Temat: fluorescence - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:: 2016
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:: Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:: Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: In vitro fluorescence studies of transcription factor IIB-DNA interaction
Autorzy:: Górecki, Andrzej
Figiel, Małgorzata
Dziedzicka-Wasylewska, Marta
Powiązania:: https://bibliotekanauki.pl/articles/1038975.pdf
Data publikacji:: 2015
Wydawca:: Polskie Towarzystwo Biochemiczne
Tematy:: transcription factors
TF2B
TFIIB
fluorescence spectroscopy
fluorescence quenching
site directed mutagenesis
Opis:: General transcription factor TFIIB is one of the basal constituents of the preinitiation complex of eukaryotic RNA polymerase II, acting as a bridge between the preinitiation complex and the polymerase, and binding promoter DNA in an asymmetric manner, thereby defining the direction of the transcription. Methods of fluorescence spectroscopy together with circular dichroism spectroscopy were used to observe conformational changes in the structure of recombinant human TFIIB after binding to specific DNA sequence. To facilitate the exploration of the structural changes, several site-directed mutations have been introduced altering the fluorescence properties of the protein. Our observations showed that binding of specific DNA sequences changed the protein structure and dynamics, and TFIIB may exist in two conformational states, which can be described by a different microenvironment of W52. Fluorescence studies using both intrinsic and exogenous fluorophores showed that these changes significantly depended on the recognition sequence and concerned various regions of the protein, including those interacting with other transcription factors and RNA polymerase II. DNA binding can cause rearrangements in regions of proteins interacting with the polymerase in a manner dependent on the recognized sequences, and therefore, influence the gene expression.
Źródło:: Acta Biochimica Polonica; 2015, 62, 3; 413-421
0001-527X
Pojawia się w:: Acta Biochimica Polonica
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 3.

Tytuł:: Adsorption of humic acid on mesoporous carbons prepared from poly- (ethylene terephthalate) templated with magnesium compounds
Autorzy:: Karolczyk, J.
Mozia, S.
Morawski, A.W.
Przepiórski, J.
Powiązania:: https://bibliotekanauki.pl/articles/778949.pdf
Data publikacji:: 2012
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: porous carbon
adsorption
humic acid
fluorescence spectroscopy
Opis:: Porous carbons obtained from poly(ethylene terephtalate) contained in a mixture with either MgCO3 or Mg(OH)2 were examined as adsorbents for removal of humic acid from water. Adsorption of the model contaminants is discussed in relation to the textural parameters of the obtained carbon materials. Pore structure parameters of the carbonaceous materials were strongly influenced by preparation conditions including temperature and relative amounts of the inorganics used during preparations as template. Porous carbons prepared revealed a potential to purify water from the model contaminant of high molecular weight. The results presented confirmed a key role of mesoporosity in the adsorption of humic acid. Fluorescence spectroscopy was confirmed to be an useful method to evaluate concentration of humic acid in water.
Źródło:: Polish Journal of Chemical Technology; 2012, 14, 4; 95-99
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 4.

Tytuł:: Dansylated analogues of the opioid peptide [Dmt1]DALDA: in vitro activity profiles and fluorescence parameters.
Autorzy:: Berezowska, Irena
Lemieux, Carole
Chung, Nga
Zelent, Bogumil
Schiller, Peter
Powiązania:: https://bibliotekanauki.pl/articles/1043324.pdf
Data publikacji:: 2004
Wydawca:: Polskie Towarzystwo Biochemiczne
Tematy:: fluorescence spectroscopy
opioid activity profile in vitro
fluorescence quantum yield
opioid peptides
fluorescent opioid peptide analogues
[Dmt1]DALDA
Opis:: Dansylated analogues of the potent and selective μ opioid peptide agonist [Dmt1]DALDA (H-Dmt-D-Arg-Phe-Lys-NH2; Dmt = 2',6'-dimethyltyrosine) were prepared either by substitution of Nβ-dansyl-α,β-diaminopropionic acid or Nε-dansyllysine for Lys4, or by attachment of a dansyl group to the C-terminal carboxamide function via a linker. All three analogues displayed high μ agonist potency in vitro and the C-terminally dansylated one retained significant μ receptor selectivity. The three analogues showed interesting differences in their fluorescence emission maxima and quantum yields, indicating that the dansyl group in two of them was engaged in intramolecular hydrophobic interactions. These dansylated [Dmt1]DALDA analogues represent valuable tools for binding studies, cellular uptake and intracellular distribution studies, and tissue distribution studies.
