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Tytuł:
Hydrogen peroxide as a biodegradation stimulator in remediation processes of soils heavily contaminated with petrochemicals
Autorzy:
Rosik-Dulewska, C.
Krzyśko-Łupicka, T.
Ciesielczuk, T.
Kręcidło, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/778974.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
soil
remediation
petrochemicals
hydrogen peroxide
Opis:
The soil contaminated with petroleum products must be excluded from the crops and treated to reclamation processes. Natural processes of decomposition of hydrocarbon compounds go very slow, so it is necessary to use bioaugumentation or stimulation in order to accelerate the return of the soil to high culture. In this study the effect of hydrogen peroxide on the process of cleaning soil strongly contaminated with pertochemicals was investigated. For this purpose, a pot experiment lasting 60 days was carried. The dynamics of changes in the population of filamentous fungi, yeasts and bacteria were examined and also content of aliphatic hydrocarbons (n-alkanes), monoaromatic and polycyclic aromatic hydrocarbons (PAHs). Experimental use of hydrogen peroxide in the process of biodegradation of petroleum compounds assisted in the analyzed soil led to an increase of the number of grampositive bacteria during the test. Stimulation of oil products biodegradation by hydrogen peroxide also increased by 35% decomposition efficiency of aliphatic hydrocarbons (C8-C40) and about 50% PAH’s in comparison to control samples without hydrogen peroxide. There was no influence of hydrogen peroxide on the content of monoaromatic hydrocarbons (BTEX) with respect to controls, although in the end of experiment, the total concentration decreased by about 50% compared to the initial content.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 17-22
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts
Autorzy:
Wróblewska, A.
Makuch, E.
Miądlicki, P.
Powiązania:
https://bibliotekanauki.pl/articles/779024.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
limonene oxidation
hydrogen peroxide
TBHP
Opis:
This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta, Ti-MCM-41 and Ti-MWW catalysts, at the autogenic pressure and atmospheric pressure. The examination were performed at the following conditions: the temperature of 140°C (studies in the autoclave) and 80°C (studies in glass reactor), the molar ratio of limonene/oxidant (H2O2 or WNTB) = 1:1, the methanol concentration 80 wt%, the catalyst content 3 wt%, the reaction time 3 h and the intensity of stirring 500 rpm. The analysis of the results showed that in process not only 1,2-epoxylimonene was formed but also: 1,2-epoxylimonene diol, carveol, carvone and perillyl alcohol but for 1,2-epoxylimonene obtaining the better method was the method at the autogenic pressure and in the presence of TBHP.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 4; 82-87
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Combined treatment of toxic cyanobacteria Microcystis aeruginosa with hydrogen peroxide and microcystin biodegradation agents results in quick toxin elimination
Autorzy:
Dziga, Dariusz
Maksylewicz, Anna
Maroszek, Magdalena
Marek, Sylwia
Powiązania:
https://bibliotekanauki.pl/articles/1038535.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
cyanobacteria
microcystins
hydrogen peroxide
microcystinase
Sphingomonas
Opis:
Under some conditions the growth of toxic cyanobacteria must be controlled by treatment with algicidal compounds. Hydrogen peroxide has been proposed as an efficient and relatively safe chemical which can remove cyanobacteria from the environment selectively, without affecting other microorganisms. However, the uncontrolled release of secondary metabolites, including toxins may occur after such a treatment. Our proposal presented in this paper concerns fast biodegradation of microcystin released after cell lysis induced by hydrogen peroxide. The effectiveness of both, Sphingomonas sp. and heterologously expressed MlrA enzyme, in the removal of the toxin from Microcystis aeruginosa culture was investigated. The results indicate that neither Sphingomonas cells nor MlrA are affected by hydrogen peroxide at the concentrations which stop the growth of cyanobacteria. A several-fold reduction in microcystin levels was documented in the presence of these agents with biodegradation ability. Our results provide evidence that such a combined treatment of water reservoirs dominated by microcystin-producing cyanobacteria may be a promising alternative which allows fast elimination of both, the bloom forming species and toxins, from the environment.
Źródło:
Acta Biochimica Polonica; 2018, 65, 1; 133-140
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Labile iron pool correlates with iron content in the nucleus and the formation of oxidative DNA damage in mouse lymphoma L5178Y cell lines.
