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Wyświetlanie 1-5 z 5
Tytuł:
Electronic Structure and X-Ray Photoelectron Spectra of YNi$\text{}_{4}$B Compound
Autorzy:
Pugaczowa-Michalska, M.
Chełkowska, G.
Kowalczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/2036993.pdf
Data publikacji:
2003-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Eh
82.80.Pv
71.20.-b
63.70.+h
Opis:
The electronic structure of the ternary YNi$\text{}_{4}$B compound, crystallizing in the hexagonal CeCo$\text{}_{4}$B structure (P6/ mmm space group), was studied by X-ray photoelectron spectroscopy and ab initio calculations. Core levels and the valence band were investigated. The X-ray photoelectron spectroscopy valence band is compared with that obtained from ab initio calculations. The valence band spectrum at the Fermi level exhibits the domination of the Ni(3d) states, which are hybridized with 4d states of Y and 2p states of B. The theoretical electronic specific heat coefficientγ derived from N(E$\text{}_{F}$) is about 11.33 mJ/(mol K$\text{}^{2}$) for experimental lattice parameters. The calculated bulk modulus is B$\text{}_{0}$=1.61632 Mbar.
Źródło:
Acta Physica Polonica A; 2003, 104, 5; 487-494
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electronic Properties of CeNiAl₄ Based on ab initio Calculations and XPS Measurements
Autorzy:
Werwiński, M.
Chełkowska, G.
Szajek, A.
Kowalczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/1030430.pdf
Data publikacji:
2018-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.b
74.25.Jb
Opis:
The CeNiAl₄ compound crystallizes in an orthorhombic YNiAl₄-type structure with a Cmcm space group. The earlier susceptibility data and X-ray photoelectron spectroscopy (XPS) suggested a localized character of the 4f states in CeNiAl₄ with a valence state close to a Ce⁺³ ion. In this work we present a combined theoretical and experimental study of the electronic structure for the Kondo dense system CeNiAl₄ based on the XPS data and ab initio calculations. Using the band structure calculations the theoretical XPS valence band spectra are evaluated. Below the Fermi energy the total density of states contains mainly 3d states of Ni hybridized with Ce 4f states.
Źródło:
Acta Physica Polonica A; 2018, 133, 3; 517-519
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Valence Band and Core Levels of $Ce_5Ni_2Si_3$ Crystal Studied by X-ray Photoemission Spectroscopy
Autorzy:
Toliński, T.
Kowalczyk, A.
Chełkowska, G.
Mihalik, M.
Timko, M.
Powiązania:
https://bibliotekanauki.pl/articles/1813673.pdf
Data publikacji:
2008-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Eh
82.80.Pv
Opis:
The crystal of $Ce_5Ni_2Si_3$ was prepared by the Czochralski method. The X-ray photoemission spectroscopy was measured for the valence band and the core levels. Based on the Ce(3d) doublet and its satellites a small value of the hybridization parameter of the f-states with the conduction electrons Δ=4 meV and the f-occupancy $n_f$ close to 1 were found. X-ray photoemission spectroscopy shows that the region between 0 and 3 eV is predominated by the Ni(3d) and Ce(4f) peaks. Some features of the multiplet structure of the Ce(4f) states are also visible close to the Fermi level.
Źródło:
Acta Physica Polonica A; 2008, 113, 1; 327-330
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
From Heavy Fermion and Spin-Glass Behavior to Magnetic Order in $CeT_4M$ Compounds
Autorzy:
Toliński, T.
Kowalczyk, A.
Falkowski, M.
Synoradzki, K.
Chełkowska, G.
Hoser, A.
Rols, S.
Powiązania:
https://bibliotekanauki.pl/articles/1426703.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Lp
71.27.+a
75.30.Mb
75.30.Cr
75.50.Lk
78.70.Nx
Opis:
We report on the transitions between the ferromagnetic order, spin-glass behavior, heavy fermion and fluctuating valence state in a series of isostructural compounds $CeT_4M$ (T = Ni, Cu; M = Al, Ga, Mn). The dilution of Ce or the T and M elements allowed us to follow the physical properties evolution employing the measurements of the heat capacity, dc magnetic susceptibility, frequency dependent ac magnetic susceptibility, magnetization relaxation, inelastic neutron scattering and also the X-ray photoemission spectroscopy. It is shown that the Mn rich compounds lean towards the spin glass behavior. For the compounds governed by the close to localization Ce 4f states the effect of the crystal electric field has been studied. It has been shown that the spin glass-like behavior can significantly influence the physics of the $CeT_4M$ compounds.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1014-1018
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Superconductivity and Electronic Structure of the W$\text{}_{7}$Re$\text{}_{13}$B Compound
Autorzy:
Kowalczyk, A.
Andrzejewski, B.
Jezierski, A.
Toliński, T.
Szlaferek, A.
Falkowski, M.
Chełkowska, G.
Powiązania:
https://bibliotekanauki.pl/articles/2046770.pdf
Data publikacji:
2006-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
71.20.Eh
74.70.-b
74.25.Ha
74.25.Jb
82.80.Pv
Opis:
The superconductor W$\text{}_{7}$Re$\text{}_{13}$B has been studied by the magnetic measurements and microwave absorption. The crystal structure of W$\text{}_{7}$Re$\text{}_{13}$B is cubic (β-Mn type). This compound exhibits a sharp superconducting transition at a temperature of T$\text{}_{c}$=7.2 K. The electronic structure of W$\text{}_{7}$Re$\text{}_{13}$B has been studied by X-ray photoelectron spectroscopy and the band structure has been calculated by the full-potential local-orbital minimum-basis method using the scalar-relativistic mode. The main contribution to the density of states at the Fermi level is from 5d electrons of W and Re. The W and Re bands are similar and substituting W by Re does not change the total density of states.
Źródło:
Acta Physica Polonica A; 2006, 109, 4-5; 597-600
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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