Źródło:: Acta Biochimica Polonica; 2004, 51, 1; 107-113
0001-527X
Pojawia się w:: Acta Biochimica Polonica
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 5.

Tytuł:: Fluorescence of natural seawater exposed to oil pollution
Autorzy:: Otremba, Z.
Baszanowska, E.
Powiązania:: https://bibliotekanauki.pl/articles/245422.pdf
Data publikacji:: 2015
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: marine fleet exploitation
seawater
oil pollution
fluorescence spectroscopy
Opis:: The natural seawater contains both dissolved and suspended organic substances originating from natural sources and human activities – like the marine transport fleet among other. To specify the type and quantity of vitally valid as well as dangerous for properly functioning marine ecosystems substances complicated and sophisticated chemical instrumentation and methodologies must be used. Only a small number of seawater components it is possible easily to determine their concentrations – for example, the salt content is determined directly in the bulk of water through simultaneous measurement of electrolytic conductivity and temperature of water. It is worth to search similarly quick method for oil substances directly in the seawater. Taking into account seawater organic pollutants originating from natural sources inter alia crude oils, the presence of refinery petroleum substances due to their fluorescence in ultra-violet light can be determined based on fluorescence spectroscopy. The aim of this paper is to search fluorescence features of oil substances dissolved in natural seawater based on excitation-emission spectroscopy. In the paper fresh and oily contaminated seawater taken from the coastal area of the Baltic Sea were used. As an oil pollution ‘Petro-baltic’ oil were applied. The natural seawater, at first was laboratory exposed to low extremely amount of oil and then it was examined by fluorescence under UV light. The seawater from vicinity of Gdynia (Poland) were tested as fresh and after artificially contaminated by different amount of oil (from 0.5 to 500 ppm). Spectrofluorometer Hitachi F-7000 FL was applied to measure excitation-emission spectra (EEMs). Low amounts of oil (up to several ppm) cause increasing of main peak in excitation-emission spectra (EEMs). Addition of larger amounts of oil results in appearance new peaks, which originate from fluorescence of soluble fractions of oil artificially added to examined water. These specific features of oil describe the spectroscopic signatures of oil, which is the basis to development operational method of the source of oil pollution identification.
Źródło:: Journal of KONES; 2015, 22, 3; 181-186
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 6.

Tytuł:: Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:: Otremba, Z.
Baszanowska, E.
Powiązania:: https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:: 2015
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:: The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:: Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 7.

Tytuł:: Fluorescence spectra of oil after it contacts with aquatic environment
Autorzy:: Baszanowska, E.
Otremba, Z.
Toczek, H.
Rohde, P.
Powiązania:: https://bibliotekanauki.pl/articles/245054.pdf
Data publikacji:: 2013
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: oil pollution
fluorescence spectroscopy
excitation-emission spectra
seawater
environment protection
Opis:: The main task for natural marine environment protection is to prevent the inflow of various contaminants including oil substances and the real challenge is the ability to rapidly detect these pollutants. Moreover important is to find the source or the maker of the oil spill. In this paper, we consider fundamental physical aspects in the area of possibility of monitoring the natural marine ecosystem based on fluorescence spectroscopy. We utilize the fluorescence ability of numerous oil components – mainly polycyclic hydrocarbons. The paper concerns the spectrofluorimetric characterization of oils have been in use during exploitation of the marine fleet, i.e. lubricate oil, fuels, transformer and hydraulic oils as well as crude oils or their residues. Every kind of oil has a chance to enter the marine environment, especially in a case of ship emergency or after collision with other vessel ore shoreline structure as well as when ship enters the stranding. After discharge of oil, some of oil components are dissolved in the water, bacteria or photochemical reactions, which results in transformation of composition of oil, degrade some. Fluorescence spectrometer Perkin Elmer LS55 was applied to obtain the fluorescence spectra using different excitation wavelength in the range from 240 nm to 500 nm. We discuss the changes of the shapes of excitationemission spectra (EEMs) of various types of oil and the EEMs spectra after contact of oil with seawater as an oil-inwater emulsion, which is the most frequent form of oil in the water column. Significant changes in the shape of spectra and displacement of the peaks are observed.