Autorzy:
Kruszewski, Marcin
Iwaneńko, Teresa
Powiązania:
https://bibliotekanauki.pl/articles/1043668.pdf
Data publikacji:
2003
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
iron homeostasis
hydrogen peroxide
comet assay
Opis:
Labile iron pool (LIP) constitutes a crossroad of metabolic pathways of iron-containing compounds and is midway between the cellular need for iron, its uptake and storage. In this study we investigated oxidative DNA damage in relation to the labile iron pool in a pair of mouse lymphoma L5178Y (LY) sublines (LY-R and LY-S) differing in sensitivity to hydrogen peroxide. The LY-R cells, which are hydrogen peroxide-sensitive, contain 3 times more labile iron than the hydrogen peroxide-resistant LY-S cells. Using the comet assay, we compared total DNA breakage in the studied cell lines treated with hydrogen peroxide (25 μM for 30 min at 4°C). More DNA damage was found in LY-R cells than in LY-S cells. We also compared the levels of DNA lesions sensitive to specific DNA repair enzymes in both cell lines treated with H2O2. The levels of endonuclease III-sensitive sites and Fapy-DNA glycosylase-sensitive sites were found to be higher in LY-R cells than in LY-S cells. Our data suggest that the sensitivity of LY-R cells to H2O2 is partially caused by the higher yield of oxidative DNA damage, as compared to that in LY-S cells. The critical factor appears to be the availability of transition metal ions that take part in the OH radical-generating Fenton reaction (very likely in the form of LIP).
Źródło:
Acta Biochimica Polonica; 2003, 50, 1; 211-215
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching of chalcopyrite concentrate in hydrogen peroxide solution
Autorzy:
Agacayak, T.
Aras, A.
Aydogan, S.
Erdemoglu, M.
Powiązania:
https://bibliotekanauki.pl/articles/110645.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chalcopyrite
dissolution
hydrogen peroxide
leaching
extraction
Opis:
The leaching conditions of chalcopyrite (CuFeS2) concentrate in a hydrogen peroxide medium were investigated by studying the effects of its leaching parameters, such as stirring speed, temperature, hydrogen peroxide concentration and the particle size of the concentrate on Cu extraction. It was found that stirring speed has no effect on the leaching. Copper extraction from chalcopyrite is directly proportional to hydrogen peroxide concentration, but the extraction decreases at temperatures above 60°C. The maximum copper extraction was obtained with the following conditions without stirring: 240 min of leaching time, 3.0 M hydrogen peroxide concentration, 40°C leaching temperature and 53-75 m particle size fraction.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 657-666
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Technological parameters of epoxidation of sesame oil with performic acid
Autorzy:
Musik, M.
Milchert, E.
Malarczyk-Matusiak, K.
Powiązania:
https://bibliotekanauki.pl/articles/778421.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
sesame oil
epoxidation
performic acid
hydrogen peroxide
Opis:
The course of epoxidation of sesame oil (SO) with performic acid formed „in situ” by the reaction of 30 wt% hydrogen peroxide and formic acid in the presence of sulfuric acid(VI) as a catalyst was studied. The most advantageous of the technological independent parameters of epoxidation are as follows: temperature 80°C, H2O2  C=C 3.5:1, HCOOH/C=C 0.8:1, amount of catalyst as H2SO4 /(H2O2 +HCOOH) 1 wt%, stirring speed at least 700 rpm, reaction time 6 h. The iodine number (IN), epoxy number (EN), a relative conversion to oxirane (RCO) and oxirane oxygen content (EOe) were determined every hour during the reaction. Under optimal conditions the sesame oil conversion amounted to 90.7%, the selectivity of transformation to epoxidized sesame oil was equal to 93.2%, EN = 0.34 mol/100 g, IN = 0.04 mol/100 g oil (10.2 g/100 g oil), a relative conversion to oxirane RCO = 84.6%, and oxirane oxygen content of EOe = 5.5%.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 3; 53-59
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Basic energetic parameters of Acanthamoeba castellanii mitochondria and their resistance to oxidative stress
Autorzy:
Jarmuszkiewicz, Wieslawa
Antos-Krzeminska, Nina
Drachal-Chrul, Danuta
Matkovic, Karolina
Nobik, Wioletta
Pieńkowska, Joanna
Swida, Aleksandra
Woyda-Ploszczyca, Andrzej
Budzinska, Malgorzata
Powiązania:
https://bibliotekanauki.pl/articles/1040753.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
Acanthamoeba castellanii
mitochondria
hydrogen peroxide
oxidative stress
Opis:
The purpose of this study was establishing the basic energetic parameters of amoeba Acanthamoeba castellanii mitochondria respiring with malate and their response to oxidative stress caused by hydrogen peroxide in the presence of Fe2+ ions. It appeared that, contrary to a previous report (Trocha LK, Stobienia O (2007) Acta Biochim Polon 54: 797), H2O2-treated mitochondria of A. castellanii did not display any substantial impairment. No marked changes in cytochrome pathway activity were found, as in the presence of an inhibitor of alternative oxidase no effects were observed on the rates of uncoupled and phosphorylating respiration and on coupling parameters. Only in the absence of the alternative oxidase inhibitor, non-phosphorylating respiration progressively decreased with increasing concentration of H2O2, while the coupling parameters (respiratory control ratio and ADP/O ratio) slightly improved, which may indicate some inactivation of the alternative oxidase. Moreover, our results show no change in membrane potential, Ca2+ uptake and accumulation ability, mitochondrial outer membrane integrity and cytochrome c release for 0.5-25 mM H2O2-treated versus control (H2O2-untreated) mitochondria. These results indicate that short (5 min) incubation of A. castellanii mitochondria with H2O2 in the presence of Fe2+ does not damage their basic energetics.
