Temat: Fe-Al - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: First principles study of the isomer shift in Fe44M6Al50 (M = Ti, V, Cr, Co, Ni, Cu) alloys with B2 structure
Autorzy:: Michalecki, T.
Deniszczyk, J.
Frąckowiak, J.
Powiązania:: https://bibliotekanauki.pl/articles/147195.pdf
Data publikacji:: 2004
Wydawca:: Instytut Chemii i Techniki Jądrowej
Tematy:: iron
aluminum
isomer shift
Fe-Al compound
LMTO
Opis:: The 57Fe isomer shift for Fe44M6Al50 intermetallics with the B2 structure doped with M = Ti, V, Cr, Co, Ni and Cu additions has been calculated with the tight-binding linear muffin-tin orbital (TB-LMTO) method. The effect of variation of Wigner-Seitz (WS) spheres radii on the calculated equilibrium lattice parameter (a) and isomer shift (IS) was analyzed. The calculations have shown that the 57Fe isomer shift in Fe44M6Al50 intermetallics is directly proportional to the changes in the local 4s electronic charge at Fe atoms involved by M addtions. The screening effect of 4s electrons due to changes in (4p + 3d) electronic charge is of secondary importance. The calculated dependence of the average IS on nuclear charge (Z) of the alloying metal (M) follows qualitatively the tendency observed experimentally for the M impurities in the Fe host.
Źródło:: Nukleonika; 2004, 49,suppl.3; 3-6
0029-5922
1508-5791
Pojawia się w:: Nukleonika
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: Defect structure of Fe-Al and Fe-Al-X (X = Ni; Cu; Cr) metallic powders obtained by the self-decomposition method
Autorzy:: Hanc, A.
Frąckowiak, J.
Powiązania:: https://bibliotekanauki.pl/articles/147208.pdf
Data publikacji:: 2004
Wydawca:: Instytut Chemii i Techniki Jądrowej
Tematy:: iron aluminides
defects
points defects
Mössbauer spectroscopy
Fe-Al
Opis:: In the present work, the Fe-Al-X (X = Cu; Ni; Cr) metallic powders produced by the self-decomposition method of the Fe-Al doped alloys were examined by Mössbauer spectroscopy. The concentration of the Fe vacancies and the Fe atoms substituting Al (Fe-AS) was determined from the intensities of the sub-spectra in the Mössbauer analysis connected with distinct Fe environments. The results have shown that nickel and copper cause an increase of vacancy concentrations in comparison with the values found for Fe-Al metallic powders, whereas chromium decreases vacancy concentrations causing a significant increase of anti-site atoms Fe-AS concentration.
Źródło:: Nukleonika; 2004, 49,suppl.3; 7-11
0029-5922
1508-5791
Pojawia się w:: Nukleonika
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 3.

Tytuł:: A Mössbauer and structural study of disordered alloys Fe3-xTixAl (0 < x < 1)
Autorzy:: Brząkalik, K.
Frąckowiak, J.
Powiązania:: https://bibliotekanauki.pl/articles/148880.pdf
Data publikacji:: 2003
Wydawca:: Instytut Chemii i Techniki Jądrowej
Tematy:: Fe2TiAl Heusler phase
Fe-Ti-Al system
Mössbauer spectroscopy
Opis:: A series of the disordered Fe3-xTixAl (x = 0, 0.2, 0.45, 0.55, 0.65, 0.70, 0.75, 1) alloys obtained by arc-melting were studied. Directly after melting the samples were mechanically crashed and in that form examined by the structural and Mössbauer effect methods. The alloys were strongly disordered, but it was possible to identify, apart from Fe-bcc phase, the origins of forming such phases as Fe2TiAl Heusler phase, Fe3Al with DO3 structure, FeAl and FeTi with B2 structure and non-stechiometric Fe2Ti Laves phase with hexagonal C14 structure. For Ti concentration up to x = 0.45, the disordered Fe-bcc phase dominates. For Ti concentration from x = 0.55 to x = 1, the Fe2TiAl phase coexists with FeAl phase (for x = 0.55, 0.65) and with FeTi phase (x = 0.7 and 0.75). In a sample with the nominal Fe2TiAl composition of Fe2TiAl Heusler phase, a non-stoichiometric Fe2Ti Laves phase with hexagonal C14 structure was observed.
Źródło:: Nukleonika; 2003, 48,suppl.1; 13-16
0029-5922
1508-5791
Pojawia się w:: Nukleonika
Dostawca treści:: Biblioteka Nauki

Artykuł

Informacja