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Wyświetlanie 1-7 z 7
Tytuł:
Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:
Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:
Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ship as a source of the sea pollution with oil
Autorzy:
Stelmaszewski, A.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247988.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
maritime transport
seawater
petroleum
environmental protection
Gulf of Gdansk
Opis:
The subject of marine vessel as a source of the sea pollution was taken because of very adverse impact of petroleum pollutants on the natural environment. Oil pollutions concern especially marine environment. However, petroleum inflows to the sea from many different sources, exploitation of the fleet are one of the significant causes of oil presence in the marine environment. MARPOL Convention requires the states parties thereto to monitor the state of contamination [3] and this is a second reason of taking this subject. During the past years, several tests of petroleum content in the Gulf of Gdansk were made by the Physics Department of Gdynia Maritime University. In total 115 samples of water were collected and analyzed during the period from 2004 to 2009 year in the Gulf of Gdansk, which is an area of intense ships traffic because of two great complexes of harbours located in Gdansk and in Gdynia. These tests were carried out with the help of Institute of Oceanology Polish Academy of Sciences during cruises of the r.v. “Oceania”. Petroleum concentration in seawater was determined by means of improved fluorescence method. Oil in water concentration ranged from value below of the detection limit, that is 10–9 (less than 1 ppb), up to 3.5ź10–7 (350 ppb). Average concentration of oil was 4.3ź10–8 (43 ppb). Obtained results confirmed that Vistula River could be a source of petroleum pollution of the Gulf of Gdansk. Apart from this, vessels are the significant sources of oil in the seawater too. The most polluted places were founded in the area where ships crossed the Gulf of Gdansk.
Źródło:
Journal of KONES; 2012, 19, 1; 385-389
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fluorescence of natural seawater exposed to oil pollution
Autorzy:
Otremba, Z.
Baszanowska, E.
Powiązania:
https://bibliotekanauki.pl/articles/245422.pdf
Data publikacji:
2015
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine fleet exploitation
seawater
oil pollution
fluorescence spectroscopy
Opis:
The natural seawater contains both dissolved and suspended organic substances originating from natural sources and human activities – like the marine transport fleet among other. To specify the type and quantity of vitally valid as well as dangerous for properly functioning marine ecosystems substances complicated and sophisticated chemical instrumentation and methodologies must be used. Only a small number of seawater components it is possible easily to determine their concentrations – for example, the salt content is determined directly in the bulk of water through simultaneous measurement of electrolytic conductivity and temperature of water. It is worth to search similarly quick method for oil substances directly in the seawater. Taking into account seawater organic pollutants originating from natural sources inter alia crude oils, the presence of refinery petroleum substances due to their fluorescence in ultra-violet light can be determined based on fluorescence spectroscopy. The aim of this paper is to search fluorescence features of oil substances dissolved in natural seawater based on excitation-emission spectroscopy. In the paper fresh and oily contaminated seawater taken from the coastal area of the Baltic Sea were used. As an oil pollution ‘Petro-baltic’ oil were applied. The natural seawater, at first was laboratory exposed to low extremely amount of oil and then it was examined by fluorescence under UV light. The seawater from vicinity of Gdynia (Poland) were tested as fresh and after artificially contaminated by different amount of oil (from 0.5 to 500 ppm). Spectrofluorometer Hitachi F-7000 FL was applied to measure excitation-emission spectra (EEMs). Low amounts of oil (up to several ppm) cause increasing of main peak in excitation-emission spectra (EEMs). Addition of larger amounts of oil results in appearance new peaks, which originate from fluorescence of soluble fractions of oil artificially added to examined water. These specific features of oil describe the spectroscopic signatures of oil, which is the basis to development operational method of the source of oil pollution identification.