Źródło:
Acta Biochimica Polonica; 2008, 55, 2; 349-356
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Phosphates and Fluorides, Included in TiO2 Nanotube Layers on the Performance of Hydrogen Peroxide Detection
Autorzy:
Arkusz, K.
Krasicka-Cydzik, E.
Powiązania:
https://bibliotekanauki.pl/articles/354114.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titania nanotubes
thermal modification
biosensor
hydrogen peroxide
Opis:
Titania nanotube (TNT) arrays fabricated by anodizing of titanium foil in organic (ethylene glycol) and inorganic (phosphoric acid) electrolytes and thermally modified in argon revealed much improved properties to detect hydrogen peroxide. Horseradish peroxidase and acetate thionine co-absorbed by a dip coating on the TNT electrode were used to detect hydrogen peroxide in phosphate buffered saline. The morphology and electrochemical properties of TNT arrays were studied by scanning electron microscopy, electrochemical impedance spectroscopy and cyclic voltammetry. Well defined oxidation and reduction peaks for potassium ferricyanide have been observed for TNT formed in ethylene glycol and annealed in argon. TNT arrays formed in organic electrolyte and annealed in argon indicated more favorable adsorption and electrochemical properties what was confirmed by detection of hydrogen peroxide towards analyte in phosphorate buffered saline solution.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 765-772
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrogen Peroxide as a High Energy Compound Optimal for Propulsive Applications
Autorzy:
Rarata, G.
Rokicka, K.
Surmacz, P.
Powiązania:
https://bibliotekanauki.pl/articles/358739.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
hydrogen peroxide
HTP
explosibility
detonability
monopropellant
oxidizer
propulsion
Opis:
This paper presents the authors’ experience in the field of the safe preparation and utilisation of HTP (98%+), a storable propellant that is finding use in various engineering applications. Brief characterisations of the material as well as examples of its potential use within relevant industries are provided. Additionally, some of the existing data and current research are included to demonstrate the full potential of this material which meets most of the needs of the propulsion industry. The laboratory technique for obtaining the substance that has been developed recently at the Institute of Aviation is briefly described. Utilisation of the method based on a special glass apparatus allows reproducible amounts of the substance to be obtained with relatively little risk.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 3; 778-790
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism and leaching kinetics of molybdenite concentrate in a hydrogen peroxide-acid system
Autorzy:
Aracena, Alvaro
Azocar, Alan
Ibáñez, Juan Patricio
Jerez, Oscar
Powiązania:
https://bibliotekanauki.pl/articles/110193.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
molybdenite concentrate
hydrogen peroxide
kinetics
mechanism of reaction
Opis:
The mechanism and leaching kinetics of a molybdenite concentrate in a H2O2-H2SO4 system were studied. The experimental work was performed in a batch reactor equipped with a condenser, a mechanical agitator and a temperature control system. The effects of the temperature, H2O2 and H2SO4 concentrations, particle size, liquid/solid ratio and agitation speed on the Mo recovery were investigated. The thermodynamic results showed that the leaching mechanism it was governed by several intermediate reactions; however, the influences of sulfuric acid and passivation were not observed in the reaction. The most predominant experimental result was the maximum Mo recovery of 81.3% by leaching 64 μm particles at 333 K (60 °C) for 5400 s (90 min). The molybdenum recovery was generally enhanced by increasing the H2O2 and H2SO4 concentrations. However, at H2SO4 concentrations higher than 1.0 mol/dm3, the Mo recovery decreased. Although the agitation speed affected the Mo recovery considerably, high recoveries could be still obtained without mixing. The experimental results and XRD analysis confirmed the reaction mechanisms. The leaching kinetics were analyzed using a shrinking core model in which the rate was controlled by diffusion through a porous layer with radius ro. The reaction rate orders were 1.0 and 0.2 for the H2O2 and H2SO4 concentrations, respectively, and the rate was inversely proportional to the square of the initial particle radius. The calculated activation energy was 75.2 kJ/mol in the temperature range of 278-333 K (5-60 °C).
