- Tytuł:
- 5,5'-Dinitrimino-3,3'-methylene-1H-1,2,4-bistriazole - a Metal Free Primary Explosive Combining Excellent Thermal Stability and High Performance
- Autorzy:
-
Dippold, A. A.
Feller, M.
Klapötke, T. M. - Powiązania:
- https://bibliotekanauki.pl/articles/358456.pdf
- Data publikacji:
- 2011
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
energetic materials
triazoles
detonation parameter
sensitivities - Opis:
- The synthesis of 5,5´-dinitrimino-3,3'-methylene-1H-1,2,4-triazole (1) and selected nitrogen rich salts are presented. All compounds were fully characterized in terms of sensitivity and energetic properties. Besides a chemical characterization including multinuclear magnetic resonance study (1H, 13C, 14N) and vibrational analysis (IR, Raman), X-Ray diffraction was performed. Thermal stability was determined using differential scanning calorimetry. Detonation parameters were calculated using the EXPLO5.4 code based on CBS-4M computed heats of formation. The presented compound 5,5´-dinitrimino-3,3´-methylene- 1H-1,2,4-bistriazole shows excellent thermal stabilities in combination with high sensitivities and therefore is of interest for possible applications as metal free primary.
- Źródło:
-
Central European Journal of Energetic Materials; 2011, 8, 4; 261-278
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki
Artykuł