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Wyświetlanie 1-10 z 10
Tytuł:
Seepage mechanism during in-situ leaching process of weathered crust elution-deposited rare earth ores with magnesium salt
Autorzy:
Liu, Defeng
Zhang, Zhenyue
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/110849.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
seepage mechanism
weathered crust elution-deposited rare earth ores
in-situ leaching
magnesium salt
Opis:
To reveal seepage mechanism during in-situ leaching process of weathered crust elution deposited rare earth ores with magnesium salt, the effects of particle gradation, particle migration, Atterberg limit on the permeability coefficient were investigated, and the relation between the particle size and rare earth content was discussed. The results showed that the ore in the humic layer (HL) with high porosity and permeability was uniformly graded particles. The ore in the completely weathered layer (CWL) with low porosity and permeability belonged to dense-graded particles. The ore in the partly weathered layer (PWL) was open-graded particles, whose permeability fell in between the HL and the PWL. The change of -0.075mm particles content was the largest in the leaching process. When - 0.075mm particle content was less than 30%, the migration ability of fine particles and the permeability coefficient decreased gradually. On the contrary, the migration ability of fine particles gradually remained stable, and the change in the permeability coefficient was not obvious. The liquid limit (LL) in the Atterberg limit of HL, CWL and PWL was inversely proportional to the permeability coefficient, and followed the order: LLHL < LLPWL < LLCWL. With the -0.075mm particle content increasing, the LL of the ore samples increased gradually and finally tended to be stable. The peak value of rare earth concentration appeared earlier and the rare earth content decreased gradually with the increase of the ore particle size. This work provided a theoretical basis for achieving high-efficient mining of weathered crust elution-deposited rare earth ores.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 2; 350-362
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Screening of high-efficiency potassium-dissolving strains and optimization of the potassium-dissolving process
Autorzy:
Xue, Yongping
Xiao, Chunqiao
Zhang, Yantu
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/1447601.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
microorganism
potassium bacteria
potassium solubilization
potassium release
optimization of potassium-dissolving process
Opis:
The biosolubilization of potassium feldspar (K-feldspar) by potassium-dissolving microorganisms has become a hot research topic. However, the screening of highly efficient potassiumdissolving strains from the soils of mining areas has not been reported. In this study, 82 strains with potassium-dissolving ability were screened from soils collected from a K-feldspar mining area in Suizhou, Hubei Province, China. One of them, JX-20, was a gram-positive is spherical bacteria with smooth edges, which was identified as a new strain by 16S rRNA gene sequencing. Simultaneously, the influences of temperature, initial pH value, inoculation volume, incubation time, shaking speed, Kfeldspar concentration, K-feldspar granularity, and the ammonium sulfate dose on the potassium releasing ability of the JX-20 strain were investigated. The results showed that the JX-20 strain had an obvious dissolution effect on K-feldspar. The optimum conditions for the JX-20 strain to remove potassium from K-feldspar were as follows: cultured at 28-30℃ for ten days, initial pH value of 7.4-8, 60 mL medium in a 250 mL conical flask, and 170 r/min shaking speed on a rotary shaker. The Kfeldspar concentration, inoculation volume, K-feldspar granularity, and ammonium sulfate dose were 2 g/L, 20%, 0.02-0.03 mm, and 0.4 g/L, respectively. Under the above conditions, the highest corrosion efficiency of 39.75% was achieved.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 1-13
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The removal of dolomite from collophane using reverse flotation process enhanced by compound collector
Autorzy:
Liu, Liu
Tian, Mengjie
Deng, Xiangyi
Luo, Huihua
Chi, Ruan
Wu, Kang
Powiązania:
https://bibliotekanauki.pl/articles/2200338.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
collophane
dolomite removal
reverse flotation
compound collector
SDS
Opis:
