- Tytuł:
- Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass
- Autorzy:
-
Stoch, P.
Ciecińska, M.
Zachariasz, P.
Suwalski, J.
Górski, L.
Wójcik, T. - Powiązania:
- https://bibliotekanauki.pl/articles/147350.pdf
- Data publikacji:
- 2013
- Wydawca:
- Instytut Chemii i Techniki Jądrowej
- Tematy:
-
iron phosphate glass
Mössbauer spectroscopy
nuclear waste
waste glass - Opis:
- A 57Fe Mössbauer spectroscopy study is presented. The main goal of the research was to investigate the structural information of the glass-like the coordination numbers and redox ratio of the iron. Most of the iron, about 80%, is present in the glass as Fe3+, which is composed of tetrahedral (57%) and octahedral (23%) coordinated iron. The rest of the iron, about 20%, is in the oxidation state Fe2+. This iron could be mostly present as VIFe2+, but five-fold coordinated iron is also possible. Finally, the structural model of the synthesized 60P2O5-40Fe2O3 glass was proposed.
- Źródło:
-
Nukleonika; 2013, 58, 1; 63-66
0029-5922
1508-5791 - Pojawia się w:
- Nukleonika
- Dostawca treści:
- Biblioteka Nauki
Artykuł