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Wyświetlanie 1-2 z 2
Tytuł:
X-Ray Diffraction Study of Bismuth Layer-Structured Multiferroic Ceramics
Autorzy:
Lisińska-Czekaj, A.
Czekaj, D.
Garbarz-Glos, B.
Bąk, W.
Kuźniarska-Biernacka, I.
Powiązania:
https://bibliotekanauki.pl/articles/355806.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Bi5FeTi3O15 ceramics
X-ray diffraction
crystal structure
Opis:
Goal of the present research was to apply a solid state reaction route to fabricate bismuth layer-structured multiferroic ceramics described with the formula Bi5FeTi3O15 and reveal the influence of processing conditions on its crystal structure and phase composition. Simple oxide powders Bi2O3, TiO2 and Fe2O3 were used to fabricate Aurivillius-type bismuth layer-structured ferroelectrics. Pressureless sintering in ambient air was employed and the sintering temperature was TS = 900°C, TS = 1000°C and TS = 1040°C. The phase composition as well as crystal structure of ceramics sintered at various processing conditions was examined with powder X-ray diffraction method at room temperature. The Rietveld refinement method was applied for analysis of X-ray diffraction data. It was found that ceramics adopted orthorhombic structure Cmc21. The unit cell parameters of bismuth layer-structured multiferroic ceramics increased slightly with an increase in sintering temperature.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 811-815
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics
Autorzy:
Lisińska-Czekaj, A.
Rerak, M.
Czekaj, D.
Lubina, M.
Garbarz-Glos, B.
Bąk, W.
Powiązania:
https://bibliotekanauki.pl/articles/353453.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
low temperature
broad band dielectric spectroscopy
multiferroic Bi6Fe2Ti3O18 ceramics
Opis:
In the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18is (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz - 10MHz) within the temperature range ΔΤ=-100°C - 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found that the measured impedance data exhibited good quality justifying further analysis. The residuals were found to be less than 1%, whereas the "chi-square" parameter was within the range χ2~-10-7 -10-5. Experimental data were analyzed using the circle fit of simple impedance arc plotted in the complex Z”-Z` plane (Nyquist plot). The total ac conductivity of the grain boundaries was thus revealed and the activation energy of ac conductivity for the grain boundaries was calculated. It was found that activation energy of ac conductivity of grain boundaries changes from ΕA=0.20eV to ΕA=0.55eV while temperature rises from Τ=-100°C up to Τ=200°C. On the base of maxima of the impedance semicircles (ωmτm=l) the relaxation phenomena were characterized in terms of the temperature dependence of relaxation times and relevant activation energy was calculated (ΕA=0.55eV).
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 3; 1447-1452
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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