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Tytuł:
Controllable preparation of highly active horseradish peroxidase-gold nanoparticle bionanoconjugate
Autorzy:
Zhang, P.
Liu, Ch.
Song, S.
Peng, Ch.
Powiązania:
https://bibliotekanauki.pl/articles/778931.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
horseradish peroxidase
gold nanoparticles
bionanoconjugate
Opis:
A novel method of immobilizing horse radish peroxidase enzyme (HRP) onto the surface of gold nanoparticles (GNPs) was developed. As a result, a high-activity bionanoconjugates was obtained through utilizing the biotin-streptavidin (SA) system. The HRP-SA-GNP bionanoconjugate with high activity was conveniently prepared through the biotin- avidin system. Compared with the HRP-GNP bioconjugate prepared through the traditional electrostatic absorption method, the enzyme activity per GNPs of this new bionanoconjugate was enhanced by 10 times. Moreover, the enzyme activity of this bionanoconjugate was controllable. The above method of bionanoconjugation preparation has promising applications In the fi elds including preparing highly active bio-nanoprobe and immobilized enzyme.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 4; 57-60
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gold catalysts supported on zeolites
Katalizatory złotowe osadzone na zeolitach
Autorzy:
Walkowiak, Adrian
Powiązania:
https://bibliotekanauki.pl/articles/2057912.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
heterogeniczne katalizatory złotowe
nanocząstki złota
zeolity
metody modyfikacji zeolitów złotem
zastosowanie zeolitów modyfikowanych złotem
proces katalityczny
heterogeneous gold catalysts
gold nanoparticles
zeolites
methods of zeolites modification with gold
application of gold-modified zeolites
catalytic process
Opis:
Heterogeneous gold catalysis is a relatively young but dynamically developing field of chemistry. At the end of the 1980s, Masatake Haruta and Graham Hutchings provided experimental evidence of high activity of supported gold catalysts in CO oxidation and acetylene hydrochlorination. Thus, these two researchers challenged the prevailing chemists’ belief that gold is almost completely chemically inert and catalytically inactive. Since then, gold catalysis has been constantly in the centre of attention of a wide array of scientists from around the world. However, there are still many questions about the nature of catalysts containing this noble metal, which inspires in-depth research in this field. From among various potential supports for gold heterogeneous catalysts, zeolites have drawn much attention thanks to several unique properties of this group of materials, among which the most important are high thermal stability and the presence of a system of pores of strictly defined sizes. Zeolites have extremely large surface area, which is desirable to obtain high dispersion of the active phase. The article provides a concise overview of the methods of gold nanoparticles deposition on zeolitic supports and catalytic applications of such materials. The first chapter sheds light on the properties of bulk and nano-sized Au and depicts the background of gold catalysis development. In the following part, a brief description of zeolites and their properties is delivered. The third chapter is devoted entirely to the description of several preparation methods of zeolite-supported gold catalysts and their applications in different catalytic processes. The following post-synthetic methods of zeolite modification with gold are described: impregnation, ion exchange, deposition-reduction, chemical vapour deposition, and grafting. The most important advantages and disadvantages of each method are summarized. The article concludes with a résumé of literature reports concerning the use of zeolitesupported gold catalysts in various processes. Special attention was paid to selective oxidation of alcohols and biomass-derived chemicals (e.g. glucose).
Źródło:
Wiadomości Chemiczne; 2021, 75, 11-12; 1259--1293
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of gold nanoparticles stabilized by chitosan using irradiation and sonication methods
Autorzy:
Czechowska-Biskup, Renata
Rokita, Bożena
Ulański, Piotr
Rosiak, Janusz M.
