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Wyświetlanie 1-3 z 3
Tytuł:
Hydrometallurgical recovery of cobalt(ii) from acidic chloride solutions by transport through polymer inclusion membranes
Autorzy:
Pospiech, B.
Powiązania:
https://bibliotekanauki.pl/articles/109755.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cobalt(II)
lithium(I)
Cyanex 301
polymer inclusion membrane
lithium-ion batteries
Opis:
In this work a selective transport of Co(II) and Li(I) ions from acidic chloride solutions through polymer inclusion membranes (PIMs) with Cyanex 301 has been studied. The effect of composition of the polymer membrane has been investigated. The obtained results show that around 98% of Co(II) was transported from the source phase containing 0.01 M Co(II) and 0.01 M Li(I) at pH 4.0 through PIM after 12 h into 3.0 M HCl. The membrane containing 18 wt.% cellulose triacetate (CTA), 32 wt.% Cyanex 301 and 50 wt.% o-nitrophenyl octyl ether (ONPOE) showed very good stability, suggesting that there is a possibility of application of the membrane for Co(II) recovery from acidic leach liquor solutions of spent lithium ion batteries (LIBs).
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 641-649
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synergistic solvent extraction of Co(II) and Li(I) from aqueous chloride solutions with mixture of Cyanex 272 and TBP
Autorzy:
Pospiech, B.
Powiązania:
https://bibliotekanauki.pl/articles/110291.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cobalt(II)
lithium(I)
Cyanex 272
TBP
synergistic extraction
Opis:
In this work, separation of cobalt(II) over lithium(I) ions from aqueous chloride solutions by synergistic solvent extraction (SX) has been studied. A synergistic mixture of commercial extractants such as bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272) and tributyl phosphate (TBP) in kerosene was used as a selective extractant. The investigations were first performed to select optimal conditions for the effective separation including pH of the aqueous phase as well as concentration of synergistic mixture. High selective solvent extraction of cobalt(II) over lithium(I) from chloride solution has been achieved by the mixture of 0.1 M Cyanex 272 and 0.05 M TBP in kerosene while efficient Co(II) stripping has been performed by 0.5 M sulphuric acid.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 353-364
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective recovery of cobalt(II) towards lithium(I) from chloride media by transport across polymer inclusion membrane with triisooctylamine
Autorzy:
Pospiech, B.
Powiązania:
https://bibliotekanauki.pl/articles/779968.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
cobalt(II)
lithium(I)
triisooctylamine
polymer inclusion membrane
PIM
lithium-ion batteries
LIBs
solvent extraction
Opis:
In this work the selective transport of cobalt(II) and lithium(I) ions from aqueous chloride solutions through polymer inclusion membranes (PIMs) is presented. Triisooctylamine (TIOA) has been applied as the ion carrier in membrane. The effects of various parameters on the transport of Co(II) and Li(I) were studied. The obtained results show that Co(II) ions were effectively removed from source phase through PIM containing 32 wt.% TIOA, 22 wt.% CTA (cellulose triacetate) and 46 wt.% ONPOE (o-nitrophenyl octyl ether) or ONPPE (o-nitrophenyl pentyl ether) into deionized water as the receiving phase. The results indicate that there is a possibility of polymer inclusion membranes application to recover Co(II) and Li(I) from aqueous chloride solutions.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 15-20
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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