To improve the magnesia removal effect of collophane and increase the P2O5 grade of phosphorus concentrate, the fatty acid collector mixed with sodium dodecyl sulfate (SDS) was used as the compound collector in reverse flotation for magnesia removal in acid system. Solution surface tension measurement, Zeta potential test and infrared spectrum analysis were conducted to analyze the intensified effect of compound collector for dolomite removal. The results showed that under the conditions of grinding fineness -0.074 mm accounted for 89.8%, sulfuric acid dosage 12.0 kg/t, phosphoric acid dosage 3.0 kg/t, SDS compound proportion 3%, collector dosage 1.0 kg/t, the P2O5 grade of concentrate is increased from 25.7% to 29.94%. SDS can reduce the surface tension of slurry, which is conducive to the formation and stability of flotation foam. Zeta potential became negative due to the compound collector adsorbed on the mineral surface. Moreover, the -CH2 antisymmetric stretching vibration peak originated from fatty acid and SDS were detected after the interaction of collectors with dolomite. The compound collector was effectively adsorbed on the surface of dolomite, enhancing the magnesium removal effect of collophane.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 159965
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of polyacrylamide on the process of removing impurities in the rare earth leachate
Autorzy:
Wu, Xiaoyan
Zhou, Fang
Liu, Chufan
Feng, Jian
Zhang, Zhenyue
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/1448504.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
polyacrylamide
rare earth leachate
impurity removal
flocs
Opis:
The impurity removal process of the rare earth (RE) leachate is usually accompanied by the formation of flocs, and a certain amount of polyacrylamide flocculant needs to be added in this process. However, few studies have investigated the effect of the flocculant on the impurity removal process. Therefore, this paper compares the influence on the process of removing impurities with or without the adding of polyacrylamide (PAM). The results showed that the addition of PAM had little effect on the removal rate of impurities, but it was conducive to the recovery of RE. When ammonium bicarbonate was firstly adopted to regulate the solution pH to 5.0, and then sodium sulfide was used to adjust the pH to 5.2, and 0.5 mL/100 mL of PAM was added to the leachate, 96% $Al^{3+}$ and 98% $Zn{2+}$ were removed from the leachate, while 95% RE was maintained. In addition, PAM could accelerate the settlement of flocs and then shorten the production cycle. The increase in RE recovery rate may be due to the addition of PAM to shorten the settling time of the flocs, thereby reducing the RE ions adsorbed during the flocculation process and increasing the recovery rate of the RE.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 182-191
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct reuse of rare earth oxalate precipitation mother liquor for rare earth leaching
Autorzy:
Wu, Xiaoyan
Zhou, Fang
Feng, Jian
Liu, Xueme
Zhang, Zhenyue
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/109869.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
weathered crust elution-deposited rare earth ore
oxalic acid
precipitation
mother liquor
Opis:
In the recovery process of rare earth (RE) from the weathered crust elution-deposited rare earth ore, ammonium sulfate is used as the leaching liquor to leach RE, and then the leachate containing RE3+ can be precipitated by oxalic acid and the RE oxalate precipitation mother liquor is reused for RE leaching process after removing the residual oxalic acid by precipitation with calcium hydroxide. However, the reuse process of precipitation mother liquor cannot proceed in the strong acid and alkali restricted areas and the discharge of mother liquor which contains a large amount of ammonium salt will cause ammonia-nitrogen waste and pollution. In order to realize the reuse of the precipitation mother liquor in this area, the direct reuse of RE oxalate precipitation mother liquor for RE leaching was investigated in this study. The RE oxalate precipitation process and the RE leaching process with oxalic acid were studied. The results showed that the residual oxalic acid concentration in the mother liquor can be controlled lower than 0.8 g/dm3 at pH 2-3 when the RE concentration in the leachate was 0.1- 1.5 g/dm3 and the RE precipitation rate reached to 94%. In addition, RE leaching efficiency was up to 90% while the oxalic acid concentration in the prepared mother liquor was 0.2-0.8 g/dm3, pH 2-3. Therefore, the precipitation mother liquor with oxalic acid concentration less than 0.8 g/dm3 could be directly reused for RE leaching. However, considering the different performance of RE ores, the recommended oxalic acid concentration in the direct used precipitation mother liquor was lower than 0.6 g/dm3.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 760-769
