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Tytuł:
Tectonic discrimination of siliciclastic sedimentary record of the northern Tethyan margin at the end of the Triassic
Autorzy:
Vďačný, Marek
Michalík, Josef
Lintnerová, Otília
Powiązania:
https://bibliotekanauki.pl/articles/2058608.pdf
Data publikacji:
2019
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
sedimentology
geodynamics
major elements
trace elements
palaeogeography
Opis:
Tectonic setting of both the uppermost Triassic Tomanová and the lowermost Jurassic Dudziniec formations can be characterized by a series of diagnostic discrimination diagrams. High-silica and low-silica multi-dimensional diagrams indicate that the sediments could have been deposited in the continental collision/rift setting. Diagrams of K2O/Na2O versus SiO2, SiO2/Al2O3 versus K2O/Na2O and Th-Co-Zr/10 as well as Th-Sc-Zr/10 determine an origin from the tectonically active and/or passive continental margin setting. REE parameters indicate predominantly a passive margin tectonic setting of the sediments. The most probable source of clastic admixture in the Scythian to Domerian sediments in the Tatric Unit was situated in a remnant of the Variscan collisional orogen - the Vindelician Highlands. Occasional monsoonal rains occurring in orbitally controlled cycles transported weathered material from the source area down river valleys on the seaward slopes of the Variscan Vindelician Mountains towards the Tethyan Sea. The input of this material influenced also the marginal parts of the Fatricum (e.g., Vysoká or Havran units).
Źródło:
Geological Quarterly; 2019, 63, 1; 30--38
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of nitrogen fertilization with ENTEC-26 and ammonium nitrate on the concentration of thirty-one elements in carrot (daucus carota l.) storage roots
Wpływ nawożenia azotem z ENTEC-26 i saletrą amonową na zawartość trzydziestu jeden pierwiastków w korzeniach spichrzowych marchwi (Daucus carota L.)
Autorzy:
Smolen, S.
Sady, W.
Wierzbinska, J.
Powiązania:
https://bibliotekanauki.pl/articles/1188055.pdf
Data publikacji:
2012
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Tematy:
nitrogen fertilization
nitrification inhibitor
DMPP
heavy metals
rare elements
trace elements
Opis:
Aplikowanie inhibitorów nitryfikacji wraz z nawozami azotowymi (zawierającymi zredukowane formy azotu: amonową i amidową) może wzmacniać zakwaszające działanie tych nawozów na glebę. W efekcie może to prowadzić do obniżenia pH oraz zmian zawartości dostępnych dla roślin form metali ciężkich i pierwiastków śladowych w glebie. Celem badań była ocena wpływu stosowania nawozów azotowych z ENTEC-26 (zawierającego inhibitor nitryfikacji 3,4-dimetylopyrazolofosfat /DMPP/) i saletrą amonową na skład mineralny korzeni spichrzowych marchwi. Przeprowadzono dwuletnie badania z polową uprawą marchwi Kazan Fj. Doświadczenie założono metodą split-plot w czterech powtórzeniach. Obiektami badań były kombinacje ze zróżnicowanym nawożeniem azotem: 1 - kontrola (bez nawożenia azotem), 2 - ENTEC-26 35+35, 3 - ENTEC-26 70+70, 4 - ENTEC-26 105+105, 5 - saletra amonowa 35+35, 6 - saletra amonowa 70+70, 7 - saletra amonowa 105+105, gdzie: 35+35, 70+70 i 105+105 oznacza dawkę azotu w kg N ha- 1 stosowaną w nawożeniu przedsiewnym i w nawożeniu pogłównym. w korzeniach spichrzowych oraz w glebie po uprawie marchwi zawartość: Ag, Al, B, Ba, Ca, Ce, Co, Cr, Dy, Fe, Ga, In, K, La, Li, Lu, Mg, Mn, Na, Ni, P, Pb, S, Sc, Sn, Sr, Ti, Tm, Y, Yb i V była oznaczana techniką ICP-OES. Nawożenie azotem miało istotny wpiyw na zawartość Co, Fe, In, Li, Mn, Ni, S, Sc, Sr, Y, Yb i V w marchwi. Jednakże wpiyw ten był zróżnicowany w zależności od zastosowanego sposobu nawożenia azotem w badanych kombinacjach. Nie stwierdzono natomiast istotnego oddziaływania nawożenia azotem na zawartość Ag, Al, B, Ba, Ca, Ce, Cr, Dy, Ga, K, La, Lu, Mg, Na, P, Pb, Ti i Sn w marchwi. W porównaniu z kontrolą, zastosowane nawożenie azotem we wszystkich dawkach zarówno w formie ENTEC-26, jak i saletry amonowej powodowało zmniejszenie zawartości Mg, Al, B, Ba, Ce, Fe, Ga, La, Ni, Pb, Ti, Y, V, Cr, Dy, In, Li, Lu, Sc i Yb oraz zwiększenie zawartości Ca, Sr i Ag w glebie po uprawie marchwi. Jednakże wykazane zmiany zawartości tych pierwiastków w glebie pod wpływem nawożenia azotem nie miały odzwierciedlenia w ich zawartości w korzeniach spichrzowych marchwi.