Źródło:: Journal of KONES; 2013, 20, 3; 29-34
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 8.

Tytuł:: Oil identification based on total synchronous spectra
Autorzy:: Baszanowska, E.
Otremba, Z.
Powiązania:: https://bibliotekanauki.pl/articles/246342.pdf
Data publikacji:: 2014
Wydawca:: Instytut Techniczny Wojsk Lotniczych
Tematy:: fluorescence spectroscopy
total synchronous spectra
lubricate oil
vessel engine room
marine environment
Opis:: Contribution of marine carriage in the global transport is in permanent developing. It leads to increase the unintentional oil spills, which may induce serious disturbances in functioning of the natural marine ecosystem, especially when it interferes with other technical activities in the marine space. That fact contributes to increase the interest in searching of new research techniques to protect the natural ecosystem. Therefore, the main task of marine international organisations concentrates on the effective and rapid detection of oil spill and on the possibility of identifying oil pollutants as well as on origin of pollution. The purpose of the study is to characterise the oil belonging to the vessel engine lubricate oils. We analyse the stage results of investigations based on one of types of fluorescence spectroscopy, namely: synchronous spectra. To characterise the oil, the Aqualog Horiba spectrofluorometer was applied, which allows performing precise measurement in a short time. Based on the measured excitation-emission spectra, total synchronous fluorescence spectra for oil were obtained using various wavelength intervals. Total synchronous fluorescence spectra of petroleum substances allow finding wavelength interval typical for particular type of oil. This approach could allow obtaining of complex mixtures, such as oils, more efficient description. We discuss the total synchronous fluorescence spectra for engine oil (Marinol type) dissolved in n-hexane in various concentrations of oil as a possible tool proposed to oil type identification. We present changes and variation of the total synchronous fluorescence spectra for oil with various oil concentrations.
Źródło:: Journal of KONES; 2014, 21, 2; 15-20
1231-4005
2354-0133
Pojawia się w:: Journal of KONES
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 9.

Tytuł:: Changes in the fluorescence excitation and emissions spectra of heated and frying rapeseed oil and sunflower oil
Autorzy:: Szukay, Beata
Stachura, Wojciech
Saletnik, Łukasz
Budzyński, Jacek
Szymańska, Justyna
Fisz, Jacek
Powiązania:: https://bibliotekanauki.pl/articles/410481.pdf
Data publikacji:: 2019
Wydawca:: Politechnika Łódzka. Wydawnictwo Politechniki Łódzkiej
Tematy:: fluorescence spectroscopy
vegetable oils
deep frying
spektroskopia fluorescencyjna
oleje roślinne
smażenie zanurzeniowe
Opis:: Frying is a popular method of cooking (meals preparation). Heating and deep-fat frying cause a series of chemical reactions, such as oxidation of polyunsaturated fatty acids and vitamin E, as well as formation of trans isomers and products of peroxidation. These chemical reactions cause organoleptic and nutritional changes in the product, which may have a negative effect on health. For this reason, the usefulness of many methods for evaluation of refined oils quality is investigated. The fluorescence spectroscopy is increasingly used for this purpose. The aim of the study was to monitor the changes in emission and excitation spectra of refined rapeseed oil and sunflower oil after processes of heating and frying frozen French fries. The obtained results show the differences between the shapes of fluorescence excitation and emission spectra of both oils due to the two processes and these changes depend on duration of both processes. This study indicates that fluorescence spectroscopy is a promising method for evaluation of changes in oils during heating or frying.
Źródło:: Biotechnology and Food Science; 2019, 83, 1; 49-56
2084-0136
2299-6818
Pojawia się w:: Biotechnology and Food Science
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 10.

Tytuł:: Badania FTIR-ATR i fluorescencyjne układów białkowo-lipidowych
FTIR-ATR and fluorescence studies of protein-lipid systems
Autorzy:: Litwińczuk-Mammadova, A.
Cieślik-Boczula, K.
Rospenk, M.
Powiązania:: https://bibliotekanauki.pl/articles/172158.pdf
Data publikacji:: 2017
Wydawca:: Polskie Towarzystwo Chemiczne
Tematy:: spektroskopia FTIR-ATR
spektroskopia fluorescencyjna
anizotropia
efekt REES
wygaszanie fluorescencji
model stanów dyskretnych Trp
sonda fluorescencyjna
białko
lipid
FTIR-ATR spectroscopy
fluorescence spectroscopy
anisotropy
REES effect
fluorescence quenching
fluorescent probes
protein
Opis:: Lipid-protein systems paly curtail roles in living systems [49]. Hence, a determination of their structure at different levels of organization is still one of the most important tasks in many research projects. A study of lipid-protein systems is based on many physicochemical techniques, such as spectroscopy of FTIR, Raman, fluorescence, NMR, EPR, as well as DLS, DSC and TEM methods. In the presented paper tow of the most frequently used methods, that is FTIR and fluorescence spectroscopy, will be discussed in details. They are characterized by a relatively low cost of sample preparation, a short measuring time, and they give a huge number of structural and physicochemical information about lipid-protein systems. In the FTIR-ATR spectroscopy many of vibrational bands are commonly used as very precise vibrational indicators of structural changes in lipids and proteins (Fig. 1) [1–6]. They allows to characterize lipid and protein components separately in mixed systems. Additionally, structural changes in lipid membranes can be monitored in one FTIR-ATR experiment simultaneously in a region of hydrophilic lipid head-groups (Fig. 5) [17, 18], in a hydrophobic part composed of hydrocarbon lipid chains (see Figures 2 and 3) [7–9], and in a lipid membrane interface represented by ester lipid groups (Fig. 4) [4, 6, 11, 12]. A secondary structure of proteins and peptides in different experimental conditions can be defined in the FTIR-ATR spectroscopy on the base of amide I bands (Fig. 6 and Tabs 1, 2 and 3) [20–22]. A fluorescence spectroscopy is a complementary methods to FTIR spectroscopy in a study of lipid-protein systems. It competes information about time-dependent and very fast (in a scale of femtoseconds) structural processes in both lipids [41–45] and proteins [23, 27, 48]. The folding, denaturation, and aggregation of proteins and lipid membranes accompanied by changes in an order, packing and hydration of the system under study [23, 27, 41–45, 48].
Źródło:: Wiadomości Chemiczne; 2017, 71, 1-2; 109-132
0043-5104
2300-0295
Pojawia się w:: Wiadomości Chemiczne
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 11.

Tytuł:: The interaction of new oxicam derivatives with lipid bilayers as measured by calorimetry and fluorescence spectroscopy
Autorzy:: Maniewska, Jadwiga
Gąsiorowska, Justyna
Szczęśniak-Sięga, Berenika
Michalak, Krystyna
Powiązania:: https://bibliotekanauki.pl/articles/1038386.pdf
Data publikacji:: 2018
Wydawca:: Polskie Towarzystwo Biochemiczne
Tematy:: oxicam derivatives
NSAIDs analogues
piroxicam
1,2- benzothiazine derivatives synthesis
model lipid bilayers
differential scanning calorimetry (DSC)
fluorescence spectroscopy
Opis:: The purpose of the present work was to assess the ability of five new oxicam analogues to interact with the lipid bilayers. To characterize the interaction of newly synthesized NSAIDs (non-steroidal anti-inflammatory drugs) analogues with DPPC lipid bilayers the two following techniques were applied - differential scanning calorimetry (DSC) and fluorescence spectroscopy. The results obtained by these experimental approaches show that new oxicams analogues interact with the lipid model membranes under consideration. As demonstrated both in calorimetric and spectroscopic studies, the greatest influence on the thermotropic properties of the lipid membrane and on the quenching of fluorescence of Laurdan and Prodan was exerted by a derivative named PR47 containing in its structure a two-carbon aliphatic linker with a carbonyl group, as well as bromine and trifluoromethyl substituents.
Źródło:: Acta Biochimica Polonica; 2018, 65, 2; 185-191
0001-527X
Pojawia się w:: Acta Biochimica Polonica
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 12.

Tytuł:: Zjawisko generowania fal harmonicznych oraz jego wykorzystanie praktyczne ze szczególnym uwzględnieniem współczesnej ultrasonografii
The phenomenon of generation of harmonic waves and its practical use with particular reference to modern ultrasonography
Autorzy:: Jeka, S.
Sokólska, E.
Dura, M.
Żuchowski, P.
Powiązania:: https://bibliotekanauki.pl/articles/261323.pdf
Data publikacji:: 2011
Wydawca:: Politechnika Wrocławska. Wydział Podstawowych Problemów Techniki. Katedra Inżynierii Biomedycznej
Tematy:: ultrasonografia
generacja drugiej harmonicznej
obrazowanie harmoniczne
spektroskopia fluorescencyjna
reumatoidalne zapalenie stawów
ultrasonography
second harmonic generation
tissue harmonic imaging
fluorescence spectroscopy
rheumatoid arthritis
Opis:: Od wielu lat z postępem w dziedzinie fizyki związany jest postęp w naukach przyrodniczych. Jednym ze zjawisk, które odgrywa coraz większą rolę w naukach przyrodniczych, jest zjawisko generacji drugiej harmonicznej w ośrodkach anizotropowych. Możliwość uzyskania fali o podwojonej częstotliwości w stosunku do fali podstawowej pozwoliło na prowadzenie badań, wcześniej trudnych bądź niemożliwych do przeprowadzenia. Dzięki wyższej jakości obrazu badania ultrasonograficzne stały się bardziej czułe i są powszechnie wykorzystywane, m.in. w kardiologii, radiologii, chirurgii, reumatologii czy diagnostyce onkologicznej. Ultrasonografia staje się niezwykle cenioną metodą obrazowania obok rezonansu magnetycznego czy tomografii komputerowej. Ze względu na jej dostępność wiązane są z nią duże nadzieje na przyszłość.
The progress in physics results in life sciences advancement. One of the phenomena, which plays more and more important role in life sciences, is the second harmonic generation in anisotropic materials. The possibility of achieving the wave, characterized by double frequency – with relation to the initial wave, allowed to conduct examinations, which were previously very difficult or impossible to perform. Thanks to higher quality of image, ultrasound examination has become more sensitive and is widely used, even in cardiology, radiology, surgery, rheumatology and oncology diagnostics. Ultrasonography with the use of tissue harmonic imaging is very valued method, so as magnetic resonance imaging or CT scan and due to its availability, high expectations are associated with it for the future.
Źródło:: Acta Bio-Optica et Informatica Medica. Inżynieria Biomedyczna; 2011, 17, 2; 140-143
1234-5563
Pojawia się w:: Acta Bio-Optica et Informatica Medica. Inżynieria Biomedyczna
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 13.

Tytuł:: Analiza struktury substancji humusowych gleb po wprowadzeniu węgla brunatnego na podstawie widm fluorescencyjnych
Analysis of humic substances structure in soils after brown coal application with use of 3-D fluorescence spectroscopy
Autorzy:: Kwiatkowska-Malina, J.
Powiązania:: https://bibliotekanauki.pl/articles/296915.pdf
Data publikacji:: 2011
Wydawca:: Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
Tematy:: materia organiczna z węgla brunatnego
substancje humusowe gleb
struktura kwasów huminowych
spektroskopia fluorescencyjna
organic matter originated from brown coal
humic substances of soil
structure of humic acids
fluorescence spectroscopy
Opis:: Badania dotyczyły analizy właściwości substancji humusowych (SH) oraz kształtowania struktury kwasów huminowych (KH) gleb po wprowadzeniu preparatu wytworzonego na bazie (85%) odpadowego węgla brunatnego. Do badań wykorzystano materiał glebowy z wieloletnich statycznych doświadczeń polowych i mikropoletkowych, a jako źródło materii organicznej Rekulter preparat wyprodukowany na bazie węgla brunatnego odpadowego i węgla brunatnego typu ziemistego z Zagłębia Konińskiego (KWB Konin). Niższe wartości intensywności fluorescencji na widmach 3-D EEM dla KH z gleby rdzawej (piaszczystej) wskazują na większy wpływ materii organicznej z węgla brunatnego na gleby bardzo lekkie piaszczyste w porównaniu do gleb cięższych (brunatna kwaśna, płowa). Wyniki ponad 20-letnich doświadczeń polowych na glebie rdzawej potwierdziły korzystne, długotrwałe oddziaływanie węgla brunatnego na właściwości gleby oraz na stan materii organicznej z tego źródła.