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enhanced biosolubilization of mid-low grade phosphate rock by formation of microbial consortium biofilm from activated sludge
Autorzy:
Xiao, Chunqiao
Wu, Xiaoyan
Zhu, Lei
Yu, Tong
Xu, Zhenghe
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/110353.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
biosolubilization
phosphate rock (PR)
microbial consortium
activated sludge
biofilm
Opis:
Mid-low grade phosphate rock (PR) is a potential source of free phosphate to facilitate crop growth, but a cost effective and environmentally responsible extraction process is required. In this study, the capacity of a microbial consortium from activated sludge to solubilize PR in a laboratory-scale column reactor was investigated. The microbial consortium proved capable of efficiently releasing soluble phosphate in the reactor effluent over the 90-day trial. The microbial consortium grew well in the column system as evidenced by reduced chemical oxygen demand (COD) in the reaction solution. Biofilm formation was identified as critical for biosolubilization of the mid-low grade PR. Imaging of the biofilm by scanning electron microscopy (SEM) revealed a dense network of microbial cells embedded in extracellular polymeric substances (EPS). The biofilm contained both oxic and anoxic zones. The pH decreased significantly in both the biofilm and the reaction solution during operation, indicating healthy growth of the microbial consortium with corresponding acid generation and subsequent enhancement of phosphate solubilization.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 217-224
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The intensified effect of nitrogen removal properties using Pseudomonas fulva K3 and MgBC for the weathered crust rare earth wastewater treatment
Autorzy:
Deng, Xiangyi
Chi, Ruan
Xiao, Chunqiao
Zhang, Zhenyue
Liu, Xuemei
Hu, Jingang
Powiązania:
https://bibliotekanauki.pl/articles/1447385.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
weathered crust rare earth wastewater
nitrogen removal
pseudomonas fulva K3
magnesium-modified biochar
intensified effect
Opis:
A new bacteria named Pseudomonas fulva K3 (P. fulva) strain was isolated from the surroundings of weathered crust rare earth tailing with efficient NH4+-N removal ability via heterotrophic nitrification and aerobic denitrification. The nitrogen removal properties could be intensified by the synergistic effect between as-prepared magnesium-modified biochar (MgBC) and P. fulva strain. The results show that P. fulva exhibited a rod-shaped morphology and $NH_4+-N$ can be completely biodegraded under the optimal conditions of pH=7.0~8.0, temperature 30 oC and initial $NH_4+-N$ concentration of 100 ~150 mg/L. The $NH_4+-N$ tolerant concentration for P. fulva was determined to be 300 mg/L. The magnesium-modified biochar (MgBC) worked as an adsorbent of $NH_4+-N$. The kinetics and isotherm model for adsorption could be described by the pseudo-secondorder kinetic and Freundlich model, respectively. The XPS results showed that $NH_4+-N$ was mainly adsorbed on the surface by chemical adsorption. Furthermore, the P. fulva could be immobilized on MgBC due to its large surface area, adjusting the concentration of $NH_4+-N$ to a proper range for the growth of P. fulva by adsorption and desorption equilibrium, and leading to the intensified effect on nitrogen removal. The total nitrogen removal efficiency of the eluted weathered crust rare earth tailing reached 84.7 % in MgBC + P. fulva system.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 3; 84-96
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of lanthanum(III) and yttrium(III) on kaolinite: kinetics and adsorption isotherms
Autorzy:
Zhou, Fang
Feng, Jian
Xie, Xiong
Wu, Baihong
Liu, Qi
Wu, Xiaoyan
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/109951.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
kaolinite
rare earth
kinetics
Opis:
Experimental investigations were carried out using kaolinite to adsorb two rare earth ions, lanthanum ion (La3+) and yttrium ion (Y3+), which will provide some useful information and new insights on the mineralization process and fractionation phenomenon of weathered crust elution-deposited rare earth ores. The results showed that the equilibrium adsorption capacity of Y3+ is greater than La3+ under the same experimental conditions. The adsorption of rare earth ions presents strongly temperature dependent indicating an endothermic adsorption process. The pseudo-first-order kinetic model and the pseudo-second-order kinetic model were applied to discuss the adsorption kinetics. It was found that the adsorption rate of rare earth follows the pseudo-second-order kinetic model among the adsorption temperature range. Furthermore, the adsorption process of rare earth ions on kaolinite followed the Langmuir isotherm model confirmed by the correlation of experimental equilibrium data to standard isotherm model, Langmuir and Freundlich isotherms. The activation energies for the adsorption of La3+ and Y3+ on kaolinite are 28.1903 kJ/mol and 25.4190 kJ/mol, respectively. All kaolinite before and after adsorption were characterized by XRD and SEM-EDX to understand the adsorption mechanism. The obtained results suggested that the adsorption of La3+ and Y3+ on kaolinite is an endothermic and chemisorption process.