- Tytuł:
- Hydrodechlorination of tetrachloromethane over silica-supported palladium-gold alloys
- Autorzy:
-
Karpiński, Zbigniew
Bonarowska, Magdalena
Juszczyk, Wojciech - Powiązania:
- https://bibliotekanauki.pl/articles/778269.pdf
- Data publikacji:
- 2014
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
Pd-Au/SiO2
CCl4 hydrodechlorination
synergy
selectivity for hydrocarbons
catalyst deactivation - Opis:
- Compared with the monometallic palladium, bimetallic Pd-Au/SiO2 catalysts show much higher activity and better stability in the reaction of hydrodechlorination of tetrachloromethane, also providing higher selectivity to longer than methane hydrocarbon products. Reasonably mixed Pd-Au particles show better catalytic performance during ~60 h operation, whereas the monometallic palladium and very rich in palladium catalysts suffer rapid deactivation. Smaller amounts of carbon- and chlorine-containing deposits found after reaction on Pd-Au catalysts correspond to their superior catalytic behavior.
- Źródło:
-
Polish Journal of Chemical Technology; 2014, 16, 4; 101-105
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł