- Tytuł:
- Hazard of Runaway of Nitration Processes in Nitrocompounds Production
- Autorzy:
-
Kozak, G. D.
Raikova, V. M. - Powiązania:
- https://bibliotekanauki.pl/articles/357950.pdf
- Data publikacji:
- 2010
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
runaway
nitration
oxidation
detonation
failure diameter
sulfuric acid - Opis:
- Hazard of runaway of nitration processes in nitrocompounds production was investigated. Temperature rise in DNT nitration mixes under near adiabatic conditions was measured, and derivative dT/dζ was computed. Heat evolution rate caused by nitration (primary reaction) and oxidation (secondary reaction) were examined by means of elaborated mathematical model. Limiting values of T and dT/dζ for safe process were determined. The second part of investigation concerns detonability of solutions of nitrocompound in sulfuric acid. The detonation failure diameter df and detonation velocity D of solutions of trinitrotoluene, dinitrotoluene, and trinitrobenzene in sulfuric acid and oleum have been measured in the wide range of concentrations at T = 90C. It was shown that the detonability of the nitrocompounds depends signifcantly on the sulfuric acid content. The minimum value of df for the mixture TNT/oleum is about 2 mm, i.e., 30 times less, than that for melted TNT, and practically equals to df of nitroglycerine.
- Źródło:
-
Central European Journal of Energetic Materials; 2010, 7, 1; 21-32
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki
Artykuł