- Tytuł:
- Effect of Tetraethylene Glycol Dimethyl Ether on Electrical, Structural and Thermal Properties of PVA-Based Polymer Electrolyte for Magnesium Battery
- Autorzy:
-
Gamal, R.
Sheha, E.
Shash, N.
El-Shaarawy, M. - Powiązania:
- https://bibliotekanauki.pl/articles/1399162.pdf
- Data publikacji:
- 2015-03
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
77.84.Lf
72.80.Tm - Opis:
- The aim of the contribution is to introduce a high performance magnesium conducting polymer electrolytes (PEs) comprising hybrid of poly(vinyl alcohol) (PVA), magnesium bromide ($MgBr_2$) and tetraethylene glycol dimethyl ether (TEGDME) as plasticizer are prepared at various compositions by solution cast technique. X-ray diffraction and thermogravimetric analyses suggest a substantial structural modification, decrease in crystallinity and various interactions in the polymer electrolyte components due to addition of TEGDME. Also there is a marked decrease in $T_{g}$ with increasing TEGDME. The conductivity conformation with the addition of plasticizer which can be explained on the basis of dissociation of ion aggregates formed in $PVA-MgBr_2$ polymer electrolytes at higher concentrations of the salt. The ionic conductivity of the polymer electrolyte increased with addition of salt and plasticizer reached to the highest conductivity value of ≈ $10^{-6} S cm^{-1}$ at 0.8 ml TEGDME. The frequency dependence of AC conductivity obeys the Jonscher power law. The estimated value of $Mg^{+2}$ ion transference number is found to be 0.68 for high conducting film. The open circuit voltage of a solid state battery which based on the optimum polymer electrolyte with a configuration Mg|PE|$V_2O_5$ is 1.5 V. Also this battery has exhibited a discharge capacity ≈3.78 mAh/g. The discharge characteristics are found to be satisfactory as a laboratory cell.
- Źródło:
-
Acta Physica Polonica A; 2015, 127, 3; 803-810
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł