plant growth was most likely influenced by improved soil conditions due to nutrient-rich amendments and metals immobilisation. Mobile fractions of metals decreased in amended soil, and the same pattern was observed for metal concentrations in plant tissues. However, the best results were obtained for the variants of combined application of sewage sludge and inorganic amendments. All investigated metals accumulated mainly in root tissues in combination with sewage sludge application. A significant reduction in metal uptake by plants was achieved after sewage sludge application, which is attributed to decreased bioavailability and the stabilisation of metals in soil. In the experiment the introduction of soil liming treatment allowed to maintain the pH at a constant level after 10 weeks of the experiment (5.5–7) (Fig. 1). The K5-K10 variants achieved a significant reduction in bioavailable forms (0.01 M CaCl2 extraction). In a study of biomass (Fig. 3) the highest yield (5.5 g DM) was obtained for the combined use of a combination of potassium and phosphate deposits and combinations of superphosphate and combined use of sewage sludge (2.5 g DM/pot). The highest immobilization effects were obtained for combined application of sewage sludge, lime fertilizer and superphosphate or potassium phosphate as compared to other options. The highest degree of immobilization of three tested heavy metals: cadmium, zinc and lead was obtained only with the application of sewage sludge and mineral amendments at a dose of TW +FP 0.8% + 1% d.m. sewage sludge. Effective process of chemophytostabilisation with the use of grass and organic additive and inorganic additives in situ sandy areas and heavily contaminated with heavy metals, can be obtained solely with the combined use of investigated additives and treatment.
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 2; 1982-2002
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Półciągła kofermentacja osadów ściekowych i odpadów tłuszczowych pochodzenia roślinnego
Semi-continuous Anaerobic Co-digestion of Mixed Sewage Sludge and Waste Fats of Vegetable Origin
Autorzy:
Grosser, A.
Worwąg, M.
Neczaj, E.
Grobelak, A.
Powiązania:
https://bibliotekanauki.pl/articles/1819118.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
osady ściekowe
odpady tłuszczowe
grease trap sludge
poultry slaughterhouse waste
organic fraction
acids
degradation
manure
fermentation
inhibition
ammonia
growth
Opis:
Anaerobic digestion (AD) is the most often applied technique for sewage sludge stabilization at medium and large wastewater treatment plants. Nonetheless, the application of AD to sewage sludge stabilization is often limited by long retention time and low VS (volatile solid) removal. For this reason in recent years a number of studies have been focused on optimize anaerobic digestion processes. One of the most interesting options for improving anaerobic digestion yields is co-digestion, namely simultaneous decomposition of a homogenous mixture of at least two biodegradable wastes. Fat-rich materials are attractive substrate for AD due to the high organic matter content of waste and high energetic potential. It is estimated that about 1,014 dm3, methane at STP (standard temperature and pressure) can by produced from 1 g VS lipids, while only 0,415, 0,496 dm3 can be produced respectively from 1 g VS carbohydrate and protein. However, due to inhibitory effect of intermediate compounds (LCFAs – long chain fatty acids) and operational problems, such as: hindrance, sedimentation clogging, scum formation, and flotation of biomass, separate AD of this waste ended with failure. The aim of the current study was to investigate how the co-digestion of fats of vegetable origin (FV) and mixed sewage sludge affected the performance of the anaerobic digestion (AD) process. The process was carried out at mesophilic conditions (37°C) in continuous stirred-tank reactor (CSTR) with working liquid volume equal to 6,5 dm3. The reactors were operated in draw-and fill mode (on a daily basis). The digestion was examined in semi-continuous mode at sludge retention time of 10 days and the organic loading rate maintained in the range 2,24–3,02 g/dm3 d. During the start-up period the digester was fed only sewage sludge. Co-digestion process was initiated after achievement of stable working parameters of bioreactor for sewage sludge digestion. Addition of fat in the feedstock was gradually increased up to 35%. Anaerobic process state indicators such as: biogas production, biogas composition, pH, alkalinity and volatile fatty acids (VFA) were used to monitor a digestion. Furthermore, the LCFAs concentrations were measured in a feed and digested sludge. The results showed that use of FV as a co-substrate adversely affects the efficiency of the process. Comparing digestion of MSS alone with co-digestion of wastes, it was shown that co-digestion resulted in lower biogas production and VS removal. Biogas yields for co-digestion mixtures were between 0,16 and0,32 dm3/g VS added, while volatile solid (VS) removal ranged from 36,75 to 42,65%.However average biogas yield and VS degradation degree observed during fermentation of the MSS(mixed sewage sludge) alone were 0,33 dm3/g VS added and 44%, respectively. Only for biogas composition noted the positive effect of mixed sewage sludge co-fermentation with FV. The study showed that the concentration of ammonia generated in this experiment did not inhibit anaerobic digestion. It was found that oleic acid, which is one of the most toxic long chain fatty acids, was present at concentrations (reached a maximum value of 34,38 mg/g TS) within the ranges for which inhibition of methanogenesis has been reported. This suggests that the low efficiency of the process was probably caused a high concentration of oleic acid.
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 3; 2108-2125
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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