Soil is non-renewable and a very complex natural resource which performs many vital functions: food (99%) and other biomass production, storage, filtration and transformation of many substances including water, carbon, nitrogen. Soil as a top layer of the earth's crust is the first receiver of anthropogenic contaminants, and may or may not serve as a natural barrier to protect groundwater against contamination from the surface. One of the most important indicators of soil quality is soil organic matter (SOM), which is an important building block for the soil structure, formation of stable aggregates, and is able to improve the infiltration rates and the storage capacity of water. SOM presents a major pool carbon in the biosphere and can act both as a source and sink for carbon dioxide and other greenhouse gases. Agricultural intensification and cultivation in general results in a serious decrease in SOM as compared to that in the natural vegetation. Presently, the protection of SOM is one of the main tasks in EU, because SOM in addition to its soil fertilizing function can act in the elimination of the soil contamination and carbon sequestration. In this context, humic substances (especially humic and fulvic acids) and cohesive fractions (clay, silt, silt clay, etc.) present in soil are favourable components. It is because of their high sorption capacity with respect to many contaminants, including heavy metals, which may results in their immobilisation and, consequently protect groundwater against contamination. Antropogenically transformed soils often do not contain humic substances (HS), thus their role as a natural barrier is decreased. Therefore, re-generation of HS through humification of organic matter from diverse sources added to soils, may be the way to re-built the protective character of soil barrier, and consequently to reduce environmental and/or health risks at areas under anthropopression. Transformation processes of brown coal applied to soil were described to evaluate the use of this material as an effective source of organic matter and HS generation in degraded soils. The goal of this study was to discuss fine brown coal derived preparation as effective sources of organic matter (and humic substances) especially in soils that are anthropogenically transformed. The research concerned the analysis of properties of HS as well as formations of humic acids (HAs) in soils after addition brown coal. Soil materials used in the research was collected from the long term field experiments and microplots, as the source of organic matter the Rekulter that is based (85%) on brown coal (soft smudge type) obtained from the Konin Basin deposits preparation was used. For qualitative characteristic of SOM, particularly, in HAs, modern analytical technique such as fluorescence intensity (FI) for 3-D EEM spectra was used. The lowest fluorescence intensity (FI) for 3-D EEM spectra were observed in the case of HAs extracted from rusty soil. The 20-years research results carried out on rusty soil (sandy) confirmed long-term effect of brown coal on soil properties as well as on organic matter that originated from this source.
Źródło:: Inżynieria i Ochrona Środowiska; 2011, 14, 3; 197-208
1505-3695
2391-7253
Pojawia się w:: Inżynieria i Ochrona Środowiska
Dostawca treści:: Biblioteka Nauki

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Tytuł:: Metody charakterystyki naturalnych organicznych składników wód ujmowanych z przeznaczeniem do spożycia przez ludzi
Methods for natural organic matter characterization in water taken and treated for human consumption
Autorzy:: Machi, J.
Mołczan, M.