Źródło:
Journal of Elementology; 2012, 17, 1; 115-137
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Indium in polymetallic mineralisation at the Gierczyn mine, Karkonosze-Izera Massif, Poland : results of EPMA and LA-ICP-MS investigations
Autorzy:
Foltyn, Krzysztof
Bertrandsson Erlandsson, Viktor
Kozub-Budzyń, Gabriela Anna
Melcher, Frank
Piestrzyński, Adam
Powiązania:
https://bibliotekanauki.pl/articles/2058542.pdf
Data publikacji:
2020
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Gierczyn
indium
trace elements
metamorphism
Opis:
Cassiterite and base-metal mineralisation from the Gierczyn mine on the Karkonosze-Izera Massif, Poland has been studied using electron microprobe and LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) techniques in order to determine the content of indium in the ore minerals. The main carriers of this element are sphalerite (up to 433 μ/g of In), chalcopyrite (up to 117 μ/g of In) and cassiterite (up to 0.02 wt.% In). Trace element contents of sulphides, especially Ga in chalcopyrite intergrown with sphalerite in comparison with chalcopyrite without sphalerite, may indicate metamorphic re-equlibration and suggests that the ore minerals might recrystallized and underwent metamorphism in conditions of greenschist/amphibolite facies. Although the deposits in the Stara Kamienica Schist Belt are not of economic value, they can contribute to better understanding of the relations between trace element partitioning and the formation of ore minerals.
Źródło:
Geological Quarterly; 2020, 64, 1; 74--85
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace analysis of Indonesian volcanic ash using thermal and epithermal neutron activation analysis
Autorzy:
Canion, B.
Jacques, C.
Landsberger, S.
Taftazani, A.
Powiązania:
https://bibliotekanauki.pl/articles/146890.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
neutron activation analysis (NAA)
trace elements
volcanic ash
rare earth elements (REE)
Mount Merapi
Opis:
There is continued great interest in determining the trace element and heavy metal content of volcanic ash for a variety of reasons. The motivation stems from the desire to understand the geochemistry of volcanic ash in imbedded geological formations, the impact on seawater, and the possible release of toxic elements into the environment that may impact livestock grazing and water systems. Ash from volcanic plumes can go as high 8-18 km thus affecting climate and air traffic. We have employed Compton suppression neutron activation analysis (NAA) with thermal and epithermal neutrons to determine trace elements in volcanic ash from Indonesian eruption of Mount Merapi in October 2010. We found a wide range of elements, including several rare earth elements.
Źródło:
Nukleonika; 2012, 57, 4; 585-589
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of the Ahmadabad hematite/barite deposit, Iran – studies of mineralogy, geochemistry and fluid inclusions
Autorzy:
Babaei, A. H.
Ganji, A.
