Temat: 61.30.-v - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Investigations of Phase Transitions in (NH$\text{}_{4}$)$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ Crystal by Means of Mn$\text{}^{2+}$ EPR Spectra
Autorzy:: Bednarski, W.
Waplak, S.
Powiązania:: https://bibliotekanauki.pl/articles/1952756.pdf
Data publikacji:: 1996-12
Wydawca:: Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:: 61.50.-f
76.30.-v
Opis:: EPR of Mn$\text{}^{2+}$ impurity ion in the (NH$\text{}_{4}$)$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal is studied in the temperature range 80-420 K. It is shown that Mn$\text{}^{2+}$ substitutes NH$\text{}_{4}^{+}$(I) ion and is coordinated in deformed oxygen octahedron in which takes two "off-center" positions. Its spin-Hamiltonian parameters and direction cosines of crystal field are determined. The successive EPR line splitting for three phase transitions is discussed.
Źródło:: Acta Physica Polonica A; 1996, 90, 6; 1185-1192
0587-4246
1898-794X
Pojawia się w:: Acta Physica Polonica A
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: EPR Study of Cu$\text{}^{2+}$ Doped Fast-Proton Conductor K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ in the Temperature Range 100-450 K
Autorzy:: Ostrowski, A.
Bednarski, W.
Waplak, S.
Powiązania:: https://bibliotekanauki.pl/articles/2037037.pdf
Data publikacji:: 2003-12
Wydawca:: Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:: 61.50.-f
76.30.-v
Opis:: The K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ doped with Cu$\text{}^{2+}$ ion was studied in detail by X-band CW EPR. Two kinds of Cu$\text{}^{2+}$ complexes (magnetically and structurally nonequivalent) denoted as Cu$\text{}^{2+}$(I) and Cu$\text{}^{2+}$(II) were found. Spin-Hamiltonian parameters, direction cosines, and coordination of Cu$\text{}^{2+}$ ion were determined at room temperature. The superhyperfine structure was observed below 250 K as a result of interacting of Cu$\text{}^{2+}$ ion with four equivalent protons (I=1/2). Temperature studies of K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal show that interbond motion as a precursor of superprotonic phase transition occurs at above≈250 K.
Źródło:: Acta Physica Polonica A; 2003, 104, 6; 549-558
0587-4246
1898-794X
Pojawia się w:: Acta Physica Polonica A
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 3.

Tytuł:: EPR Study of VO$\text{}^{2+}$ Center in Fast Proton Conductor K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$
Autorzy:: Ostrowski, A.
Waplak, S.
Bednarski, W.
Powiązania:: https://bibliotekanauki.pl/articles/2043409.pdf
Data publikacji:: 2005-07
Wydawca:: Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:: 61.50.-f
76.30.-v
Opis:: The pretransitional phenomena of superprotonic phase transition (T$\text{}_{sp}$=471 K) were studied in detail by X-band continuous wave EPR spectra of K$\text{}_{3}$H(SO$\text{}_{4}$)$\text{}_{2}$ crystal doped with VO$\text{}^{2+}$ ions. Three kinds of VO$\text{}^{2+}$ complexes (magnetically equivalent but structurally non-equivalent) denoted as VO$\text{}^{2+}$(I), VO$\text{}^{2+}$(II), and VO$\text{}^{2+}$(III) were found. "Smearing out" of the superhyperfine structure was observed as a result of interbond proton motion. VO$\text{}^{2+}$ impurity replaces K$\text{}^{+}$ ion and experiences the same average crystal field gradient at T$\text{}_{sp}$=471 K for I- and II-type complexes. The increase in interbond proton frequency hopping above 360 K is a reason of significant line broadening.
Źródło:: Acta Physica Polonica A; 2005, 108, 1; 127-135
0587-4246
1898-794X
Pojawia się w:: Acta Physica Polonica A
Dostawca treści:: Biblioteka Nauki

Artykuł

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