Autor: Zapała, W. - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Modeling of the influence of the modifier concentration on the retention process in NP-HPLC
Autorzy:: Zapała, W.
Powiązania:: https://bibliotekanauki.pl/articles/778255.pdf
Data publikacji:: 2008
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: NP-HPLC
model retencji
faza ruchoma
retention models
mobile phase composition
Opis:: The adsorption model for an accurate prediction of the analyte retention in the normal - phase liquid chromatography with a binary mobile phase has been proposed. This model was derived using a thermodynamically consistent modified competitive Langmuir isotherm. The performance of the proposed equation was compared with two retention models reported in literature. All models were verified for different NP-LC systems by use of three criteria: the sum of squared differences between the experimental and theoretical data, approximation of the standard deviation and the Fisher test.
Źródło:: Polish Journal of Chemical Technology; 2008, 10, 1; 52-56
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: Investigations of selected properties of pharmacologically active compounds by chromatographic and potentiometric methods on the chrysin example
Autorzy:: Pusz, J.
Zapała, W.
Papciak, B.
Powiązania:: https://bibliotekanauki.pl/articles/778249.pdf
Data publikacji:: 2008
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: RP-HPLC
model retencji
chryzyna
stała dysocjacji
retention model
chrysin
dissociation constant
Opis:: The RP-TLC method was used to determine the dissociation constant of chrysin (5,7-dihydroxyflavone) in methanol-aqueous (1:1 v/v) solutions. In this method the pK value was quantified on the basis of retention data and a retention model. The accuracy of determining the model parameters was analysed using the following statistical criteria: the sum of the squared differences between the experimental and theoretical data, approximation of standard deviation, and the Fisher test. Besides, in this work the potentiometric method was used. Investigations were carried out at ionic strength I=0.1 at T= 298 K. The dissociation constant were determined using the Rossotti method as well as the numerical method based on the procedures of non-linear curve fitting using Microsoft Excel Solver and the user-defined function. It has been found that the differences in the evaluated pK values were relatively small and did not exceed 1.2%.
Źródło:: Polish Journal of Chemical Technology; 2008, 10, 1; 41-44
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

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