Powiązania:: https://bibliotekanauki.pl/articles/237105.pdf
Data publikacji:: 2016
Wydawca:: Polskie Zrzeszenie Inżynierów i Techników Sanitarnych
Tematy:: oczyszczanie wody
absorbancja w nadfiolecie
absorbancja właściwa w nadfiolecie
spektroskopia fluorescencyjna
magnetyczny rezonans jądrowy
chromatografia cieczowa
chromatografia wykluczenia
frakcjonowanie jonowymienne
frakcjonowanie membranowe
water treatment
UV absorbance
specific UV absorbance (SUVA)
fluorescence spectroscopy
nuclear magnetic resonance
liquid chromatography
size exclusion chromatography
resin fractionation
membrane fractionation
Opis:: Wiedza o zawartości sumy naturalnych substancji organicznych nie jest obecnie wystarczająca zarówno przy planowaniu, jak i eksploatacji instalacji do oczyszczania wody. Pogłębiona charakterystyka zawartych w ujmowanych wodach naturalnych związków organicznych pozwala na lepsze zrozumienie ich przemian w procesach oczyszczania wody, a także odgrywa bardzo ważną rolę podczas optymalizacji pracy poszczególnych etapów układu technologicznego. Powszechnie stosowanym wskaźnikiem do analizy związków organicznych w wodzie jest absorbancja w nadfiolecie, która umożliwia zarówno ocenę jakościową, jak i ilościową tych związków. Absorbancja właściwa w UV (SUVA), jako odniesienie wartości absorbancji w 254 nm do zawartości w wodzie rozpuszczonego węgla organicznego, umożliwia natomiast kontrolę procesów oczyszczania wody, zwłaszcza w zakresie dawkowania koagulantów oraz utleniaczy. Inne metody charakterystyki naturalnych substancji organicznych stanowią domenę prac badawczych i nie są szerzej wykorzystywane w praktyce funkcjonowania przedsiębiorstw wodociągowych. Wśród nich na uwagę zasługują techniki spektroskopii fluorescencyjnej, które pozwalają na monitorowanie jakości wody w czasie rzeczywistym i cechują się zwiększoną selektywnością oraz czułością w zestawieniu z absorbancją w nadfiolecie. Analiza fluorescencyjna, umożliwiająca identyfikację frakcji biodegradowalnej związków organicznych, pozwala na wybór właściwych metod ich usuwania. Bardzo duże możliwości analityczne zapewnia chromatografia, zwłaszcza w połączeniu z szeroką gamą dostępnych detektorów. Umożliwia ona badanie takich cech substancji organicznych, jak masa cząsteczkowa, polarność, aromatyczność czy podatność na tworzenie ubocznych produktów dezynfekcji wody. Daje to szerokie możliwości interpretacyjne w odniesieniu do optymalizacji pracy układu technologicznego oczyszczania wody. Bardzo pomocne do charakteryzowania składu wody pod względem obecnych w niej związków organicznych są także metody frakcjonowania z wykorzystaniem membran lub żywic selektywnych. Separacja cząsteczek substancji organicznych według takich cech, jak wielkość, hydrofilowość czy kwasowość, pozwala na otrzymanie wyselekcjonowanych próbek, które mogą być poddane dalszym badaniom.
Today’s knowledge on total Natural Organic Matter (NOM) content proves not sufficient both at planning and operation of water treatment installations. Detailed characteristics of NOM present in raw and treated water enables better understanding of its changes during water treatment processes as well as substantially contributes towards operation optimization of subsequent stages of a technological set-up. UV absorbance, a common indicator used for NOM analysis in water, allows for both its qualitative and quantitative assessment. Specific UV absorbance (SUVA), being the UV absorbance of a water sample at 254 nm normalized for dissolved organic carbon (DOC), allows monitoring of water treatment processes, especially in terms of coagulant and oxidizing agent dosing. Other NOM characterization methods are a domain for research and are not widely employed in daily practice of water supply corporations. Among those techniques, fluorescence spectroscopy methods are worth noticing as they enable water quality monitoring in real time and are characterized by higher selectivity and sensitivity compared to UV absorbance. Fluorescence analysis that allows identification of biodegradable organic fractions, enables selection of adequate methods of their removal. Chromatography offers a number of analytical capabilities, especially when combined with a wide range of available detectors. It allows examination of NOM characteristics such as molecular weight, polarity, aromaticity or susceptibility to water disinfection by-product formation. Thus multiple possibilities of interpretation arise in regard to optimization of technological system operation in water treatment. In terms of NOM presence, fractionation methods employing membranes and selective resins are particularly helpful in water composition characterization. NOM particle separation according to its size, hydrophilicity, acidity and others enables monitoring its removal susceptibility in particular treatment processes and predicting the technological effects based on NOM characteristics.