Powiązania:
https://bibliotekanauki.pl/articles/94546.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
geochemistry
trace elements
rare earth elements
Semnan
geochemia
pierwiastki śladowe
pierwiastki ziem rzadkich
REE
Opis:
The Ahmadabad hematite/barite deposit is located to the northeast of the city of Semnan, Iran. Geostructurally, this deposit lies between the Alborz and the Central Iran zones in the Semnan Subzone. Hematite-barite mineralisation occurs in the form of a vein along a local fault within Eocene volcanic host rocks. The Ahmadabad deposit has a simple mineralogy, of which hematite and barite are the main constituents, followed by pyrite and Fe-oxyhydroxides such as limonite and goethite. Based on textural relationships between the above-mentioned principal minerals, it could be deduced that there are three hydrothermal mineralisation stages in which pyrite, hematite and barite with primary open space filling textures formed under different hydrothermal conditions. Subsequently, in the supergene stage, goethite and limonite minerals with secondary replacement textures formed under oxidation surficial conditions. Microthermometric studies on barite samples show that homogenisation temperatures (TH) for primary fluid inclusions range from 142 to 256°C with a temperature peak between 200 and 220°C. Salinities vary from 3.62 to 16.70 NaCl wt% with two different peaks, including one of 6 to 8 NaCl wt% and another of 12 to 14 NaCl wt%. This indicates that two different hydrothermal waters, including basinal and sea waters, could have been involved in barite mineralisation. The geochemistry of the major and trace elements in the samples studied indicate a hydrothermal origin for hematite and barite mineralisation. Moreover, the Fe/Mn ratio (>10) and plots of hematite samples of Ahmadabad ores on Al-Fe-Mn, Fe-Mn-(Ni+Co+ Cu)×10, Fe-Mn-SiX2 and MnO/TiO2 – Fe2O3/TiO2 diagrams indicate that hematite mineralisation in the Ahmadabad deposit occurred under hydrothermal conditions. Furthermore, Ba and Sr enrichment, along with Pb, Zn, Hg, Cu and Sb depletion, in the barite samples of Ahmadabad ores are indicative of a low temperature hydrothermal origin for the deposit. A comparison of the ratios of LaN/YbN, CeN/YbN, TbN/LaN, SmN/NdN and parameters of Ce/Ce* and La/La* anomalies of the hematite, barite, host volcanic rocks and quartz latite samples to each other elucidate two important points: 1) the barite could have originated from volcanic host rocks, 2) the hematite could have originated from a quartz latite lithological unit. The chondrite normalised REE patterns of samples of hematite barite, volcanic host rocks and quartz latite imply that two different hydrothermal fluids could be proposed for hematite and barite mineralisation. The comparison between chondrite normalised REE patterns of Ahmadabad barite with oceanic origin barite and low temperature hydrothermal barite shows close similarities to the low temperature hydrothermal barite deposits.
Źródło:
Geologos; 2018, 24, 1; 55-68
1426-8981
2080-6574
Pojawia się w:
Geologos
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace element geochemistry of coals from the Southern Cantabrian Zone (NW Spain): preliminary results
Autorzy:
Botor, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/2086486.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
trace elements
coal
Cantabrian Mountains
Spain
Opis:
Bituminous to anthracite coals from three small Stephanian intramontane coal-bearing basins (La Magdalena, Cinera-Matallana and Sabero) located along the Sabero-Gordón fault line strike-slip systems of the Southern Cantabrian Zone (SCZ) were examined. Coal rank expressed as mean vitrinite reflectance values of these Stephanian coals is in the range 0.72-3.96%. The vitrinite maceral group exceeds 72 vol. % in all of the coals. The coals are characterized by relatively variable contents of mineral matter and coal-ash. The mineral matter comprises, in the main, clay minerals, carbonates, sulphides and quartz. The coals exhibit medium-high concentrations (see for comparison Ronov et al. 1990; Kabata-Pendias, Pendias 1999; Ketris, Yudovich 2009) of the following elements (in ppm): ΣREE (53-205), Ba (300-900), As (11-57), Zn (<50-150), Cr (10-160), Rb (50- 145), Co (5-26), Sc (2-24.6), Ce (17-99), Yb (1.3-4.5), Th (2.4-11.9) and U (1.1-8.1), Br (<1-14), Cs (<2-9), Eu (<0,3-1.5), Lu (0.11-0.85) and Sb (0.8-4.8), and relatively low concentrations of Sm (0.6-6.6) and Ta (<1-2). They are also characterised by relatively high Th/U values (1.31-2.29). LREE/HREE values fall in the range 24-44 (average - 30). In contrast, concentrations of Au, Ag, Hg, Ir, Ni, Se, Sn, Sr, and W are below detection limits for the applied INAA method. As the concentrations of elements are significantly higher in coal-ash, most are likely related to mineral matter in the coals.
Źródło:
Mineralogia; 2011, 42, 1; 39--51
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace element geochemistry of coals from the Southern Cantabrian Zone (NW Spain): preliminary results
Autorzy:
Botor, D.
