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Wyszukujesz frazę "binding sand" wg kryterium: Wszystkie pola


Wyświetlanie 1-3 z 3
Tytuł:
Assessment of the Harmfulness of Moulding Sands with Alkyd Resin Subjected to the High Temperature Influence
Autorzy:
Holtzer, M.
Dańko, R.
Żymankowska-Kumon, S.
Kubecki, M.
Bobrowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/354778.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
moulding sand
binding
BTEX
thermal analysis
GC/MS
Opis:
Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. These resins in their initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin, under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAHs) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX and PAHs group. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 500 – 1 300°C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. The qualitative and quantitative analyses of compounds were performed by means of the gas chromatography coupled with the mass spectrometry (GC/MS).
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 4; 2171-2176
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kryteria oceny właściwości wiążących bentonitów
Assessment criteria of bentonite binding properties
Autorzy:
Żymankowska-Kumon, S.
Powiązania:
https://bibliotekanauki.pl/articles/381878.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bentonit
montmorillonit
masa formierska
pęcznienie masy
kompleks miedziowy
wytrzymałość na ściskanie
bentonite
montmorillonite
green sand
growth indicator
copper complex
compression strength
Opis:
W artykule zaproponowano kryteria jakimi należy się kierować przy ocenie właściwości wiążących bentonitów stosowanych do mas formierskich. Poza standardowym parametrem jakim jest zawartość aktywnego bentonitu należy uwzględnić wskaźnik swobodnego pęcznienia, który wydaje się być bardziej adekwatny w ocenie wytrzymałości masy na ściskanie. Przeprowadzone badania dla trzech rodzajów bentonitów stosowanych w polskich odlewniach, poddanych działaniu wysokiej temperatury wykazały, że przebieg zmian wskaźnika swobodnego pęcznienia jest bardzo zbliżony do przebiegu zmian wytrzymałości masy na ściskanie. Natomiast charakter zmian zawartości montmorillonitu w masie w zależności od temperatury jest odmienny. Pomimo tego, że masa wykazuje znaczną zawartość aktywnego bentonitu, jej wytrzymałość na ściskanie spada bardzo gwałtownie. Zawartość montmorillonitu w próbkach bentonitów oznaczono nowoczesną metodą kompleksu miedziowego – trietylenotetraaminy (Cu(II)-TET). Badania prowadzono dla bentonitów i mas z tymi bentonitami poddawanych działaniu wysokiej temperatury w zakresie 100-700ºC.
The criteria, with which one should be guided at the assessment of the binding properties of bentonites used for moulding sands, are proposed in the paper. Apart from the standard parameter which is the active bentonite content, the unrestrained growth indicator should be taken into account since it seems to be more adequate in the estimation of the sand compression strength. The investigations performed for three kinds of bentonites, applied in the Polish foundry plants, subjected to a high temperature influences indicate, that the pathway of changes of the unrestrained growth indicator is very similar to the pathway of changes of the sand compression strength. Instead, the character of changes of the montmorillonite content in the sand in dependence of the temperature is quite different. The sand exhibits the significant active bentonite content, and the sand compression strength decreases rapidly. The montmorillonite content in bentonite samples was determined by the modern copper complex method of – triethylenetetraamine (Cu(II)-TET). Tests were performed for bentonites and for sands with those bentonites subjected to high temperatures influences in a range: 100-700ºC.
Źródło:
Archives of Foundry Engineering; 2012, 12, 1s; 209-213
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the compounds from the BTEX group, emitted during thermal decomposition of alkyd resin
Autorzy:
Kubecki, M.
Holtzer, M.
Bobrowski, A.
Dańko, R.
Grabowska, B.
Żymankowska-Kumon, S.
Powiązania:
https://bibliotekanauki.pl/articles/380216.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
masa formierska
wiązanie
BTEX
analiza termiczna
GC-MS
moulding sand
binding
thermal analysis
Opis:
Suitability of the given binding agent for the moulding sands preparation depends on the one hand on the estimation of technological properties of the sand and the mould made of it and the obtained casting quality and on the other hand on the assessment of this sand influence on the natural and working environment. Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. If in the initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin (phenol-formaldehyde, urea, furfuryl, urea-furfuryl, alkyd) under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAH) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX group. An emission of these components constitutes one of the basic criteria of the harmfulness assessment of binders applied for moulding and core sands. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 5000C - 13000C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. Within investigations the minimal amount of adsorbent necessary for the adsorption of compounds released during the decomposition of the resin sample of a mass app. 15 mg was selected. Also the minimal amount of solvent needed for the desorption of compounds adsorbed in the column with adsorbent was found. The temperature range, in which the maximal amounts of benzene, toluene, ethylobenzene and xylenes are released from the resin, was defined. The qualitative and quantitative analyses of compounds from the BTEX group were performed by means of the gas chromatography combined with the mass spectrometry (GC/MS).
Źródło:
Archives of Foundry Engineering; 2012, 12, 3; 69-74
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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