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Wyświetlanie 1-2 z 2
Tytuł:
An Insensitive Booster Explosive: DAAF Surface-coated with Viton A
Autorzy:
Li, X.
Wu, B.
Liu, S.
An, C.
Wang, J.
Powiązania:
https://bibliotekanauki.pl/articles/358841.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
DAAF
refinement
surface-coated
thermal analysis
impact sensitivity
Opis:
3,3’-Diamino-4,4’-azoxyfurazan (DAAF) is the principal component of an insensitive booster explosive; refined DAAF and DAAF surface-coated with Viton A were prepared. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and differential scanning calorimetry (DSC) were employed to characterize the morphology, composition, and thermal decomposition of these samples. The impact sensitivity and theoretical detonation velocity of DAAF-based composites were also measured and analyzed. The results showed that DAAF surface-coated with Viton A was successfully obtained, and the impact sensitivity of DAAF/Viton A composites was much lower than that of crude DAAF. In addition, DAAF/Viton A composites exhibited better thermal stability compared to crude DAAF and refined DAAF. The theoretical detonation velocity of DAAF/Viton A composites and TATB/Viton A composites are roughly the same. Therefore, there is still great potential for DAAF to be used as the main explosive component of a booster explosive.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 445-455
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantum Chemical Study of Aminonitrocyclopentanes as Possible High Energy Density Materials (HEDMs)
Autorzy:
Bai, J.
Chi, W. J.
Li, L. L.
Yan, T.
Wen, X. E.
Li, B. T.
Wu, H. S.
Ma, F. L.
Powiązania:
https://bibliotekanauki.pl/articles/358101.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
cyclopentane derivatives
high energy density materials
impact sensitivity
quantum chemistry
DFT
available free space
Opis:
Nitro and amine groups were introduced into the cyclopentane skeleton, and the heats of formation, detonation performance, bond dissociation energies, and impact sensitivity for these aminonitrocyclopentanes were calculated in detail at the B3LYP/6-311G** level. The results show that all of the derivatives have negative heats of formation, which are influenced by the position of the substituent groups. Their stabilities were estimated and analyzed according to their bond dissociation energies and calculated characteristic H50 values. Most of the compounds were found to have a lower impact sensitivity than HMX. Furthermore, the detonation velocities and detonation pressures were predicted via the Kamlet-Jacobs equation. Of all these aminonitrocyclopentanes, E has the best detonation properties (ρ = 2.05 g/cm3, D = 9.11 m/s, P = 39.62 GPa) and can be considered as a candidate high energy density material.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 4; 467-480
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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