- Tytuł:
- Synthesis and characterization of TiO2/ZSM-5 photocatalysts for degradation of rhodamine
- Autorzy:
-
Liu, Rulai
Hu, Jiapeng
Rau, Juiye
Lin, Hao
He, Huan
Gao, Biao
Lai, Wenliang - Powiązania:
- https://bibliotekanauki.pl/articles/2086909.pdf
- Data publikacji:
- 2022
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
photodegradation
TiO2
ZSM-5
kaolin clay
fotodegradacja
glinka kaolinowa - Opis:
- ZSM-5 synthesized by the hydrothermal method from raw kaolin clay was used as support to prepare TiO2/ZSM-5 catalysts via the sol-gel method. All prepared samples were characterized by X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), transmission electron microscopy (TEM), particle size analysis and surface area measurement. The photocatalytic performance of TiO2/ZSM-5 was investigated based on rhodamine B (RhB) removal under UV radiation (450-600 nm. The results showed that the kaolin clay was successfully transformed into ZSM-5. The BET surface area and pore size distribution of the synthesized ZSM-5 were 364 m2/g and 0.54 nm, respectively. SEM and TEM revealed that TiO2 nanoparticles were well distributed on the surface of ZSM-5. The composite TiO2/ZSM-5 catalyst showed 98.53% removal, which is higher than that of pure TiO2 (80.13%) due to adsorption and degradation of RhB (5.0 mg/dm3) under 60 min UV light irradiation at 1 g/dm3 photocatalyst loading. The synergistic effect of TiO22 and ZSM-5, including adsorption, conduction band electron (e-), and valence-band holes (h+), makes the composite superior to pure TiO2, showing its potential for the degradation of organic dye.
- Źródło:
-
Environment Protection Engineering; 2022, 48, 2; 29--42
0324-8828 - Pojawia się w:
- Environment Protection Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł