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    Wyświetlanie 1-4 z 4
    Tytuł:
    Lead(II) removal from aqueous solutions by solvent extraction with tetracarboxylresorcin[4]arene
    Autorzy:
    Konczyk, J.
    Kozlowski, C.
    Walkowiak, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110670.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    solvent extraction
    lead(II)
    zinc(II)
    cadmium(II)
    resorcinarene
    Opis:
    A novel tetracarboxylresorcin[4]arene was synthesized and its selective complexing ability towards Pb(II) ions was examined. The influence of several parameters such as pH of aqueous phase, agitation time, extractant and modifier concentrations on solvent extraction of Pb(II) ions from the aque-ous nitrate phase into chloroform organic phase was studied. The stoichiometry of the formed metal-ligand complexes was established by slope analysis. Pb(II) ions were quantitatively extracted in the form of 2:1 Pb(II)-resorcin[4]arene complex from aqueous solutions of pH 5.5 to the solution of ligand in chloroform. Competitive solvent extraction experiments in the presence of Zn(II) and Cd(II) ions were also carried out and high selectivity of the extractant towards Pb(II) over Zn(II) and Cd(II) was found. The selectivity order was: Pb(II) >> Cd(II) > Zn(II).
    Źródło:
    Physicochemical Problems of Mineral Processing; 2013, 49, 1; 213-222
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    N-(diethylthiophosphoryl)-aza[18]crown-6: synthesis and ability of solvent extraction toward lead(II), zinc(II) and cadmium(II) metal cations
    Autorzy:
    Kozlowska, J.
    Miroshnichenko, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/346955.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
    Tematy:
    crown ethers
    solvent extraction
    lead(II)
    zinc(II)
    cadmium(II)
    Opis:
    This work presents the synthesis of a strongly hydrophobic, functionalized monaza crown ether, i.e., lariat ether, namely N-(diethylthiophosphoryl)-aza[18]crown-6 and its application as ion extractant in solvent extraction systems. The synthesis of thiophosphorylated aza[18]crown-6 was performed with good yield. Separation systems have been successfully developed to extract Pb(II), Cd(II) and Zn(II) into organic phase, i.e., chloroform with the crown ethers: aza[18]crown-6 and N-(diethylthiophosphoryl)-aza[18] crown-6 as extractants. The selectivity order in both crown ethers was Pb(II) >> Cd(II) > Zn(II). The obtained results suggest that N-(diethylthiophosphoryl)-aza[18]crown-6 can be used for the selective removal of Pb(II) at lower pH values than aza[18]crown-6.
    Źródło:
    Ars Separatoria Acta; 2012-2013, 9/10; 7-14
    1731-6340
    Pojawia się w:
    Ars Separatoria Acta
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Extraction properties of tetraheptylresorcin[4]arenes in relation to Cr(III) ions
    Autorzy:
    Konczyk, J.
    Miroshnychenko, S.
    Kozlowski, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/109751.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    solvent extraction
    resorcin[4]arenes
    chromium(III)
    cadmium(II)
    zinc ions
    Opis:
    Resorcin[4]arene-based ligand bearing four heptyl chains at the lower rim of the molecule was prepared and modified by four tetradietoxyphosphoryl groups in the upper rim. The compounds obtained were characterized by NMR spectroscopy and their extractability toward chromium(III) ions was studied. The influence of process parameters such as the pH of aqueous phase, agitation time and also extractant’s structure and concentration on efficiency of Cr(III) ions solvent extraction is presented. The highest yield of Cr(III) solvent extraction was obtained for two-hour agitation time of 5.010−4 M metal solution of pH 5.0 and 5.010−3 M chloroform solution of the tetradietoxyphosphorylated derivative of heptyl-resorcin[4]arene. Under optimal conditions, competitive solvent extraction of Cr(III), Zn(II), and Cd(II) ions was performed and separation factor values were established as 77.0 and 24.9 for Cr(III)/Cd(II) and Cr(III)/Zn(II) ions pairs, respectively. The stoichiometry of formed metal-ligand complexes 1:1 was found by classical slope analysis method.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 835-844
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Zinc(II) selective removal from other transition metal ions by solvent extraction and transport through polymer inclusion membranes with D2EHPA
    Autorzy:
    Ulewicz, M.
    Walkowiak, W.
    Pośpiech, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/346997.pdf
    Data publikacji:
    2003
    Wydawca:
    Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
    Tematy:
    polymer inclusion membrane
    solvent extraction
    zinc(II)
    cobalt(II)
    nickel(II)
    copper(II)
    cadmium(II)
    Opis:
    An experimental investigation concerns zinc(II), cobalt(II), nickel(II), copper(II) and cadmium(II) ions separation from aqueous chloride solutions by solvent extraction and transport through polymer inclusion membrane (PIM) processes. The selective transport of metal ions from the aqueous chloride source phase through PIM containing cellulose triacetate (support), o-nitrophenyl pentyl ether (plasticizer) and di(2-ethylhexyl)phosphoric acid (ion carrier) is shown. Zn(II) can be effectively removed from dilute aqueous chloride solutions by its transport through PIMs with di(2-ethylhexyl)phosphoric acid as the ionic carriers into 1.0 M HCl as the receiving phase. The transport selectivity of Zn(II) over Co(II), Ni(II), Cu(II) and Cd(II) decreases while the pH of the solution increases in the source phase. Also, by solvent extraction, Zn(II) can be selectively removed from dilute aqueous chloride solutions.
    Źródło:
    Ars Separatoria Acta; 2003, 2; 47-55
    1731-6340
    Pojawia się w:
    Ars Separatoria Acta
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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