Źródło:
Journal of KONES; 2015, 22, 3; 181-186
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oil residuals in the sea : comparison its optical features with optical properties of the seawater
Autorzy:
Freda, W.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/248105.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine transport
oil slicks
seawater
inherent optical features
sea surface imaging
Opis:
Growing intensity of marine transport results in the increase of the amount of oil pollution released into the sea water. The presence of oil in the sea, which is thought to have come from accidental spills or tanker disaster, is connected mainly with the daily operation of marine engines. Pollution from ships engines, can reach the sea water masses together with ballast or bilge water as the result of human error or a failure of marine equipment. This paper is focused on a comparison of the optical properties of marine waters and oil substances. These include the spectra of absorption coefficient, spectra of scattering coefficient and scattering phase-function (for different wavelength) which describes an angular distribution of scattered light intensity in the sea water. The light scattering phase function depends on the water constituents like mineral suspensions, zooplankton and phytoplankton cells, gas bubbles or so-called yellow substances as well as oil droplets of water pollution. Detection of oil substances in the sea can be effective when it is done remotely, from ships, buoys, inshore or offshore towers, the decks of aircraft or satellites. The knowledge of the listed above properties of natural (clean) seawater is necessary, because they determine the field of light coming out from the sea and allow interpret images of sea surface from point of view of crude oil and the petroleum products detection. In this study we also discuss optical contrast of oil residuals in the sea in various sea regions.
Źródło:
Journal of KONES; 2012, 19, 1; 99-103
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:
Otremba, Z.
Baszanowska, E.
Powiązania:
https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:
2015
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:
The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:
Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fluorescence spectra of oil after it contacts with aquatic environment
Autorzy:
Baszanowska, E.
Otremba, Z.
Toczek, H.
Rohde, P.
Powiązania:
https://bibliotekanauki.pl/articles/245054.pdf
Data publikacji:
2013
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
fluorescence spectroscopy
excitation-emission spectra
seawater
environment protection
Opis:
The main task for natural marine environment protection is to prevent the inflow of various contaminants including oil substances and the real challenge is the ability to rapidly detect these pollutants. Moreover important is to find the source or the maker of the oil spill. In this paper, we consider fundamental physical aspects in the area of possibility of monitoring the natural marine ecosystem based on fluorescence spectroscopy. We utilize the fluorescence ability of numerous oil components – mainly polycyclic hydrocarbons. The paper concerns the spectrofluorimetric characterization of oils have been in use during exploitation of the marine fleet, i.e. lubricate oil, fuels, transformer and hydraulic oils as well as crude oils or their residues. Every kind of oil has a chance to enter the marine environment, especially in a case of ship emergency or after collision with other vessel ore shoreline structure as well as when ship enters the stranding. After discharge of oil, some of oil components are dissolved in the water, bacteria or photochemical reactions, which results in transformation of composition of oil, degrade some. Fluorescence spectrometer Perkin Elmer LS55 was applied to obtain the fluorescence spectra using different excitation wavelength in the range from 240 nm to 500 nm. We discuss the changes of the shapes of excitationemission spectra (EEMs) of various types of oil and the EEMs spectra after contact of oil with seawater as an oil-inwater emulsion, which is the most frequent form of oil in the water column. Significant changes in the shape of spectra and displacement of the peaks are observed.
Źródło:
Journal of KONES; 2013, 20, 3; 29-34
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Test of the suitability of chosen materials in terms of their use for removing oil spillage from the water environment
Autorzy:
Guźlińska, E.
Kończewicz, W.
Otremba, Z.
Trojnar, D.
Powiązania:
https://bibliotekanauki.pl/articles/241568.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
sorbents
fuel
seawater
maritime engineering
environmental protection
Opis:
The paper presents the study about impregnability of various loose materials dedicated as the fillers of oil absorbent socks and booms. Purpose of the survey was finding the material, which is characterized with the smallest hygroscopicity and the highest absorptivity towards typical fuels used in the marine techniques. The cause of take up the topic is the fact, that the contamination of sea areas with petroleum substances are unfortunately very often, are dangerous for natural environment and first of all are so hard to remove from the sea surface. The natural, mineral and synthetic sorbents were studied under laboratory conditions. Samples of the ten kinds of sorbent, each of 2 grams, were treated with the same amount of the diesel fuel, heavy fuel oil and the sea water also, each time in the same period-time (5 minutes). In order to determine the reliability of the results the authors carried out the test fivefold for the one of searched sorbents (recognized as the most hydrophobic-oleophilic substance). The results are presented in graphical form, based on which we are able to select sorbent that fulfils the greatest extent of required expectations. The results of performed tests show that the method that was described in the paper could be used to test the suitability of various materials for the production of devices for collecting the oil film from the surface of the water.
Źródło:
Journal of KONES; 2016, 23, 3; 171-176
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-7 z 7

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