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Wyświetlanie 1-3 z 3
Tytuł:
The effect of Pt active coating application inside diesel engine on polycyclic aromatic hydrocarbons (PAHS) emission
Autorzy:
Janicka, A
Walkowiak, W.
Szczepaniak, W.
Powiązania:
https://bibliotekanauki.pl/articles/244056.pdf
Data publikacji:
2008
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
active coating
catalyst
polycyclic aromatic hydrocarbons
diesel engine
Opis:
Application of active coating inside of an self-ignition engine may have an important impact on several stages of combustion process: fuel cracking, fore-flame phase, combustion phase and secondary combustion phase [7]. Investigations of such construction are very rare in the literature - especially of hydrocarbons emission. Polycyclic aromatic hydrocarbons (PAHs) are known to have mutagenic and carcinogenic effect on humans [2, 6, 7]. One of the most important anthropogenic sources of these substances is motorization (especially diesel engines). The paper presents results of measurements of PAHs emissions from SB3.1 self-ignition engine with Pt active coating application inside. The catalyst was applied on engine valves surface. Zirconium ceramic was chosen as a coating for catalyst application (also because of its thermo-insulating properties). Because of unstable parameters of self-ignition engine work (pressure and temperature jumps), PAHs were extracted from two phases: gas phase and solid phase (particle matter - PM). A chromatographic method of PAHs identification and analysis, because of their low level of concentration in exhaust gases, needed to be supported by sample purification and enrichment stages [40]. It has been found that a significant decrease of total toxic polycyclic aromatic hydrocarbons concentration in engine exhaust gases for engine with Pt catalyst application. The catalyst application causes also changes in relative concentrations of polycyclic aromatic hydrocarbons.
Źródło:
Journal of KONES; 2008, 15, 2; 131-136
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of Pt internal catalyst on relative carcinogenic coefficient (RCC) of polycyclic aromatic hydrocarbons (PAHs) emitted from diesel engine
Autorzy:
Janicka, A.
Walkowiak, W.
Szczepaniak, W.
Powiązania:
https://bibliotekanauki.pl/articles/247594.pdf
Data publikacji:
2008
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
internal catalyst
polycyclic aromatic hydrocarbons
relative carcinogenic coefficient
diesel engine
Opis:
One of the main anthropogenic sources of PAHs emission is motorization, especially compression ignition engines. The researches of International Agency for Research on Cancer (IARC) proved that some compounds from polycyclic aromatic hydrocarbons group are toxic for live organisms and cause damages of adrenal glands, lymphatic, circulation and respiratory systems. Because of carcinogenic properties and common occurrence in human environment benzo(a)pirene has been accepted as polycyclic aromatic hydrocarbons indicator. In relation to benzo(a)pirene, Nisbet and LaGoy determined relative carcinogenic coefficients (RCC) for individual polycyclic aromatic hydrocarbons. The paper presents results of analysis of PAHs RCC emitted from SB3.1 self-ignition engine with Pt active coating application inside. The catalyst was applied on engine valves surface. Zirconium ceramic was chosen as a coating for catalyst application (also because of its thermo-isolating properties). Because of unstable parameters of self-ignition engine work (pressure and temperature jumps), PAHs were extracted from two phases: gas phase and solid phase (particle matter - PM). A chromatographic method of polycyclic aromatic hydrocarbons identification and analysis, because of their low level of concentration in exhaust gases, needed to be supported by sample purification and enrichment stages. It has been found that implementation of catalytic coating on valves of the engine causes decrease of polycyclic aromatic hydrocarbons concentration in exhaust gases, what results in decrease (in most cases) of the sum of relative carcinogenic coefficient of polycyclic aromatic hydrocarbons.
Źródło:
Journal of KONES; 2008, 15, 3; 209-213
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Toxicity of polycyclic aromatic hydrocarbons (PAHs) in diesel exhausts
Autorzy:
Janicka, A.
Walkowiak, W.
Tkaczyk, M.
Czarny, A.
Zaczyńska, E.
Powiązania:
https://bibliotekanauki.pl/articles/245718.pdf
Data publikacji:
2009
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
polycyclic aromatic hydrocarbons
exhaust toxicity
Opis:
The paper presents results of analysis of Polycyclic Aromatic Hydrocarbons (PAHs) concentration and toxicity emitted from 1,9 TDI self-ignition. Because of unstable parameters of self-ignition engine work (pressure and temperature jumps), PAHs were extracted from two phases: gas phase and solid phase (particle matter - PM). A chromatographic method (Capillary gas Chromatography) of polycyclic aromatic hydrocarbons identification and analysis, because of their low level of concentration in exhaust gases, needed to be supported by sample purification and enrichment stages. Calibration of the chromatograph was made by attested mixture of 16 model samples (according to EPA, USA). Two different methods for toxicity estimation was used in this researches. The authors used relative carcinogenic coefficients (RCC) which was determined by Nisbet and LaGoy for individual polycyclic aromatic hydrocarbons in relation to benzo(a)pirene. Samples consist PAHs was also tested for cytotoxicity in standardized cell-culture system (human cell line A549, mouse fibroblasts line cell L929). Cell growth, cell morphology and cell viability were used as parameters to determine the cytotoxicity of the materials. The measure the lethality effect on cells was determined spectrophotometrically with the use of a mitochondrial enzyme activity assay for mitochondrial succinate dehydrogenase activity by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT assay). Cells were exposed to the biomaterials for 24, 72 and 120 h. The results of in vitro tests are discussible. A lach of correlation between toxicity measurement methods which was used in these researches was observed.
Źródło:
Journal of KONES; 2009, 16, 4; 195-199
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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