- Tytuł:
- Application of polymer inclusion membranes doped with 1-hexyl-4-methylimidazole for pertraction of zinc(II) and other transition metal ions
- Autorzy:
-
Ulewicz, M.
Radzyminska-Lenarcik, E. - Powiązania:
- https://bibliotekanauki.pl/articles/110567.pdf
- Data publikacji:
- 2015
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
polymer inclusion membrane
PIM
metal ions separation
zinc(II)
transition metal ions
imidazole derivatives - Opis:
- Transport of Zn(II) from unary aqueous chloride solutions and from solutions which contain mixtures of Cd(II), Co(II) and Ni(II) ions in source phases (cMe = 0.001 mol/dm3, pH = 6.0) across polymer inclusion membranes (PIMs) doped with 1-hexyl-4-methylimidazole as ion carrier was studied. The use of 1-hexyl-4-methylimidazole enables the separation of 98.5% Zn(II) from a unary solution and 96.9% from a quaternary solution of Zn(II)-Cd(II)-Co(II)-Ni(II) after running the process for 24 hours. Using that ion carrier, the metals are transported in the following order: Zn(II) > Cd(II) > Ni(II) > Co(II), and the selectivity coefficients of Zn(II)/Cd(II), Zn(II)/Ni(II), and Zn(II)/Co(II) are 12.9, 23.4 and 40.8, respectively. Findings of atomic force microscopy (AFM) examinations as well as thermograms of a polymer inclusion membrane containing 1-hexyl-4-methylimidazole are also presented. A membrane with 1.0 mol/dm3 of carrier has a porosity of 15.8%, and roughness of 6.6 nm. The membranes remain thermally stable at temperatures up to 200oC. The findings were compared with earlier-reported results for 1-hexylimidazole.
- Źródło:
-
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 447-460
1643-1049
2084-4735 - Pojawia się w:
- Physicochemical Problems of Mineral Processing
- Dostawca treści:
- Biblioteka Nauki
Artykuł