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Wyświetlanie 1-2 z 2
Tytuł:
Ion exchange investigation for recovery of uranium from acidic pregnant leach solutions
Autorzy:
Danko, B.
Dybczyński, R. S.
Samczyński, Z.
Gajda, D.
Herdzik-Koniecko, I.
Zakrzewska-Kołtuniewicz, G.
Chajduk, E.
Kulisa, K.
Powiązania:
https://bibliotekanauki.pl/articles/147778.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
uranium recovery
acidic pregnant leach solution
ion exchange separation
Opis:
The article describes studies on the separation of uranium from acid pregnant leach solutions obtained from Polish uranium ores: dictyonema shales and sandstone rocks. Ion exchange chromatography was applied for uranium sorption, using commercially available, strongly basic anion exchanger, Dowex 1. In model experiments, the influence of degree of crosslinking of Dowex 1 on the efficiency of uranium extraction was investigated. The effect of H2SO4 concentration on the breakthrough curve of uranyl ions for the Dowex 1 resins, of different crosslinking: X4, X8 and X10, was examined. Unexpectedly high increase of exchange capacity of uranium was observed in case of Dowex 1X10. This gives potential opportunity of improving the effectiveness of uranium recovery process. Applying column packed with Dowex 1X10, ‘yellow cake’ with ca. 92% yield and high purity of recovered uranium was obtained. A block diagram of the procedure for uranium and lanthanides extraction from acidic leach liquor has been proposed.
Źródło:
Nukleonika; 2017, 62, 3; 213-221
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dictyonema black shale and Triassic sandstones as potential sources of uranium
Autorzy:
Kiegiel, K.
Zakrzewska-Kołtuniewicz, G.
Gajda, D.
Miśkiewicz, A.
Abramowska, A.
Biełuszka, P.
Danko, B.
Chajduk, E.
Wołkowicz, S.
Powiązania:
https://bibliotekanauki.pl/articles/147500.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
uranium ores
leaching
extraction
ion-exchange chromatography
precipitation
Opis:
The main objective of the present study was an assessment of the possibility of uranium recovery from domestic resources in Poland. In the fi rst stage uranium was leached from the ground uranium ore by using acidic (sulfuric acid or hydrochloric acid) or alkaline (carbonate) solutions. The leaching efficiencies of uranium were dependent on the type of ore and it reached 81% for Dictyonemic shales and almost 100% for sandstones. The novel leaching routes, with the application of the helical membrane contactor equipped with rotating part were tested. The obtained postleaching solutions were concentrated and purifi ed using solvent extraction or ion exchange chromatography. New methods of solvent extraction, as well as hybrid processes for separation and purifi cation of the product, were studied. Extraction with the use of membrane capillary contactors that has many advantages above conventional methods was also proposed as an alternative purification method. The fi nal product U3O8 could be obtained by the precipitation of ‘yellow cake’, followed by calcination step. The results of precipitation of ammonium diuranate and uranium peroxide from diluted uranium solution were presented.
Źródło:
Nukleonika; 2015, 60, No. 3, part 2; 515-522
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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