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    Wyświetlanie 1-4 z 4
    Tytuł:
    Geochemical signatures of pervasive meteoric diagenesis of Early Miocene syn-rift carbonate platform, Red Sea, NW Saudi Arabia
    Autorzy:
    Al-Ramadan, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060345.pdf
    Data publikacji:
    2017
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    meteoric diagenesis
    carbonate
    stable isotopes
    trace elements
    Red Sea
    Miocene
    Opis:
    Different diagenetic environments have been recognized in the Early Miocene carbonate platform of Musayr Formation in the Red Sea rift area. Early marine diagenesis includes micritisation that occurs as thin envelope around skeletal and non-skeletal grains in low-energy mud dominated facies and isopachous fibrous calcite in high-energy grain-dominated facies. Pervasive meteoric water diagenesis resulted in cementation of the carbonates by coarse-crystalline blocky-drusy calcite and meniscus cements. Depletion of oxygen (avg. –9.08‰), carbon (avg. –1.6‰) isotopes and trace elements concentrations (avg. values of Fe: 1387 ppm; Mn: 1444 ppm; Sr: 419 ppm; Na: 1194 ppm) in conjunction with negative correlation between Mn2+ and oxygen isotope data suggest variable degrees of fluid-rock interactions and pervasive meteoric diagenesis. The formation of meteoric diagenesis in the Musayr Formation can be explained by two subsequent mechanisms: (1) the presence of meteoric lenses during the time of deposition might have been associated with active freshwater input from the hinterland (NE) due to fall in the relative sea level; (2) later uplift episode during Plio-Pleistocene may have also contributed to the pervasive meteoric diagenetic alterations of the carbonates of the Musayr Formation. The first mechanism is supported by the cement stratigraphy where the blocky-drusy cements postdate the meniscus cement. The latter mechanism seems to have more pronounced effect on the alteration of Musayr carbonate sequence by observing the occurence of late cements such as blocky calcite in most of the samples. The impact of meteoric diagenesis on the studied samples suggest that dissolution is less severe than cementation, hence the visible porosity is very low. Understanding the timing of meteoric diagenesis provides useful information about the reservoir quality distribution in syn-rift carbonate sequences.
    Źródło:
    Geological Quarterly; 2017, 61, 1; 239--250
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Regional hardening of Upper Cretaceous Chalk in eastern England, UK: trace element and stable isotope patterns in the Upper Cenomanian and Turonian Chalk and their significance
    Autorzy:
    Jeans, C. V.
    Long, D.
    Hu, X.-F.
    Mortimore, R. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/139436.pdf
    Data publikacji:
    2014
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    chalk hardening
    trace elements
    stable isotopes
    cement modelling
    reservoir diagenesis
    history
    kreda
    hartowanie
    pierwiastki śladowe
    izotopy trwałe
    cement
    historia
    Opis:
    The regional hardening of the Late Cenomanian to Early Turonian Chalk of the Northern Province of eastern England has been investigated by examining the pattern of trace elements and stable carbon and oxygen isotopes in the bulk calcite of two extensive and stratigraphically adjacent units each 4 to 5 m thick of hard chalk in Lincolnshire and Yorkshire. These units are separated by a sequence, 0.3–1.3 m thick, of variegated marls and clayey marls. Modelling of the geochemistry of the hard chalk by comparison with the Standard Louth Chalk, combined with associated petrographic and geological evidence, indicates that (1) the hardening is due to the precipitation of a calcite cement, and (2) the regional and stratigraphical patterns of geochemical variation in the cement are largely independent of each other and have been maintained by the impermeable nature of the thin sequence of the clay-rich marls that separate them. Two phases of calcite cementation are recognised. The first phase was microbially influenced and did not lithify the chalk. It took place predominantly in oxic and suboxic conditions under considerable overpressure in which the Chalk pore fluids circulated within the units, driven by variations in compaction, temperature, pore fluid pressure and local tectonics. There is evidence in central and southern Lincolnshire of the loss of Sr and Mg-enriched pore fluids to the south during an early part of this phase. The second phase of calcite precipitation was associated with the loss of overpressure in probably Late Cretaceous and in Cenozoic times as the result of fault movement in the basement penetrating the overlying Chalk and damaging the seal between the two chalk units. This greatly enhanced grain pressures, resulting in grain welding and pressure dissolution, causing lithification with the development of stylolites, marl seams, and brittle fractures. Associated with this loss of overpressure was the penetration of the chalk units by allochthonous fluids, rich in sulphate and hydrocarbons, derived probably from the North Sea Basin. Microbial sulphate-reduction under anoxic conditions within these allochthonous fluids has been responsible for dissolving the fine-grained iron and manganese oxides within the chalk, locally enriching the Fe and Mn content of the calcite cement. The possibility is discussed that the pattern of cementation preserved in these regionally hard chalks of Late Cenomanian and Early Turonian age may be different from that preserved in the younger (late Turonian to Campanian) more basinal chalks of eastern England.