Powiązania:
https://bibliotekanauki.pl/articles/1035040.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
gold nanoparticles
irradiation
sonication
stabilization
Opis:
Gold nanoparticles (AuNPs) were synthesized, in the absence of any reducing agent, using ionizing radiation or ultrasound in aqueous solutions of chloroauric acid (HAuCl4). Chitosan (average molecular weight 158 kDa, degree of deacetylation 90 %) was used as a stabilizing agent. Both techniques yielded AuNPs which were stable in solution at RT for at least 3 months after synthesis. UV-Vis spectroscopy was used to follow substrate decay, nanoparticles formation, size of the gold core and particles stability. Hydrodynamic radii and polydispersion of the chitozan-stabilized AuNPs (i.e. the whole core-shell nanoparticles) were determined by dynamic light scattering. Zeta potential measurements were performed to assess the surface charge and stability of the particles. Influence of synthesis parameters and presence of isopropanol on the formation and properties of the products have been described and reaction mechanisms have been discussed. Radiation and sonochemical methods are demonstrated to be very efficient, fast and easy-to-control methods of synthesizing gold nanoparticles, leaving behind no unreacted reducing agent or unwanted side products, while stabilization by chitosan provides AuNPs with excellent stability and long shelf life.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2015, 20; 18-33
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of an aptamer and a reagent based on gold nanoparticles for detection of Escherichia coli
Autorzy:
Pięta, P. P.
Szczerba, A.
Dobroczyńska, J. I.
Grabas, K.
Powiązania:
https://bibliotekanauki.pl/articles/207434.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Escherichia coli
złoto
aptamery
komórki bakteryjne
nanocząstki złota
zawiesiny wodne
gold
aptamers
bacterial cells
gold nanoparticles
water suspensions
Opis:
Plates functionalized with an Escherichia coll binding aptamer and a reagent based on gold nanoparticles were used for the detection of bacterial cells. Bacteria suspended in samples were caught by specific aptamers immobilized on a plastic plate whereas the gold nanoparticle reagent is an indicator reagent for visualization of the test result. Changes in colour of the gold nanoparticle reagent caused by gold nanoparticle agglomeration were observed with the naked eye. The test was designed for the detection of Escherichia coli in water suspensions.
Źródło:
Environment Protection Engineering; 2013, 39, 4; 125-133
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dose enhancement in brachytherapy in the presence of gold nanoparticles : a Monte Carlo study on the size of gold nanoparticles and method of modelling
Autorzy:
Ghorbani, M.
Pakravan, D.
Bakhshabadi, M.
Meigooni, A. S.
Powiązania:
https://bibliotekanauki.pl/articles/146605.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
brachytherapy
dose enhancement
gold nanoparticles
Monte Carlo (MC)
Opis:
The aim of this study was to evaluate the effect of the size of gold nanoparticles (GNPs) on dose enhancement in brachytherapy with photon emitting sources. Four photon emitting sources, 125I, 169Yb, 103Pd, and 192Ir were simulated and dose rate constant and radial dose functions were compared with published corresponding data for these sources. Dose enhancement factor in the presence of gold nanoparticles of 30 mg/ml concentration was calculated separately for nanoparticles with a diameter of 50, 100 and 200 nm. Gold nanoparticles were simulated precisely as nanospheres utilizing a lattice option in the MCNPX Monte Carlo code and the results were compared with those obtained with a simple model in which gold atoms are distributed uniformly in tumor volume as a simple mixture. Among the four mentioned sources, the dose enhancement related to 125I source is higher. Our results have shown that with gold nanoparticles of higher diameter, the level of dose enhancement is higher in the tested tumor. It has been also observed that the simple model overestimates the dose enhancement factor when compared with the precise model in which nanoparticles are defined according to the Monte Carlo code. In the energy range produced by the brachytherapy sources, the dose enhancement is higher when using brachytherapy sources with lower energy. Among the size range of gold nanoparticles used in medicine, it is predicted that nanoparticles with higher diameter can be more useful when are utilized in brachytherapy. It is also recommended that when calculating dose enhancements, a precise model be used for modelling of nanoparticles in the Monte Carlo simulations.