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 140-152
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New insights into pyrite-hydrogen peroxide interactions during froth flotation: experimental and DFT study
Autorzy:
Cao, Qinbo
Yan, Wenchao
Wen, Shuming
Liu, Dianwen
Li, Yanjun
Powiązania:
https://bibliotekanauki.pl/articles/2200334.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydrogen peroxide
oxidization
pyrite flotation
adsorption models
DFT
Opis:
Hydrogen peroxide (H2O2) is an efficient depressant for pyrite (FeS2) flotation. However, the depressing mechanism of H2O2 is not fully understood. In this paper, the depressing capacity of H2O2 for pyrite was examined by flotation tests. Results revealed that pyrite flotation could be inhibited by H2O2 at pH 6.4. The pyrite powder in H2O2 solution enhanced the release of O2 from H2O2. However, the O2 concentration in the solution was less than that of H2O2; thus, H2O2 is the major oxidant in the solution. Moreover, density functional theory calculations were performed to study the interactions between H2O2 and hydrated pyrite (100) surface. The H2O2 molecule tended to react with the pyrite surface to generate one S=O bond and an H2O molecule. The possible binding models of O2 molecules on the pyrite (100) surface were also studied for comparison. The O2 dissociation on the pyrite surface was more favorable than the adsorption of O2 as a whole. In addition, the orbital interaction in the S=O bond raised from the reaction of H2O2/O2 with the pyrite surface was also investigated by the density states analysis. These results provide some insights into the oxidizing effect of H2O2 in pyrite flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 157409
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of spermidine on germination of Salix spp. after storage under controlled conditions
Autorzy:
Wawrzyniak, M.K.
Ley-Lopez, J.M.
Kijowska-Oberc, J.
Chmielarz, P.
Ratajczak, E.
Powiązania:
https://bibliotekanauki.pl/articles/2130180.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
hydrogen peroxide
cryopreservation
spermidine
Salix
antioxidant
seed storage
Opis:
Willows produce fast germinating and short-lived seeds, difficult to store in the long-term under controlled conditions. The aim of this study was to examine the feasibility of storage of three Salix spp. at controlled temperatures (3°, −10°, −196 °C). We also analyzed the effect of spermidine (Spd) as an antioxidant factor in desiccated seeds. Collected seeds were either desiccated or hydrated to obtain 10 levels of moisture content (between app. 4% and 2%) and subjected to storage at temperatures 3°, −10°, or −196 °C (liquid nitrogen; LN). After two months, seeds were germinated on the light at 20 °C. Seeds desiccated below a safe range of moisture content were further tested and germinated on filter paper with additions of 0.25 mM Spd solution. After 7 days seedlings were examined for hydrogen peroxide content (H2O2) and total antioxidant capacity (TAC). Fresh seeds of three Salix species: Persian willow (S. aegyptiaca L.), heartleaf willow (S. cordata Michx.) and crack willow (S. ×fragilis L.) were successfully stored at temperature −10° and −196 °C for two months. After cryopreservation seed of S. aegyptiaca, S. cordata, and S. ×fragilis germinated without viability loss in moisture content ranging from 4.4–15.9%, 6.4–18.5%, and 7.1–11.5% respectively. The addition of Spd during germination of desiccated seed did not affect germination capacity. However, seedlings of S. aegyptiaca had lower hydrogen peroxide content in comparison with control (germination on water). Seedlings of S. cordata showed an increase in hydrogen peroxide content in control after storing in LN. In seedlings of Crack willow Spd increased hydrogen peroxide content. Seeds of tested species differ in response to storage conditions. Salix seeds can be stored successfully for two months at −10° or −196 °C without losing viability in the safe range of moisture content. Storing at 3 °C can be used for storage in the narrower range of seeds’ moisture content, however, seedlings stored at this temperature produce a higher level of reactive oxygen species. Germinating seeds in Spd did not increase their germination, however in S. aegyptiaca and S. cordata decreased hydrogen peroxide content.