    Źródło:
    Acta Geologica Polonica; 2014, 64, 4; 419-455
    0001-5709
    Pojawia się w:
    Acta Geologica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Geochemical and stable isotope patterns of calcite cementation in the Upper Cretaceous Chalk, UK: Direct evidence from calcite-filled vugs in brachiopods
    Autorzy:
    Hu, X.
    Jeans, C.
    Dickson, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/139259.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    cement kalcytowy
    diageneza
    historia
    izotopy stabilne
    kreda
    pierwiastki śladowe
    wpływ drobnoustrojów
    anoxia
    calcite cement
    chalk
    diagenesis
    history
    Microbial influence
    oxia
    stable isotopes
    suboxia
    trace elements
    Opis:
    The history of research into the cementation of the Upper Cretaceous Chalk of the UK is reviewed. Calcite-filled vugs within the shell cavities of terebratulid brachiopods from the Cenomanian Chalk of eastern england have been investigated by cathodoluminesence imaging, staining, electron microprobe and stable isotope analysis. This has provided the first detailed analysis of the geochemistry of the Chalk.s cement. two cement series, suboxic and anoxic, are recognized. Both start with a Mg-rich calcite with positive [delta^13]C values considered to have been precipitated under oxic conditions influenced by aerobic ammonification. The suboxic series is characterized by positive [delta^13]C values that became increasingly so as cementation progressed, reaching values of 3.5[per mil]. Manganese is the dominant trace element in the earlier cement, iron in the later cement. Mn-and Fe-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. The anoxic series is characterized by [delta^13]C values that became increasingly negative as cementation progressed, reaching values of .6.5[per mil]. Trace elements are dominated by iron and manganese. Sulphate-reducing microbes influenced cement precipitation and the trace element and [delta^13]C patterns. Both cement series are related closely to lithofacies and early lithification pre-dating the regional hardening of the Chalk. The suboxic series occurs in chalk which was continuously deposited and contained hematite pigment and limited organic matter. The anoxic series was associated with slow to nil deposition and hardground development inc halks that originally contained hematite pigment but no longer do so, and an enhanced supply of organic matter.
    Źródło:
    Acta Geologica Polonica; 2012, 62, 2; 143-172
    0001-5709
    Pojawia się w:
    Acta Geologica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Porównanie podatności magnetycznej (MS) i wskaźników geochemicznych środkowego i górnego franu w Kanadyjskich Górach Skalistych: implikacje dla analiz paleoklimatycznych i paleośrodowiskowych oraz interpretacji zdarzenia punctata
    Comparison of magnetic susceptibility (MS) and other geochemical proxies from the Middle-Late Frasnian of the Canadian Rocky Mountains: implication for paleoenvironmental and paleoclimatic analyses and interpretations of the punctata Event
    Autorzy:
    Śliwiński, M. G.
    Whalen, M.
    Day, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2074752.pdf
    Data publikacji:
    2010
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    późny dewon
    podatność magnetyczna
    zdarzenie punctata
    pierwiastki śladowe
    wycieczka geochemiczna
    izotopy trwałe
    zbiorniki osadowe Kanady zachodniej
    Late Devonian
    magnetic susceptibility
    punctata Event
    trace elements
    stable isotopes
    Western Canada Sedimentary Basin
    Opis:
    Ongoing magnetostratigraphic and geochemical studies (including major and trace element geochemistry and stable isotopes of C, N, O) in the Canadian Rocky Mountains are providing insight into the paleoenvironmental changes of the mid-Frasnian punctata Event, a prominent marine geochemical perturbation. The data is evaluated with 1) a regional sequence stratigraphic perspective and 2) within the context of a rapidly changing Late Devonian world, characterized by numerous sedimentological and faunal perturbations leading up to the eventual Frasnian-Fammenian (F/F) mass extinction. Proxies for bottom water paleoredox conditions (Mo, V, U), oceanic primary productivity (δ13Corg, δ15Nbulku, Cu, Ni, Ba), changes in detrital input (Si, Al, K, Ti, Zr), and magnetic susceptibility display similar trends, indicating that these proxies and MS variations are inherently linked. The observed excursions suggest that changes in detrital input were the main driver of a bioproductivity increase. Elevated organic matter export from the photic zone likely led to the deposition and later preservation of organic-carbon rich facies under facilitated conditions of bottom water suboxia-anoxia. These geochemical trends were likely influenced by eustatic sea level change, but may have been enhanced by pulses of coincident orogenic activity and pulses of terrestrial afforestation. The rise and expansion of the first true forests is thought to have drastically altered nutrient fluxes to the oceans via increases in pedogenesis and the expansion of a mature soil profile. Our work is intended to complement the growing body of research aimed at elucidating the causes and understanding the effects of terrestrial and marine events of the P. punctata biozone and, more broadly, at understanding the Earth-system changes of the Late Devonian leading up to the F/F boundary.
    Źródło:
    Przegląd Geologiczny; 2010, 58, 12; 1152-1160
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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