- Tytuł:
-
Problemy kompatybilności rop naftowych
Crude oil compatibility problems - Autorzy:
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Krasodomski, Wojciech
Altkorn, Beata
Duda, Anna
Szuflita, Sławomir
Krasodomski, Michał - Powiązania:
- https://bibliotekanauki.pl/articles/1834263.pdf
- Data publikacji:
- 2020
- Wydawca:
- Instytut Nafty i Gazu - Państwowy Instytut Badawczy
- Tematy:
-
ropa naftowa
kompatybilność
test plamkowy
p-value
równoważnik ksylenowy
liczba nierozpuszczalności
liczba rozpuszczalności
crude oil
compatibility
spot test
xylene equivalent
Insolubility Number
Solubility Blending Number - Opis:
- Crude oil processed in refineries is a complex mixture of hydrocarbons in which some heteroorganic compounds are dissolved or suspended. These types of systems are usually characterized by some instability, associated with precipitation of multiphase structures depending on the chemical nature of the oil components. These phenomena affect the proper course of refinery processes. The formed suspensions, and consequently sediments, associated with a change in the chemical nature of the matrix (mixtures of hydrocarbons derived from petroleum), can block the refinery infrastructure – tanks and pipelines – as well as heat exchangers. These deposits can be transferred to the liquid phase only by increasing matrix polarity. Therefore, to prevent thermally irreversible peptization and sedimentation of asphaltene – resin structures and aggregates, it is necessary to assess the compatibility of processed oil as precisely as possible. When composing the charge, it is necessary to assess and test the compatibility of mixed crude oils. This work summarizes information on both the practical and the theoretical aspects of crude oil compatibility. The principles of petroleum classification, contemporary views on the construction of colloidal structures suspended in a hydrocarbon environment, theoretical basis of knowledge about the properties of hydrocarbons as solvents were discussed, and the techniques and methods used to assess the compatibility of petroleum raw materials were analyzed. Blotter tests are presented, from the simplest spot test, originally developed for testing the presence of insoluble particles in asphalt and its variants, to automated methods (the PORLA analyzer). Parameters characterizing compatibility are compared, the method of determining parameters such as the p-value, the xylene equivalent or the Heithaus coefficients and their use is presented. The article also discusses other parameters describing the petroleum compatibility model and their components, such as solubility parameters, defined as the Insolubility Number (IN), which is also a measure of the solubility of the asphaltenes, and the solubility blending number Solubility Blending Number (SBN), determining the oil’s ability to dissolve asphaltenes.
- Źródło:
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Nafta-Gaz; 2020, 76, 5; 332-339
0867-8871 - Pojawia się w:
- Nafta-Gaz
- Dostawca treści:
- Biblioteka Nauki
Artykuł