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 4; 928-939
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of cations on rare earth adsorption and desorption in binding sites of montmorillonite
Autorzy:
He, Zhengyan
Nie, Wenrui
Yang, Huifang
Tang, Yuchen
Sha, Aoyang
Qu, Jun
Xu, Zhigao
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/24085808.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
desorption
external site
interlayer site
basal spacing
Opis:
The exchangeability of rare earth (RE) in weathered crust elution-deposited rare earth ores largely depends on its interaction with clay minerals, which may be significantly influenced by various cations. Therefore, the effects of K+, Ca2+ and Al3+ on RE3+ adsorption and desorption in binding sites of montmorillonite (MMT) were investigated. Through the pre-saturation, the interlayer ions of MMT had been replaced by K+, Ca2+ or Al3+. RE3+ can adsorb on the interlayer sites of Ca-MMT and K-MMT, but nearly not Al-MMT. The basal spacing of Ca-MMT is larger than K-MMT, which provides a smaller hinder effect of interlayer collapse for the interlayer diffusion of RE3+. The adsorption capacity followed the order: Ca-MMT>K-MMT>Al-MMT and La3+>Y3+>Eu3+. It can predict that the grade of the exchangeable RE in ores abundant in Ca2+ is the most, followed by the ore rich in K+ and Al3+ the least. Clay minerals tend to adsorb light RE and hard to adsorb middle and heavy RE. The reversibility of RE adsorbed in interlayers, especially in collapsed interlayers, is far worse than that on externals. The desorption rates of RE were in the order of RE-Al-MMT>RE-K-MMT>RE-Ca-MMT and Eu3+>Y3+>La3+. For the desorption of interlayer RE3+, NH4+ is better than Mg2+ because the larger change of the basal spacings (Δd) provides more minor activation energy barriers (ΔE) for NH4+ diffusion within interlayers. It can enrich the metallogeny theory of weathered crust elution-deposited rare earth ores and provide a certain theoretical basis for its efficient exploitation.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 168280
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of chromatographic plate theory on the weathered crust elution-deposited rare earth ore with carboxylate
Autorzy:
Zhang, Zhenyue
Wang, Guangshuai
Li, Chunhua
Chi, Ruan
Long, Fei
Chen, Zhuo
Chi, Xiao Wang
Liu, Defeng
Powiązania:
https://bibliotekanauki.pl/articles/1446022.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
weathered crust elution-deposited rare earth ore
carboxylate ammonium
mass transfer
theory plate
rare earth
Opis:
To improve the leaching process of rare earth and reduce the impurities in the leachate, the carboxylate ammonium, such as ammonium acetate, ammonium citrate and ammonium tartrate, were selected as lixiviant to compare the effects of concentration, flow rate, pH and temperature on leaching mass process of rare earth and aluminum. Meanwhile, the leaching behaviors of rare earth and aluminum leached by three kinds of carboxylate ammonium were analyzed by chromatographic plate theory. The relationship between the flow rate and height equivalent (HETP) could fit well with the Van Deemter equation and there was an optimal flow rate (uopt) for the leaching of the rare earth and aluminum. Besides, the conditions of carboxylate ammonium lixiviant were optimized. The optimum concentrations of ammonium acetate, ammonium tartrate and ammonium citrate were 15 g/L, 25 g/L and 5 g/L respectively, the leaching flow rate was 0.50 mL/min, the pH value was approximatively 7.00 and the leaching temperature was 293 K to 303 K. At these conditions, the mass transfer efficiencies of three ammonium carboxylates for rare earth and aluminum was in the order of ammonium acetate > ammonium tartrate > ammonium citrate. Moreover, the ammonium acetate could commendably inhibit aluminum ions entering the lixivium.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 48-62
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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