Powiązania:
https://bibliotekanauki.pl/articles/2086537.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
trace elements
coal
Cantabrian Mountains
Spain
Opis:
Bituminous to anthracite coals from three small Stephanian intramontane coal-bearing basins (La Magdalena, Cinera-Matallana and Sabero) located along the Sabero-Gordón fault line strike-slip systems of the Southern Cantabrian Zone (SCZ) were examined. Coal rank expressed as mean vitrinite reflectance values of these Stephanian coals is in the range 0.72-3.96%. The vitrinite maceral group exceeds 72 vol. % in all of the coals. The coals are characterized by relatively variable contents of mineral matter and coal-ash. The mineral matter comprises, in the main, clay minerals, carbonates, sulphides and quartz. The coals exhibit medium-high concentrations (see for comparison Ronov et al. 1990; Kabata-Pendias, Pendias 1999; Ketris, Yudovich 2009) of the following elements (in ppm): ΣREE (53-205), Ba (300-900), As (11-57), Zn (<50-150), Cr (10-160), Rb (50- 145), Co (5-26), Sc (2-24.6), Ce (17-99), Yb (1.3-4.5), Th (2.4-11.9) and U (1.1-8.1), Br (<1-14), Cs (<2-9), Eu (<0,3-1.5), Lu (0.11-0.85) and Sb (0.8-4.8), and relatively low concentrations of Sm (0.6-6.6) and Ta (<1-2). They are also characterised by relatively high Th/U values (1.31-2.29). LREE/HREE values fall in the range 24-44 (average - 30). In contrast, concentrations of Au, Ag, Hg, Ir, Ni, Se, Sn, Sr, and W are below detection limits for the applied INAA method. As the concentrations of elements are significantly higher in coal-ash, most are likely related to mineral matter in the coals.
Źródło:
Mineralogia; 2011, 42, 1; 39--51
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The content of macro and microelements in the shoots of Glyceria maxima of the Słupia River
Autorzy:
Parzych, A.
Cymer, M
Powiązania:
https://bibliotekanauki.pl/articles/125150.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
macrophytes
macroelements
trace elements
accumulation
pollution
Opis:
The study shows the content of macro- and microelements in the leaves and rhizomes of Glyceria maxima of the Słupia River in Słupsk. The content of macro and micro-elements in G. maxima was analyzed for each component separately and in an integrated way, and comparing the demand for nutritions. The largest quantity of nitrogen, phosphorus, potassium, magnesium and calcium were found in the leaves, meanwhile zinc, iron, manganese, nickel and copper in the G. maxima rhizomes. The amount of Zn and Cu, in all of the tested positions, within the range of the limit for the plants, and the concentrations of Ni and Mn exceed physiological needs. The U Mann Whitney test showed a number of statistically significant differences in the concentration of the analyzed elements in leaves – rhizomes, leaves – bottom sediment and rhizome bottom sediment relation. The relations between designated heavy metals formed a following series: Mn>Fe>Zn>Ni>Cu in leaves and Fe>Mn>Zn>Ni>Cu in rhizomes. The G. maxima shoots accumulated 985.8 do 1441.4 mmolc∙kg-1 in all the analyzed components, and the lower value of the sum of the accumulated macro and microelements were found in rhizomes. The sum of ion comospition of the macronutrients in the leaves and rhizomes was similar. The content of nitrogen was 51.7–53.7% of this amount, 5.8–8.6% phosphorus, potassium 22.8 – 26.6%, 4.9-5.8% of magnesium, calcium, 8.2–11.9%, and trace elements were 0.58% in total, in the case of leaves and 8.70% in the rhizomes.
Źródło:
Journal of Ecological Engineering; 2014, 15, 4; 29-36
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prognosis of environmental impact of trace elements from brown coal-fired power plant Bełchatów
Autorzy:
Konieczyński, J.
Komosiński, B.
Jabłońska, M.
Cieślik, E.
Powiązania:
https://bibliotekanauki.pl/articles/204574.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
environment protection
brown coal
trace elements
combustion products
fl ue gas desulphurization (FGD) gypsum
forecast of trace elements emission
forecast of trace elements transfer
Opis:
A forecast of the negative impact exerted on the environment by selected trace elements in "Bełchatów" Power Plant has been prepared on the basis of the results of investigations into these elements’ distribution carried out as part of earlier research on coal from “Bełchatów” Field and the data on updated analyses of the content of these elements in 55 brown coal samples from test boreholes. Work in "Bełchatów" Power Plant, which is supplied with coal from "Szczerców" Field, will be accompanied by trace elements transfer. On the basis of the conducted investigations it has been found that the biosphere is most threatened by mercury emissions. As shown by the presented results of analyses and calculations, the emissions of mercury in "Bełchatów" Power Plant are low. Mercury is accumulated chiefly in gypsum produced in the FGD plant. The content of mercury in slag and ash is low.