Źródło:: Ochrona Środowiska; 2016, 38, 4; 25-32
1230-6169
Pojawia się w:: Ochrona Środowiska
Dostawca treści:: Biblioteka Nauki

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Tytuł:: Aminokwasy, glikany, peptydy i białka w ścieżkach diagnostycznych i terapeutycznych chorób cywilizacyjnych XXI wieku : projektowanie i charakterystyka fizykochemiczna oraz strukturalna
Amino acids, glycans, peptides and proteins in the diagnostic and therapeutic pathways of the 21st century civilization diseases : design, physicochemical and structural characterisation
Autorzy:: Bylińska, Irena
Dzierżyńska, Maria
Giżyńska, Małgorzata
Guzow, Katarzyna
Jankowska, Elżbieta
Jurczak, Przemysław
Kaczyński, Zbigniew
Karska, Natalia
Kowalczyk, Agnieszka
Kuncewicz, Katarzyna
Orlikowska, Marta
Sawicka, Justyna
Spodzieja, Marta
Szpakowska, Nikola
Szymańska, Aneta
Wieczerzak, Ewa
Witkowska, Julia
Rodziewicz-Motowidło, Sylwia
Powiązania:: https://bibliotekanauki.pl/articles/2200549.pdf
Data publikacji:: 2022
Wydawca:: Polskie Towarzystwo Chemiczne
Tematy:: fluorophores
fluorescence spectroscopy
antimicrobial activity
anticancer activity
Cystapep
Stahylococcus aureus
antimicrobial compounds
amyloidogenic protein
mutagenesis
fibrilization
proteasome
aging
neurodegeneration
self-assembling peptides
tissue engineering
biomaterials
immune checkpoints
peptide inhibitors
immunotherapy
ligands of TAP protein
viral diseases
NMR structure of the UL49.5 protein
glycans
glycoconjugates
fluorofory
spektroskopia fluorescencyjna
aktywność przeciwdrobnoustrojowa
aktywność antynowotworowa
Staphylococcus aureus
związki przeciwbakteryjne
białko amyloidogenne
mutageneza
fibrylizacja
proteasom
procesy starzeniowe
neurodegeneracja
peptydy samoorganizujące
inżynieria tkankowa
biomateriały
punkty kontrolne układu immunologicznego
inhibitory peptydowe
immunoterapia
ligandy białka TAP
choroby wirusowe,
struktura NMR białka UL49.5
glikany
glikokoniugaty
Opis:: The civilization diseases of the 21st century are non-infectious disorders, affecting a large part of modern society. They are associated with the significant development of industry and technology, and hence with environmental pollution and an unhealthy lifestyle. These factors have led to the development of many civilization diseases, which currently include: cardiovascular diseases, respiratory diseases, diabetes, obesity, malignant tumors, gastrointestinal diseases, mental disorders and allergic diseases. The development of technologies, including modern therapies and new drugs, resulted in increase in life expectancy. This creates a global problem of an aging population with an increasing number of diseases of the old age, i.e. dementias. In addition, sedentary lifestyles and changing diets are the reasons why more and more people develop metabolic diseases, as well as neurological and cognitive disorders characterized by progressive damage to nerve cells and dementia. Currently, problem on a global scale is also the growing resistance to existing antimicrobial drugs. Therefore, the scientists face many challenges related to searching for the causes of these diseases, their diagnosis and treatment. Scientific research conducted at the Department of Biomedical Chemistry at the Faculty of Chemistry of the University of Gdańsk is part of this research trend. In this publication, we discuss various research topics with the long-term aim of solving the problems associated with the diseases mentioned above. The following chapters are dedicated to (i) looking for new effective fluorophores with diagnostic and anti-cancer activity; (ii) designing of new compounds with antibacterial and antiviral activity and their synthesis; (iii) investigating the mechanisms of amyloid deposit formation by human cystatin C and possibilities of inhibition of this process; (iv) designing and studies of compounds activating the proteasome with the potential to suppress the development of neurodegenerative diseases; (v) designing peptide fibrils and hydrogels as drug carriers; (vi) searching for peptide inhibitors of immune checkpoint as potential drugs for immunotherapy; (vii) studying the mechanism of action of selected herpesviruses by determining the structure of viral proteins and (viii) studying the composition of natural glycans and glycoconjugates in order to better understand the mechanisms of interaction of bacteria with the environment or with the host.
Źródło:: Wiadomości Chemiczne; 2022, 76, 5-6; 393--431
0043-5104
2300-0295
Pojawia się w:: Wiadomości Chemiczne
Dostawca treści:: Biblioteka Nauki

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