Źródło:
Nukleonika; 2012, 57, 3; 401-406
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gold nanoparticles in an enhancement of antimicrobial activity
Autorzy:
Wanarska, Ewelina
Maliszewska, Irena
Powiązania:
https://bibliotekanauki.pl/articles/1450221.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
gold nanoparticles
photodynamic therapy
methylene blue
staphylococcus aureus
Opis:
The effect of antimicrobial photodynamic therapy (aPDT) on Gram-positive bacterium Staphylocccus aureus was studied. Methylene blue (MB) at non-toxic concentration of 31.25µg/ml was used as a photosensitizer. LEDs diodes were used as a light source to study the effect of methylene blue alone and the MB-gold nanoparticle mixture on the viability of S. aureus cells. Biogenic gold nanoparticles (biolAuNPs, 10ppm) and chemically synthesized gold nanoparticles (chemAuNPs, 3ppm) were tested as enhancement agents. In the presence of MB alone as a photosensitizer, the killing effect was about 92% after 30min of irradiation. The aPDT therapy was enhanced by addition of biolAuNPs and chemAuNPs and killing rate of S. aureus was 95-96% after 30min of irradiation. The probable mechanism of enhancement of MB-mediated photodynamic bactericidal efficacy against S. aureus in the presence of gold nanoparticles is discussed leading to the conclusion that colloidal gold increases the accumulation of MB in bacterial cells.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 269-279
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational fluid dynamics simulation of heat transfer from densely packed gold nanoparticles to isotropic media
Autorzy:
Radomski, Piotr
Ziółkowski, Paweł
de Sio, Luciano
Mikielewicz, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/1954995.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
heat transfer
gold nanoparticles
glasses
polymers
computational fluid dynamics
Opis:
This work aims to determine and compare heat generation and propagation of densely packed gold nanoparticles (Au NPs) induced by a resonant laser beam (532 nm) according to the Mie theory. The heat flux propagation is transferred into the materials, which here are: silica glass; soda-lime-silica glass; borosilicate glass; polymethyl methacrylate (PMMA); polycarbonate (PC); and polydimetylosiloxane (PDMS). This analysis aims to select the optimum material serving as a base for using photo-thermoablation. On the other hand, research focused only on Newtonian heat transfer in gold, not on non-Fourier ones, like the Cattaneo approach. As a simulation tool, a computational fluid dynamics code with the second-order upwind algorithm is selected. Results reveal a near-Gaussian and Gaussian temperature distribution profile during the heating and cooling processes, respectively. Dependence between the maximum temperature after irradiation and the glass thermal conductivity is observed confirming the Fourier law. Due to the maximum heating area, the borosilicate or soda-lime glass, which serves as a base, shall represent an excellent candidate for future experiments.
Źródło:
Archives of Thermodynamics; 2021, 42, 3; 87-113
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gold Nanoparticles Like A Matrix For Covalent Immobilization Of Cholesterol Oxidase – Application For Biosensing
Nanocząstki złota jako matryca do immobilizacji oksydazy cholesterolu – zastosowanie w biosensorach
Autorzy:
Wojnarowska, R.
Polit, J.
Broda, D.
Gonchar, M.
Sheregii, E. M.
Powiązania:
https://bibliotekanauki.pl/articles/352497.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gold nanoparticles
biofunctionalization
enzyme
FTIR
SERS
nanocząstki złota
biofunkcjonalizacja
enzymy
Opis:
Gold nanoparticles are emerging as promising agents for various areas of material science as well as nanotechnology, electronics and medicine. The interest in this material is provided due to its unique optical, electronic and molecular-recognition properties. This paper presents results of preparation, characterization and biofunctionalization of gold nanoparticles. Nanoparticles have been conjugated with the cholesterol oxidase enzyme in order to prepare the active element for biosensors. Cholesterol oxidase is one of the most important analytical enzyme, used for cholesterol assay in clinical diagnostics, and there is still a necessity in improvement of existing analytical techniques, including bio-nanotechnological approaches based on modern nanosystems. The prepared bio-nanosystem was characterized by the enzyme activity test. Obtained results showed a stable binding of the enzyme with nanoparticles and preserved the bioactivity approves which gives possibility to use the prepared bio-nanosystems for analytical purposes. The Surface Plazmon Resonance and the Surface Enhanced Raman Scattering as specific for nanocurriers effects were observed what enable us to research the oscillation spectra of enzyme. These spectra were compared with ones obtained by IR-spectroscopy. The vibrational lines are attributed to chemical functional groups existing in enzyme, for example, amino acids, amide groups as well as flavin – adenine dinucleotide cholesterol oxidase prosthetic group. By this way the identified spectral lines can be used as a distinguishing mark of enzyme.