Źródło:
Archives of Environmental Protection; 2012, 38, 3; 59-72
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemometric evaluation of concentrations of trace elements in intervertebral disc tissue in patient with degenerative disc disease
Autorzy:
Kubaszewski, Łukasz
Zioła-Frankowska, Anetta
Gasik, Zuzanna
Frankowski, Marcin
Dąbrowski, Mikołaj
Molisak, Bartłomiej
Kaczmarczyk, Jacek
Gasik, Robert
Powiązania:
https://bibliotekanauki.pl/articles/987050.pdf
Data publikacji:
2017
Wydawca:
Instytut Medycyny Wsi
Tematy:
intervertebral disk
degeneration
trace elements
chemometrics
Opis:
Background. The work is designed to uncover the pattern of mutual relation among trace elements and epidemiological data in the degenerated intervertebral disk tissue in humans. Hitherto the reason of the degenerative process is not fully understood. Trace elements are the basic components of the biological compound related both its metabolism as well as environmental exposure. The relation pattern among elements occurs gives new perspective in solving the cause of the disease. Methods. We have analysed trace elements content in the 30 intervertebral disc from 22 patients with degenerative disc disease. The concentrations of Al, Cu, Cd, Mo, Ni and Pb were determined with Atomic Absorption Spectrometry. To analyse the multidimentional relation between trace element concentration and epidemiological data the chemometric analysis was applied. Results. The similarity have been shown in occurrence of following pairs: Cd-Mo as well as Mg-Zn. The second pair was correlated with Pb concentration. Pb levels are observed to be competitive to Cu concentration. Cd concentration was related to Zn and Mg deficiency. No single but rather cluster of epidemiological data show observable influence on the TE tissue variance. Zn and Cu was related to the male sex. Operation with orthopedic implants were related to combined Al, Mo and Zn concentration. Conclusions. This is the first chemometric analysis of trace elements in disk tissue. It shows multidimentional relations that are missed by the classical statistic. The analysis shows significant relation. The nature of the relations is the basis for further metabolic and environmental research.
Źródło:
Annals of Agricultural and Environmental Medicine; 2017, 24, 4
1232-1966
Pojawia się w:
Annals of Agricultural and Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Content and uptake of selected trace elements by weeds in potato to cultivation under different conditions of soil tillage and weed control methods
Autorzy:
Zarzecka, K.
Gugała, M.
Baranowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/124723.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
weeds
trace elements
content
uptake
potato
Opis:
The study utilized data from a field experiment carried out at the Experimental Station in Zawady owned by the University of Natural Sciences and Humanities in Siedlce in the years 2005–2007. The experimental factors included two soil tillage systems and seven weed control methods in potato. Iron, copper and zinc in weeds were deter- mined with the AAS method. The trace element content in weed dry matter before row closure of potato depended significantly on soil tillage methods (excluding Cu), weed control methods and weather conditions, and, prior to tuber harvest, on soil tillage and weather conditions during the growing season. The uptake of Fe, Cu, and Zn by weeds from the area of 1 hectare depended on the experimental factors, weed biomass and weed chemical composition.
Źródło:
Journal of Ecological Engineering; 2014, 15, 4; 131-136
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ nałogu palenia na interakcje pierwiastków fizjologicznych z Mo, Li, Ti, Sr w strukturze mineralnej złogów pęcherzyka żółciowego
Effects of smoking addiction on the interactions of physiological elements with Mo, Li, Ti, Sr in the mineral structure of gallbladder deposits
Autorzy:
Musielińska, R.
Kwapuliński, J.
Szady, B.
Szady, A.
Powiązania:
https://bibliotekanauki.pl/articles/410261.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet Humanistyczno-Przyrodniczy im. Jana Długosza w Częstochowie. Wydawnictwo Uczelniane
Tematy:
złogi pęcherzyka żółciowego
interakcje
nałóg palenia
pierwiastki śladowe
pierwiastki odnośnikowe
gallstones
interactions
smoking
trace elements
reference elements
Opis:
Celem badań było określenie kierunku zmian zawartości Ti, Li, Mo, Sr w nawiązaniu do zmian zawartości czterech podstawowych pierwiastków fizjologicznych (Mg, K, Ca, Na) w strukturze mineralnej hydroksyapatytów złogów pęcherzyka żółciowego, na podstawie analizy zmian ilorazów przeciętnej zawartości badanych pierwiastków w hydroksyapatytach złogów pęcherzyka żółciowego i zawartości poszczególnych metali traktowanych jako odnośnikowe. Zawartość pierwiastków w złogach pęcherzyka żółciowego pozyskanych podczas cholecystektomii oznaczano metodą emisyjnej spektrometrii z plazmą wzbudzoną indukcyjnie (ICP-AES) z wykrywalnością 0,01µg/g. Obecność i kierunek zmian badanych pierwiastków w złogach pęcherzyka żółciowego obrazowana ilorazem przeciętnej zawartości danego pierwiastka Me+n i przeciętnej zawartości pierwiastków odnośnikowych Me+k jest determinowana płcią, nałogiem palenia oraz miejscem zamieszkania w zależności od stopnia zanieczyszczenia powietrza tymi pierwiastkami. Graficzny obraz zmian ilorazu Me+n/Me+k w odniesieniu do przeciętnej zawartości pozostałych pierwiastków odnośnikowych - Me+k wchodzących w skład struktury mineralnej złogów pęcherzyka żółciowego pozwala wskazać na znaczenie fizjologiczne danego pierwiastka w procesie jego złożonej kumulacji w patogenie.
The aim of this study was to determine the direction of changes in the content of Ti, Li, Mo, Sr in relation to changes in the content of four basic physiological elements (Mg, K, Ca, Na) in the mineral structure of hydroxyapatites of gallbladder deposits, on the basis of the analysis of changes in the quotient of the average content of the tested elements in hydroxyapatites of gallbladder deposits and the content of individual metals treated as references. The content of elements in gallstones deposits obtained during cholecystectomy was determined by inductively induced plasma emission spectrometry (ICP-AES) with a detection rate of 0,01µg/g. The presence and direction of changes in the examined elements in the gallbladder deposits, illustrated by the quotient of the average content of a given Me+n element and the average content of the Me+k reference elements, is determined by sex, smoking addiction and place of residence depending on the degree of air pollution with these elements. The graphical picture of changes in the Me+n/Me+k ratio in relation to the average content of other reference elements - Me+k, which are part of the mineral structure of gallstones deposits - allows to indicate the physiological significance of a given element in the process of its complex accumulation in pathogenesisethods.
Źródło:
Chemistry, Environment, Biotechnology; 2018, 21; 30-37
2083-7097
Pojawia się w:
Chemistry, Environment, Biotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical composition of soil and lake sediments - an indicator of geological processes in Lithuania
Autorzy:
Gregorauskiene, V.
Kadunas, V.
Powiązania:
https://bibliotekanauki.pl/articles/2059444.pdf
Data publikacji:
2000
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Lithuania
trace elements
soil
lake sediments
geoindicators
Opis:
Long-term multipurpose geochemical studies in Lithuania show that the chemical composition of surface sediment can be used as an indicator of geological process: duration of weathering, soil formation and thickness of sediment. The chemical composition of upper and lower soil layers and of lake sediments gives information on past sedimentation: the type and age of Quaternary deposits and the location and depth of Pleistocene glaciolacustrine basins. We therefore have a baseline to predict changes in surface chemistry provoked by current anthropogenic pressures.
Źródło:
Geological Quarterly; 2000, 44, 4; 347-354
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessing Spatial Distributions of Total Trace Elements Content in Bottom Sediments of Dzierżno Duże Water Reservoir – Geostatistics-Based Studies
Autorzy:
Rozpondek, R.
Rozpondek, K.
