- Tytuł:
- Application of MoO3 as an efficient catalyst for wet air oxidation treatment of pharmaceutical wastewater (Experimental and DFT study)
- Autorzy:
-
Chen, Chen
Cheng, Ting
Wang, Lei
Tian, Yuan
Deng, Qin
Shi, Yisu - Powiązania:
- https://bibliotekanauki.pl/articles/1845416.pdf
- Data publikacji:
- 2021
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
wet air oxidation
catalytic wet air oxidation
pharmaceutical wastewater
DFT - Opis:
- In this work, a highly effective catalyst (MoO3) is synthesized and applied for catalytic wet air oxidation (CWAO) treatment of pharmaceutical wastewater. The catalyst is systematically characterized to investigate the morphology, crystal structure and chemical composition, and the findings demostrated that MoO3 catalyst is successfully synthesized. The degradation mechanism is also illustrated by the density functional theory (DFT) calculation. The degradation experiments confirm that MoO3 catalyst exhibits excellent catalytic performance in CWAO, and the removal rate of TOC (Total Organic Carbon) and COD (Chemical Oxygen Demand) is achieved to more than 93%. The catalyst doses, reaction temperature and reaction time have a significant impact on the removal of pollutants. The degradation process of pollutants in CWAO could be satisfactorily fitted by the second-order kinetics. Besides, MoO3 displays a favorable stability as CWAO catalyst. DFT calculation illustrates that MoO3 catalyst is a typical indirect band gap semiconductor. Moreover, the high temperature environment provides the thermal excitation energy, which favors to the free electrons nearing Fermi level to escape the material surface, and excites them to the conduction band, then directly reduces the pollutants in CWAO. These findings demonstrate that MoO3 can be used as an efficient and excellent catalyst for CWAO of pharmaceutical wastewater.
- Źródło:
-
Archives of Environmental Protection; 2021, 47, 2; 47-60
2083-4772
2083-4810 - Pojawia się w:
- Archives of Environmental Protection
- Dostawca treści:
- Biblioteka Nauki
Artykuł