Nanocząstki złota zdają się być niezwykle obiecującym materiałem, który z powodzeniem może być wykorzystywany w różnych dziedzin inżynierii materiałowej, nanotechnologii, elektroniki czy medycyny. Zainteresowanie tym materiałem wynika z posiadanych przez niego unikatowych właściwości optycznych, elektronicznych i identyfikacji na poziomie molekularnym. W artykule przedstawiono wyniki prowadzonych badań dotyczących przygotowania, charakterystyki i biofunkcjonalizacji nanocząstek złota. Celem wytwarzania i łączenia nanocząstek złota z enzymem oksydazą cholesterolową było opracowanie aktywnego biologicznie elementu biosensora. Oksydaza cholesterolowa jest jednym z najważniejszych enzymów analitycznych, stosowanych w diagnostyce klinicznej do oznaczenia stężenia cholesterolu. Istnieje potrzeba doskonalenia istniejących metod analitycznych, między innymi poprzez wykorzystanie nowoczesnych nanomateriałów. Przeprowadzono badania aktywności enzymu immobilizowanego, jak również dokonano charakterystyki danego bionanosystemu za pomocą wybranych metod optycznych. Na podstawie uzyskanych wyników można stwierdzić, że wiązanie enzymu z nanocząstkami jest stabilne, a aktywność biologiczna została zachowana, co pozwala na przygotowanie bio-nanosystemu do celów analitycznych. Zaobserwowano również wystąpienie dwóch efektów optycznych charakterystycznych w przypadku zastosowania odpowiednich nanonośników: Powierzchniowego Rezonansu Plazmonów oraz Powierzchniowo Wzmocnionego Rozproszenia Ramanowskiego. Uzyskane widma były porównywane z widmami w podczerwieni. Zaobserwowane linie przypisano do charakterystycznych grup funkcyjnych, aminokwasów, wiązań peptydowych, jak również dinukleotydu flawinoadeninowego czyli grupy prostetycznej oksydazy cholesterolowej. Zidentyfikowane linie mogą być wykorzystywane jako marker analityczny dla danego enzymu.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 3; 2289-2296
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of polymer-grafted gold nanoparticles via gamma radiation
Synteza polimerów szczepionych nanocząstkami złota z wykorzystaniem promieniowania gamma
Autorzy:
Mokhtar, Abdul Khaliq
Mohd Hidzir, Norsyahidah
Rahman, Irman Abdul
Mohamed, Faizal
Radzal, Nur Ain Mohd
Powiązania:
https://bibliotekanauki.pl/articles/2088259.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
gold nanoparticles
polymer
grafting
radiosensitizers
polimer
szczepienie
nanocząstki złota
radiouczulacze
Opis:
The research focused on the synthesis of polytetrafluoroethylene (PTFE) grafted with gold nanoparticles (AuNP). The Turkevich method, one of the common techniques of AuNP synthesis, was used to obtain an AuNP solution with a nanoparticle size of 20 nm. The PTFE-AuNP samples were subsequently irradiated and the absorbed doses were 0.5, 2, 5, 10 and 20 kGy. It was noticed that samples irradiated with 0.5 and 2 kGy were less stable and less concentrated than samples irradiated with higher doses due to aggregation and formation of precipitation after 30 days.
W artykule omówiono technikę syntezy poli(tetrafluoroetylenu) (PTFE) szczepionego nanocząstkami złota (AuNP). Metodą Turkevicha, jedną z powszechnie stosowanych technik syntezy AuNP, uzyskano roztwór AuNP o wielkości cząstek 20 nm. Próbki roztworu PTFE-AuNP były następnie naświetlane promieniowaniem gamma; zaabsorbowane dawki promieniowania wyniosły 0,5, 2, 5, 10 oraz 20 kGy. Stwierdzono, że w przypadku dawek 0,5 i 2 kGy roztwór był mniej stabilny, a stężenie nanocząstek było niższe niż w przypadku wyższych dawek. Wiązało się to z agregacją i precypitacją nanocząstek po upływie 30 dni od naświetlania.
