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Wyszukujesz frazę "Smoliński, M." wg kryterium: Autor


Wyświetlanie 1-2 z 2
Tytuł:
Studies on hydrometallurgical processes using nuclear techniques to be applied in copper industry. I. Application of 64Cu radiotracer for investigation of copper ore leaching
Autorzy:
Smoliński, T.
Rogowski, M.
Brykała, M.
Pyszynska, M.
Chmielewski, A. G.
Powiązania:
https://bibliotekanauki.pl/articles/147894.pdf
Data publikacji:
2018
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
copper ore
hydrometallurgy
leaching
NAA
Opis:
Scientific objective of this work was elaboration of radiometric method for the development of hydrometallurgical process for recovery of Cu from the copper ore. A neutron activation analysis (NAA) was identified as a very convenient tool for the process investigation. The samples of copper ore were activated in a nuclear reactor. The parameters of the neutron activation were calculated. Radioisotope 64Cu was selected as an optimal tracer, and it was used for the investigation of the leaching process. During the experiments, various processes applying leaching media such as sulphuric acid, nitric acid, and organic acids were investigated. The recovery of the metals using sulphuric acid was insufficient, around 10%. Investigated organic media also did not meet expectations. The best results were obtained in experiments with nitric acid. Up to 90% of Cu and other metals were extracted from the copper ore. Copper concentration calculations obtained by NAA were confimed by inductively coupled plasma mass spectrometry (ICP-MS) technique. Both techniques gave comparable results, but the advantage of the NAA is a possibility for easy online measurements without shutting down or disturbing the system.
Źródło:
Nukleonika; 2018, 63, 4; 123-129
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on hydrometallurgical processes using nuclear techniques to be applied in copper industry. 2. Application of radiotracers in copper leaching from fl otation tailings
Autorzy:
Rogowski, M.
Smoliński, T.
Pyszynska, M.
Brykała, M.
Chmielewski, A. G.
Powiązania:
https://bibliotekanauki.pl/articles/146346.pdf
Data publikacji:
2018
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
flotation waste
hydrometallurgy
leaching
radiotracer
Opis:
The use of radiotracers in the present study is intended to replace traditional steps of metal quantitative analysis (solution sampling and instrumental chemical analysis) and to allow real-time measurements of metal concentrations during the leaching process. In this study, 64Cu, an isotope of copper, was selected as a radiotracer. Samples of copper flotation tailings were irradiated in the Maria research reactor (Świerk, Poland) and mixed with an inactive portion of the milled flotation waste. The leaching process was carried out in a glass reactor, and the radiation spectrum was measured using a gamma spectrometer. The material was then treated using various acids (sulphuric acid, nitric acid, acetic acid, citric acid, and ascorbic acid) in a wide range of their concentrations. Experiments with the radiotracer were conducted in sulphuric and nitric acids. The amount of the leached metal (copper) was calculated on the basis of the peak area ratio in the gamma-ray spectrum of the activated tailings and standard samples. Inductively coupled plasma mass spectrometry (ICP-MS) was also used to analyse the metal content. Maximum recovery of 56% Cu was achieved using 9 M HNO3, whereas the recovery was lowest for ascorbic acid (1%). Both analytical methods were compared, and the results presented in this paper are in good agreement with radiometric measurements obtained using ICP-MS analysis.
Źródło:
Nukleonika; 2018, 63, 4; 131-137
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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