Źródło:
Dendrobiology; 2022, 87; 137-148
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxidation of Cyclohexene with H₂O₂ Catalyzed by Vanadium Based Polyoxometalates Doped Modified Clays as Green Catalysts
Autorzy:
Boudjema, S.
Rabah, H.
Choukchou-Braham, A.
Powiązania:
https://bibliotekanauki.pl/articles/1031903.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
heteropolyacids
bentonite
acid catalyst
cyclohexene oxidation
hydrogen peroxide
Opis:
The catalytic performance of supported heteropolyacids in various liquid-solid and gas-solid heterogeneous reactions may be affected by the choice of support and/or the method of heteropolyacid deposition. Vanadium substituted polyphosphomolybdate with the Keggin structure H₄[PVMo₁₁O₄₀]· 13H₂O (PVMo) was dispersed throughout acid activated bentonite (clay from Hammam Boughrara, Maghnia, Algeria). A series of catalysts were prepared via modified impregnation. Modified preparation method employed ultrasonication as a means of the dispersion homogenization, followed by freeze-drying. The catalysts were characterized by the Brunauer-Emmett-Teller, the Fourier transform infrared, and ³¹P solid-state magic angle spinning-NMR spectroscopy. The catalytic performance of PVMo/Hmont was evaluated in the oxidation of cyclohexene. Intact Keggin anions were preserved on Hmont after deposition aided by ultrasonication. The obtained results showed that a better catalytic activity can be obtained with PVMo/bentonite (98% of conversion and 89% of cyclohexene oxide), by drop addition of H₂O₂, for 3 h.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 469-472
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The key role of the redox status in regulation of metabolism in photosynthesizing organisms
Autorzy:
Kornas, Andrzej
Kuźniak, Elżbieta
Ślesak, Ireneusz
Miszalski, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/1040395.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
evolution
chloroplast
ROS
redox status
photosynthesis
hydrogen peroxide
Opis:
The redox status of the cell is described by the ratio of reduced to non-reduced compounds. Redox reactions which determine the redox state are an essential feature of all living beings on Earth. However, the first life forms evolved under strongly anoxic conditions of the young Earth, and the redox status probably was based on iron and sulphur compounds. Nowadays, redox reactions in cells have developed in strict connection to molecular oxygen and its derivatives i.e. reactive oxygen species (ROS). Oxygen has started to accumulate on the Earth due to oxygenic photosynthesis. All aspects of aerobic life involve ROS, reactive nitrogen species (RNS), antioxidants and redox regulation. Many different redox-active compounds are involved in the complex of redox processes, including pyridine nucleotides, thioredoxins, glutaredoxins and other thiol/disulphide-containing proteins. Redox regulation is integrated with the redox-reactions in photosynthesis and respiration to achieve an overall energy balance and to maintain a reduced state necessary for the biosynthetic pathways that are reductive in nature. It underlies the physiological and developmental flexibility in plant response to environmental signals.
Źródło:
Acta Biochimica Polonica; 2010, 57, 2; 143-151
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Measurements of the VOD of Selected Mining Explosives and Novel “Green Explosives” Using the Continuous Method
Autorzy:
Nikolczuk, Karolina
Maranda, Andrzej
Mertuszka, Piotr
Fuławka, Krzysztof
Wilk, Zenon
Koślik, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/357982.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
detonation velocity
emulsion explosives
hydrogen peroxide
MicroTrap™ System
Opis:
Explosive velocity, also known as detonation velocity or velocity of detonation (VOD), is one of the most important and basic parameters describing the properties of explosives. This work presents the VOD results of three different explosives. Two of the explosives were ammonium nitrate-based (straight emulsion and Heavy ANFO). The third explosive was based on hydrogen peroxide (HP). The aim of the experiments was to compare the VOD of the HP-based against the VOD of the ammonium nitrate-based explosives. The final conclusions and results of this preliminary work and the analysis of available literature show that HP-based explosives, so called “green explosives”, have the potential to successfully replace ammonium nitrate-based explosives in some applications. The results of this work will be used to develop production technology for new HP-based explosives and to find their possible applications, considering their environmentally friendly character (this novel formulation of explosive eliminates post-blast nitrogen oxide fumes (NOx), as a direct product of the detonation process). During the burning reaction, nitrogen oxides (NO, NO2) are produced as a result of the use of bulk ammonium nitrate-based commercial explosives. Exposure to these toxic gases can have negative effects on the health and safety of personnel and the surrounding environment. The results obtained for the new emulsion explosives allow them to be used extensively in the industry as a competitive product on the market.
Źródło:
Central European Journal of Energetic Materials; 2019, 16, 3; 468-481
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
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