Powiązania:
https://bibliotekanauki.pl/articles/123432.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
bottom sediments
spatial distribution
trace elements
geostatistics
Opis:
The aim of this study was to assess the spatial distributions of total trace elements content in the bottom sediments of Dzierżno Duże water reservoir, along with the comparison of the accuracy and characteristics of Kriging and IDW interpolations. On the basis of regular measurement grid consisting of 53 points, bottom sediments samples were collected. Mean values of total trace elements content in bottom sediments of Dzierżno Duże were as follows: Zn – 410 mg/kg, Pb – 57 mg/kg, Cr – 36 mg/kg, Cu – 40 mg/kg, Cd – 5 mg/kg, Ni – 16 mg/kg and Ba – 267 mg/kg. According to the geochemical quality classification, the concentrations of Cd in 32% of samples were assigned to class IV (heavily contaminated), 45% to class III (contaminated), Zn in 42% samples to class III with 1 sample in class IV and 26% to class II (slightly contaminated), Pb in 9% to class III and 58% to class II, Cu in 4% to class III and 68% to class II, Cr in 17% to class II, Ni in 55% to class II, Ba in 8% to class III and 61% in class II. Coefficient of determination was determined between each case of trace elements content. The highest correlation (R2 in range from 0.81 to 0.96) was observed between Zn and Pb, Zn and Cu, Zn and Cr, Zn and Ni, Pb and Cu, Pb and Cr, Cu and Cr, Cr and Ni. Significant correlation (R2 in range from 0.70 to 0.80) occurred between: Zn and Cd, Pb and Ni, Cu and Ni, Cd and Ni. The lowest correlations (R2 in range from 0.25 to 0.70) were observed between concentration of Ba and the rest of trace elements. Two different interpolation methods were chosen for the purpose of generating spatial distributions – Inverse Distance Weighted and Ordinary Kriging. These methods were chosen for purpose of obtaining optimal accuracy result of spatial distributions. The distributions of trace elements content were classified by means of geochemical criteria. In the case of accuracy comparison between IDW and Ordinary Kriging, the former had slightly better results in terms of mean value and root mean square. The generated spatial distributions allowed to determine the most contaminated areas, which were mainly northern-central and southern-central parts of water Dzierżno Duże reservoir.
Źródło:
Journal of Ecological Engineering; 2018, 19, 3; 52-60
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Multi-element analysis of urine using dynamic reaction cell inductively coupled plasma mass spectrometry (ICP-DRC-MS) — A practical application
Autorzy:
Brodzka, Renata
Trzcinka-Ochocka, Małgorzata
Janasik, Beata
Powiązania:
https://bibliotekanauki.pl/articles/2179785.pdf
Data publikacji:
2013-04-01
Wydawca:
Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
Tematy:
metals
trace elements
exposure
urine
ICP-MS
Opis:
Objectives: The method for the determination of As, Al, Cd, Ni, Pb (toxic elements) and Cr, Co, Cu, Fe, Mn, Zn (essential elements) in human urine by the use of Inductively Coupled Plasma Mass Spectrometry (quadrupole ICP-MS DRCe Elan, Perkin Elmer) with the dynamic reaction cell (DRC) was developed. Materials and Methods: The method has been applied for multi-element analysis of the urine of 16 non-exposed healthy volunteers and 27 workers employed in a copper smelter. The analysis was conducted after initial 10-fold dilution of the urine samples with 0,1% nitric acid. Rhodium was used as an internal standard. The method validation parameters such as detection limit, sensitivity, precision were described for all elements. Accuracy of the method was checked by the regular use of certified reference materials ClinCheck®-Control Urine (Recipe) as well as by participation of the laboratory in the German External Quality Assessment Scheme (G-EQUAS). Results: The detection limits (DL 3s) of the applied method were 0.025, 0.007, 0.002, 0.004, 0.004, 0.086, 0.037, 0.009, 0.016, 0.008, 0.064 (μg/l) for Al, As, Cd, Cr, Co, Cu, Fe, Mn, Ni, Pb, Zn in urine, respectively. For each element linearity with correlation coefficient of at least 0.999 was determined. Spectral interferences from some of the ions were removed using DRC-e with addition of alternative gas: methane for cobalt, copper, cadmium, chromium, iron, manganese, nickel and rhodium, and oxygen for arsenic. Conclusions: The developed method allows to determine simultaneously eleven elements in the urine with low detection limits, high sensitivity and good accuracy. Moreover, the method is appropriate for the assessment of both environmental and occupational exposure.
Źródło:
International Journal of Occupational Medicine and Environmental Health; 2013, 26, 2; 302-312
1232-1087
1896-494X
Pojawia się w:
International Journal of Occupational Medicine and Environmental Health
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 110

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