- Tytuł:
- UV-VIS and FTIR Investigations of Long-Term Aged Explosives. Part 1
- Autorzy:
-
Shishkov, P.
Nedkova, M.
Atanasova, P. - Powiązania:
- https://bibliotekanauki.pl/articles/358450.pdf
- Data publikacji:
- 2011
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
UV-VIS
FTIR
TD-50
tetryl
H-bond - Opis:
- An investigation of TD-50 and tetryl samples obtained by dismantling of weapons, made in 1961 in Bulgaria, was carried out. The weapons were stored in non-heated military stores and the explosives were aged in this time (50 years). The results from UV-VIS and FTIR spectroscopy showed the formation of H-bonds in the solutions and in the investigated materials. The most available properties for determination of H-bond formation from UV-VIS spectra were: the shift, (Δ λ); ratio shift/dilution, (Δ λ /C1/Cn, nm, and Δ λ/Δ C, nm.ml/mg) in acetone solutions and only the shift, (Δ λ) in toluene solutions. The results from FTIR spectroscopy showed that the most available for determination of H-bond formation were: absorbances of some maxima for -NO2 groups, divided from maxima for -CH2 at 917 and 715 cm-1 like internal standards and some values of Δh*1/2.
- Źródło:
-
Central European Journal of Energetic Materials; 2011, 8, 4; 293-301
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki
Artykuł