Temat: emission fluorescence - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:: Otremba, Z.
Baszanowska, E.
Powiązania:: https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:: 2015
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:: The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:: Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: Fluorescence spectra of oil after it contacts with aquatic environment
Autorzy:: Baszanowska, E.
Otremba, Z.
Toczek, H.
Rohde, P.
Powiązania:: https://bibliotekanauki.pl/articles/245054.pdf
Data publikacji:: 2013
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
fluorescence spectroscopy
excitation-emission spectra
seawater
environment protection
Opis:: The main task for natural marine environment protection is to prevent the inflow of various contaminants including oil substances and the real challenge is the ability to rapidly detect these pollutants. Moreover important is to find the source or the maker of the oil spill. In this paper, we consider fundamental physical aspects in the area of possibility of monitoring the natural marine ecosystem based on fluorescence spectroscopy. We utilize the fluorescence ability of numerous oil components – mainly polycyclic hydrocarbons. The paper concerns the spectrofluorimetric characterization of oils have been in use during exploitation of the marine fleet, i.e. lubricate oil, fuels, transformer and hydraulic oils as well as crude oils or their residues. Every kind of oil has a chance to enter the marine environment, especially in a case of ship emergency or after collision with other vessel ore shoreline structure as well as when ship enters the stranding. After discharge of oil, some of oil components are dissolved in the water, bacteria or photochemical reactions, which results in transformation of composition of oil, degrade some. Fluorescence spectrometer Perkin Elmer LS55 was applied to obtain the fluorescence spectra using different excitation wavelength in the range from 240 nm to 500 nm. We discuss the changes of the shapes of excitationemission spectra (EEMs) of various types of oil and the EEMs spectra after contact of oil with seawater as an oil-inwater emulsion, which is the most frequent form of oil in the water column. Significant changes in the shape of spectra and displacement of the peaks are observed.
Źródło:: Journal of KONES; 2013, 20, 3; 29-34
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 3.

Tytuł:: Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:: 2018
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:: Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:: Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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