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    Wyświetlanie 1-3 z 3
    Tytuł:
    Homogenization phenomena of surface components of fluorite and calcite
    Autorzy:
    Sun, Ruofan
    Liu, Dan
    Zhang, Benyue
    Lai, Hao
    Wen, Shuming
    Powiązania:
    https://bibliotekanauki.pl/articles/1448969.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    homogenization phenomena
    surface composition
    fluorite
    calcite
    mixed grinding
    Opis:
    The flotation separation of fluorite and calcite poses one of the most difficult problems in the mineral processing industry. In particular, the surface homogenization of fluorite and calcite worsens the result of fluorite flotation. In this paper, time of flight secondary ion mass spectrometry and principal component analysis are used to study the surface homogenization of fluorite and calcite during grinding and in solution using X-ray photoelectron spectroscopy, infrared spectroscopy, and solution chemical calculations. The results show that the surface composition of calcite converts to fluorite after mixed grinding and that the surface composition of fluorite also converts to calcite in clarified calcite solution.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 250-258
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence and mechanism of Zn2+ on fluorite/calcite in sodium hexametaphosphate flotation system
    Autorzy:
    Ruitao, Liu
    Dan, Liu
    Ruofan, Sun
    Daqian, Wang
    Wenkang, Zhang
    Yuebing, Liu
    Shuming, Wen
    Powiązania:
    https://bibliotekanauki.pl/articles/2175451.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    calcite
    sodium hexametaphosphate
    flotation
    metal ions
    Opis:
    Fluorite and calcite have similar surface properties and natural floatability, so their flotation separation has always been a problem faced by the beneficiation industry. The key to flotation separation is the choice of depressants. Sodium hexametaphosphate (SHMP) has a good effect on fluorite calcite selective inhibition. In this paper, the effects of Zn2+ on the selective inhibition of SHMP in the flotation process of fluorite and calcite were studied through single mineral and artificial mixed mineral flotation experiments. Solution chemical calculation, X-ray photoelectron spectroscopy (XPS), Fourier Transform Infrared spectroscopy (FT-IR) and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) analyses investigated the mechanism of action of Zn2+, which had the most significant negative effect on the selective inhibition of SHMP. The results show that the main components of SHMP inhibiting minerals are HPO42- and H2PO4-, which can react with Ca active sites on the mineral surface to form hydrophilic Ca(H22PO4)2 and CaHPO4, while Zn2+ The presence of HPO42- in solution resulted in the formation of stable ZnHPO4 complexes, thereby weakening the inhibitory effect of SHMP on minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151676
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of polyacrylic acid on the surface properties of calcite and fluorite aiming at their selective flotation
    Autorzy:
    Zhang, C.
    Gao, Z.
    Hu, Y.
    Sun, W.
    Tang, H.
    Yin, Z.
    He, J.
    Guan, Q.
    Zhu, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/110577.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    calcite
    fluorite
    selective flotation
    polyacrylic acid
    Opis:
    In this study, the polyacrylic acid (PAA) was studied as a selective depressant for calcite in the selective flotation of fluorite and calcite, and the implications of this process for the separation of fluorite ore were studied using micro-flotation tests, and the results were analyzed with Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses. The flotation tests indicated that the preferential adsorption of PAA onto calcite rather than sodium oleate (NaOl) could selectively depress the flotation of calcite, allowing its separation from fluorite at pH 7. The zeta potential of calcite became more negative with the addition of PAA rather than with NaOl. However, the characteristic features of PAA adsorption were not observed for fluorite, suggesting that NaOl preferentially adsorbed on the surface of fluorite, or that PAA could be replaced by NaOl on the fluorite surface. FT-IR and XPS analysis were utilized to obtain a better understanding of the mechanism by which PAA was more strongly adsorbed on the calcite surface than NaOl. This was revealed to occur through chemical bonding between the carboxyl group of PAA and the hydroxyl groups of the Ca species on the calcite surface, modifying the structure of the adsorbed layer. A possible adsorption mechanism, along with a postulated adsorption mode for the surface interaction between PAA and calcite, is proposed.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 868-877
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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