Źródło:
Polimery; 2021, 66, 11-12; 584--588
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Towards mechanisms of nanotoxicity - interaction of gold nanoparticles with proteins and DNA
Autorzy:
Krupa, P.
Mozolewska, M. A.
Rasulev, B.
Czaplewski, C.
Leszczyński, J.
Powiązania:
https://bibliotekanauki.pl/articles/1935819.pdf
Data publikacji:
2014
Wydawca:
Politechnika Gdańska
Tematy:
gold nanoparticles
proteins
DNA
molecular dynamics
nanocząstki złota
białka
dynamika molekularna
Opis:
Even though most of the existing studies of gold nanoparticles indicate that they are safe to use, some researchers show that specific forms of nanoparticles (e.g. nanorods) are able to destroy the cell membrane and very small nanoparticles (below 37nm in diameter) in high concentration have been deadly for mice. We used the Amber12 package to perform a series of molecular dynamics (MD) simulations of gold nanoparticles with various small proteins important for the human body and a DNA molecule to determine the interactions and consequently the possible toxicity of gold clusters. Lennard-Jones interactions were used to simulate the behavior of gold nanoparticles with biomacromolecules in water with an optimal set of parameters (selected based on a comparison of MD structures and structures computed by DFT). Gold nanoparticle structures were obtained as a result of MD simulations from an initial structure, where gold atoms were at a distance of 10 ̊ A from one another. A predicted BDNA structure of a palindromic sequence‘ CGCATGAGTACGC ’ and a 2 JYK molecule were used as representatives of the DNA molecule. The preliminary results show that, in particular small gold nanoparticles, interact strongly with proteins and DNA by creating stable complexes, which can then cause harmful reactions to the human body when present in high concentration.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2014, 18, 4; 337--341
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Radiolytic synthesis of gold nanoparticles in HEMA-based hydrogels : potentialities for imaging nanocomposites
Autorzy:
Dziarabina, Katsiaryna
Pinaeva, Uliana
Kadłubowski, Sławomir
Ulański, Piotr
Coqueret, Xavier
Powiązania:
https://bibliotekanauki.pl/articles/2055680.pdf
Data publikacji:
2021
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
functional hydrogels
gold nanoparticles
nanocomposites
network properties
radiation--induced reactions
stimuli-responsiveness
Opis:
This article reports on the radiolytic synthesis of nanocomposites containing gold nanoparticles (AuNPs) within two types of hydrogels based on 2-hydroxyethyl methacrylate (HEMA): (i) plain networks with various contents in ethylene glycol dimethacrylate (EGDMA), as a cross-linker and (ii) stimuli-responsive (SR) networks prepared from these monomers copolymerized with [2-(methacryloyloxy)ethyl]trimethylammonium chloride (MADQUAT) to confer pH-switchable swelling. Hydrogels were prepared by photopolymerization with well-defi ned composition and a high degree of monomer conversion using two experimental procedures, as xerogels or in aqueous solution. Besides MADQUAT, acrylic acid (AA) or N-isopropylacrylamide have been tested as copolymers, yielding pH- or temperature-sensitive hydrogels, respectively. Isothermal swelling in water was affected by monomer composition. Electron beam (EB) irradiation at doses up to 100 kGy of poly(HEMA) xerogels and water-swollen networks prepared with 0.5 wt% of EGDMA had a moderate impact on swelling characteristics and thermomechanical properties of the plain materials, whereas small amounts of extractables were formed. Poly(HEMA)-based nanocomposites containing AuNPs were successfully obtained by EB irradiation of samples swollen by aqueous solutions of Au(III). The effects of dose and cross-linking density on the formation of AuNPs were monitored by UV-visible spectroscopy. Irradiation at well-defined temperatures of the Au(III)-loaded SR hydrogels induced the formation of nanoparticles with size-dependent features, whereas the efficiency of Au(III) reduction at 10 kGy was not significantly affected by the network structure. EB-induced reduction of Au(III) in poly(HEMA) hydrogels using a lead mask to generate well-defined patterns yielded coloured and long-lasting images in the zones where the nanocomposite was formed.
Źródło:
Nukleonika; 2021, 66, 4; 165--177
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Deposition of Gold Nanoparticles Onto Activated Carbon
Osadzanie nanocząstek złota na węglu aktywnym
Autorzy:
Jaworski, W.
Streszewski, B.
Szaciłowski, K.
Pacławski, K.
Powiązania:
https://bibliotekanauki.pl/articles/351364.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gold nanoparticles
activated carbon
functionalization
amines
nanocząstki złota
węgiel aktywny
funkcjonalizacja
aminy
Opis:
This work reports the results of spectrophotometric, dynamic light scattering (DLS) and microscopic (SEM) studies of the gold nanoparticles (AuNPs) deposition on activated carbon (AC) surface modified with primary (ethanolamine) and secondary (diethylenetriamine and triethylenetetramine) amines. It was found that this method is efficient for deposition of AuNPs from aqueous solution. However, nanoparticles change their morphology depending on the kind of amine used in experiments. On the AC surface modified with ethanolamine, the uniform spherical AuNPs were formed. In case of diethylenetriamine and triethylenetetramine application, the agglomerates of AuNPs are present. The diameter of individual AuNPs did not exceed 15 nm and was bigger as compared with the diameter of particles present in precursor solution (ca. 10 nm).
W pracy przedstawiono wyniki badań spektrofotometrycznych, metodą dynamicznego rozpraszania światła (DLS) oraz mikroskopowe (SEM) dotyczące osadzania nanocząstek złota na węglu aktywnym, modyfikowanym aminami: pierwszorzędową (etanoloamina) i drugorzędowymi (dietylenotriamina i trietylenotetraamina). Wykazano, że ten sposób modyfikacji umożliwia osadzanie nanocząstek złota z roztworu wodnego na powierzchni węgla. W zależności od rodzaju używanej aminy ulega jednak zmianie morfologia osadów nanocząstek. Na powierzchni węgla aktywnego, modyfikowanego etanoloaminą, tworzą się jednorodne cząstki złota o kształcie sferycznym. W przypadku zastosowania dietylenotriaminy oraz trietylenotetraaminy obserwowano powstawanie agregatów nanocząstek. Średnica pojedynczych nanocząstek nie przekraczała 15 nm i była większa od średnicy nanocząstek obecnych w roztworze prekursora (ok. 10 nm).
Źródło:
Archives of Metallurgy and Materials; 2014, 59, 3; 899-903
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gold Nanoparticles as a Modifying Agent of Ceramic-Polymer Composites
Nanocząsteczkowe złoto jako modyfikator kompozytów polimerowo-ceramicznych
Autorzy:
Sobczak-Kupiec, A.
Tyliszczak, B.
Krupa-Żuczek, K.
Malina, D.
Piątkowski, M.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/353222.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gold nanoparticles
ceramic-polymer composites
biomaterials
złoto nanocząsteczkowe
kompozyty polimerowo-ceramiczne
biomateriały
Opis:
Much effort has been invested in the development of biomaterials for the repair or replacement of hard tissue. The synthesis of composites based on mineral and organic constituents is nowadays extremely important for the development of materials for biomedical applications. In this paper we report the preparation and characterization of ceramic-polymer composites doped with gold nanoparticles. Properties and applications in medicine and dentistry of colloidal gold nanoparticles depends upon their size and shape. The influence of the presence of the metallic nanoparticles on the degradation process was investigated by pH and conductivity analyses of water filtrates. The nanocomposites were characterized with the use of X-ray Diffaction (XRD) and Fourier Transformed Infrared Spectroscopy (FT-IR) methods. The results of in vitro tests confirmed that it is possible to produce hydroxyapatite/polymer (HA/polymer) composites doped with gold nanoparticles (AuNPs) for medical applications. Tests proved that content of gold nanoparticles in composites had influence on degradation behaviour of HA/Polymer/AuNPs in water environment.
