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Wyszukujesz frazę "chemical kinetics" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Regularities of Crystallization Heat Release During Solidification of Alloyed Cast Irons
Autorzy:
Aftandiliants, Y.
Gnyloskurenko, S.
Meniailo, H.
Khrychikov, V.
Lomakin, V.
Powiązania:
https://bibliotekanauki.pl/articles/27314122.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
alloying
cast irons
crystallization
kinetics of crystallization
chemical composition
stopowanie
żeliwo
krystalizacja
kinetyka krystalizacji
skład chemiczny
właściwości
Opis:
The chemical composition of alloys plays an important role at their crystallization and influences the solid phase formation, and thus, microstructure and properties. The present paper studies the release of the heat of crystallization of alloyed wear-resistant cast irons in order to determine the quantitative patterns of the chemical composition influence to the kinetics of crystallization. The differential thermal analysis was applied to get the data of heat release, its rate at cast iron temperature decrease. The normalized dependence of the amount of crystallization heat over time was obtained. The main temperature parameters were analyzed and four stages at irons crystallization were established and characterized with their duration and released heat. The multiple correlation analysis allowed considering a numerous physical and chemical factors and distinguishing their role at crystallization of irons. As a result, the quantitative regularities are determined of influencing the content of alloying elements, impurities and carbides on a heat and time of crystallization at the different stages of solidification, which are of great importance in developing alloyed irons with required quality and properties.
Źródło:
Archives of Foundry Engineering; 2023, 23, 1; 110--117
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of the continuous reaction crystallization of barium sulphate in BaCl2 - (NH4)2SO4 - NaCl - H2O system - neural network model
Autorzy:
Piotrowski, K.
Koralewska, J.
Wierzbowska, B.
Matynia, A.
Powiązania:
https://bibliotekanauki.pl/articles/778848.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
siarczan baru
jony sodu
sole pohartownicze
hartowanie stali
chlorek baru
kinetyka krystalizacji
barium sulphate
sodium ions
used quenching salts
steel hardening
barium chloride
reaction crystallization kinetics
population density distribution
chemical neutralization
solid waste utilization
neural network model
Opis:
One of the main toxic components of post quenching salts formed in large quantities during steel hardening processes is BaCl2. This dangerous ingredient can be chemically neutralized after dissolution in water by means of reaction crystallization with solid ammonium sulphate (NH4)2SO4. The resulting size distribution of the ecologically harmless crystalline product - BaSO4 - is an important criteria deciding about its further applicability. Presence of a second component of binary quenching salt mixture (BaCl2-NaCl) in water solution, NaCl, influences the reaction-crystallization process kinetics affecting the resulting product properties. The experimental 39 input-output data vectors containing the information about the continuous reaction crystallization in BaCl2 - (NH4)2SO4 - NaCl - H2O system ([BaCl2]RM = 10-24 mass %, [NaCl]RM = 0-12 mass %, T = 305-348 K and τ = 900-9000 s) created the database for the neural network training and validation. The applicability of diversified network configurations, neuron types and training strategies were verified. An optimal network structure was used for the process modeling.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 4; 13-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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