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Wyświetlanie 1-2 z 2
Tytuł:
Studies on Sensitivity of Nitrate Ester Plasticized Hydroxyl Terminated Prepolymer Based Energetic Solid Rocket Propellants
Autorzy:
Bhowmik, D.
Sadavarte, V. S.
Charbhe, V. D.
Pande, S. M.
Powiązania:
https://bibliotekanauki.pl/articles/358663.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
sensitivity
impact
friction
card gap test
DDT test
SLSG test
Opis:
The sensitivities of energetic materials as well as advanced energetic solid propellants are invariably associated with the nature of the stimuli that are responsible for the initiation of their decomposition. Hence it is important to study the chemical processes involved with these decompositions. While assessing the potential application of new propellant formulations containing energetic materials, it is important to assess their sensitivity to the hazards involved during their handling, transport, storage and use. This paper reports the results of impact, friction, heat, spark and shock sensitivities of advanced high energy solid rocket propellant formulations based on nitrate ester plasticized, hydroxyl terminated prepolymer (SPB-255) as an energetic binder loaded with solid ingredients like ammonium perchlorate (AP), aluminium (Al) and cyclotetramethylenetetranitramine (HMX). The results of the small card gap test showed that they are more sensitive than a composite modified double base (CMDB) propellant, which in turn is more sensitive than double base (DB) as well as composite propellants. Deflagration to detonation transition (DDT) tests carried out for the advanced energetic propellant did not show any detonation phenomena. Trinitrotoluene (TNT) equivalence and super large scale gap (SLSG) tests have been carried out for the determination of hazard classification of the energetic solid rocket propellant. The requirements to achieve both higher performance in terms of improved energy (i.e., specific impulse, Isp) and reduced sensitivity for the same propellant composition are contradictory; one should be sacrificed for the other, within manageable limits.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 3; 605-620
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Concerning the shock sensitivity of cyclic nitramines incorporated into a polyisobutylene matrix
Autorzy:
Pelikán, W.
Zeman, S.
Yan, Q. L.
Erben, M.
Elbeih, A.
Akštein, Z.
Powiązania:
https://bibliotekanauki.pl/articles/358036.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
BCHMX
β-HMX
RDX
ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
CL-20
gap test
impact
Opis:
Two types of plastic bonded explosives (PBXs) based on ε-2,4,6,8,10,12hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (ε-HNIW, CL-20), and PBXs based on 1,3,5-trinitro-1,3,5-triazinane (RDX), β-1,3,4,7-tetranitro-1,3,5,7-tetrazocane (β-HMX) and cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole (bicycloHMX, BCHMX) were prepared using a polyisobutylene binder with dioctylsebacate (DOS) as plasticizer, i.e. a C4 matrix. One version of the ε-HNIW PBX is a product with reduced sensitivity (RS-ε-HNIW). All these PBXs, referenced respectively as RS-ε-HNIW-C4, ε-HNIW-C4, RDX-C4, HMX-C4 and BCHMX-C4, were tested using the Small Scale Gap Test according to STANAG 4488. The results of the gap test on the PBXs with RDX, β-HMX and BCHMX correspond to the impact sensitivities of the original crystalline nitramines. This is not entirely valid for ε-HNIW. In other words, PBXs with RS-ε-HNIW cannot achieve as low a shock sensitivity as would be expected from the differences obtained from the impact sensitivities between RDX, β-HMX and BCHMX, on the one hand, and RS-εHNIW on the other. It is shown that the morphological stability of RS-ε-HNIW in the C4 matrix is insufficient. However, further development and use of RS-ε-HNIW as a filler of PBXs would seem to be both desirable and beneficial. Despite the relatively high impact sensitivity of crystalline BCHMX, the shock sensitivity of its analogous C4 PBX is already good, and comparable with that of RS-ε-HNIW.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 2; 219-235
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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