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Wyświetlanie 1-2 z 2
Tytuł:
Alternative, Direct Synthesis Method of the Ceramic Solid Solutions Based on BaTiO3 Through a High Energy Ball Milling
Autorzy:
Bąk, W.
Dulian, P.
Garbarz-Glos, B.
Czekaj, D.
Lisińska-Czekaj, A.
Powiązania:
https://bibliotekanauki.pl/articles/351595.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ceramics
mechanochemical synthesis
dielectric properties
phase transitions
ferroelectrics
Opis:
Polycrystalline samples BaTiO3 and the solid solutions Ba0.9 Sr0.1 TiO3, 0.9 Sr0.1 Ti0.9 Sn0.1 O3, Ba0.9 Sr0.1 Ti0.8 Sn0.2 O3 were obtained by means of a mechanochemical treatment based on the high-energy ball milling technique and next a high temperature solid state reaction method. The influence of synthesis condition on microstructural, dielectric and ferroelectric properties of obtained solid solutions were investigated. The structure and morphology of the investigated samples were characterized by an X-ray diffraction (XRD) and scanning electron microscopy (SEM). The characterization of electrical properties of the ceramics within the temperature range from –130°C to 250°C were performed by means of a dielectric spectroscopy method at the frequency ranging from 0.1 Hz to10 MHz. The diffusion of the paraelectric – ferroelectric phase transition and dielectric relaxation for ceramic samples are described.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 805-810
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Semiconductor Element Substitution on the Electric Properties of Barium Titanate Ceramics
Autorzy:
Garbarz-Glos, B.
Lisińska-Czekaj, A.
Czekaj, D.
Bąk, W.
Powiązania:
https://bibliotekanauki.pl/articles/354672.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
barium titanate
ceramics
dielectric permittivity
electric conductivity
phase transitions
PTCR effect
Opis:
The investigated ceramics were prepared by a solid-state reaction from simple oxides and carbonates with the use of a mixed oxide method (MOM). The morphology of BaTi0.96Si0.04O3 (BTSi04) ceramics was characterised by means of a scanning electron microscopy (SEM). It was found that Si+4 ion substitution supported the grain growth process in BT-based ceramics. The EDS results confirmed the high purity and expected quantitative composition of the synthesized material. The dielectric properties of the ceramics were also determined within the temperature range (ΔT=130-500K). It was found that the substitution of Si+4 ions had a significant influence on temperature behavior of the real (ε’) and imaginary (ε”) parts of electric permittivity as well as the temperature dependence of a.c. conductivity. Temperature regions of PTCR effect (positive temperature coefficient of resistivity) were determined for BTSi04 ceramics in the vicinity of structural phase transitions typical for barium titanate. No distinct maximum indicating a low-temperature structural transition to a rhombohedral phase in BTSi04 was found. The activation energy of conductivity was determined from the Arrhenius plots. It was found that substitution of Si ions in amount of 4wt.% caused almost 50% decrease in an activation energy value.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 887-890
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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