Obecnie wiele starań jest wkładanych w badania dotyczące rozwoju biomateriałów do naprawy i wymiany tkanki kostnej. Otrzymywanie kompozytów opartych na składnikach mineralnych i organicznych jest niezwykle istotne dla rozwoju materiałów do zastosowań biomedycznych. Właściwości i zastosowanie nanocząstek złota w medycynie i stomatologii zależy przede wszystkim od ich wielkości i kształtu. W pracy opisano metodykę otrzymywania oraz charakterystykę kompozytów ceramiczno-polimerowych domieszkowanych nanocząstkami złota. Badano wpływ obecności nanocząstek metalicznych na proces degradacji w środowisku wodnym z wykorzystaniem analiz pH i przewodnictwa. Charakterystykę nanokompozytów wykonano z zastosowaniem dyfrakcji promieni rentgenowskich (XRD) i spektroskopii w podczerwieni z transformacją Fouriera (FT-IR). Na podstawie badań in vitro stwierdzono, że możliwe jest otrzymanie kompozytów polimerowo-ceramicznych modyfikowanych nanocząstkami złota do zastosowań biomedycznych. Badania wykazały, że zawartość nanocząstek złota wpływa na degradację kompozytów HA/Polymer/AuNPs w środowisku wodnym.
Źródło:
Archives of Metallurgy and Materials; 2014, 59, 3; 1005-1009
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mixtures of selected n-alkanes and Au nanoparticels for optical fiber threshold temperature transducers
Autorzy:
Przybysz, N.
Marć, Paweł
Tomaszewska, E.
Grobelny, Jarosław
Jaroszewicz, Leszek R.
Powiązania:
https://bibliotekanauki.pl/articles/1818228.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Stowarzyszenie Elektryków Polskich
Tematy:
optical fiber sensors
temperature treshold sensors
gold nanoparticles
n-alkanes
photonic crystal transducers
Opis:
Thermo-optic properties enhancement of the bi-stable temperature threshold sensors based on a partially filled photonic crystal fiber was reported. Previously tested transducers filled with a selected group of pure n-alkanes had in most cases differences between switching ON and OFF states. Therefore, the modification of filling material by using additional crystallization centers in the form of gold nanoparticles was applied to minimize this undesirable effect. The evaluation of the thermodynamic properties of pentadecane and its mixtures with 14 nm spherical Au nanoparticles based on the differential scanning calorimetry measurements was presented. Optical properties analysis of sensors prepared with these mixtures has shown that they are bounded with refractive index changes of the filling material. Particular sensor switches ON before melting process begins and switches OFF before crystallization starts. Admixing next group of n-alkanes with these nanoparticles allows to design six sensors transducers which change ON and OFF states at the same temperature. Thus, the transducers with a wider temperature range for fiber-optic multi-threshold temperature sensor tests will be used.
Źródło:
Opto-Electronics Review; 2020, 28, 4; 220--228
1230-3402
Pojawia się w:
Opto-Electronics Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mixtures of selected n-alkanes and Au nanoparticels for optical fiber threshold temperature transducers
Autorzy:
Przybysz, N.
Marć, P.
Tomaszewska, E.
Grobelny, J.
Jaroszewicz, L. R.
Powiązania:
https://bibliotekanauki.pl/articles/1818233.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Stowarzyszenie Elektryków Polskich
Tematy:
optical fiber sensors
temperature treshold sensors
gold nanoparticles
n-alkanes
photonic crystal transducers
Opis:
Thermo-optic properties enhancement of the bi-stable temperature threshold sensors based on a partially filled photonic crystal fiber was reported. Previously tested transducers filled with a selected group of pure n-alkanes had in most cases differences between switching ON and OFF states. Therefore, the modification of filling material by using additional crystallization centers in the form of gold nanoparticles was applied to minimize this undesirable effect. The evaluation of the thermodynamic properties of pentadecane and its mixtures with 14 nm spherical Au nanoparticles based on the differential scanning calorimetry measurements was presented. Optical properties analysis of sensors prepared with these mixtures has shown that they are bounded with refractive index changes of the filling material. Particular sensor switches ON before melting process begins and switches OFF before crystallization starts. Admixing next group of n-alkanes with these nanoparticles allows to design six sensors transducers which change ON and OFF states at the same temperature. Thus, the transducers with a wider temperature range for fiber-optic multi-threshold temperature sensor tests will be used.
Źródło:
Opto-Electronics Review; 2020, 28, 4; 220--228
1230-3402
Pojawia się w:
Opto-Electronics Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 22

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