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Wyświetlanie 1-2 z 2
Tytuł:
Thermodynamic properties of dilute Co-Fe solid solutions studied by 57Fe Mössbauer spectroscopy
Autorzy:
Konieczny, R.
Idczak, R.
Powiązania:
https://bibliotekanauki.pl/articles/146524.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectroscopy
binding energy
short-range order
enthalpy of solution
enthalpy of mixing
binary alloys
Opis:
The Co1–xFex alloys where x ranges from 0.01 to 0.06 were measured at room temperature using transmission Mössbauer spectroscopy (TMS). The analysis of the obtained data allowed the determination of the short-range order (SRO), the binding energy Eb between two iron atoms in the studied materials using the extended Hrynkiewicz-Królas idea and the enthalpy of solution HCo-Fe of Fe in Co. The results showed that the Fe atoms dissolved in a Co matrix interact repulsively and the estimated value of HCo-Fe = –0.166(33) eV/atom. Finally, values of the enthalpy of solution were used to predict the enthalpy of mixing for the Co-Fe system. These findings were compared with corresponding data given in the literature, which were derived from calorimetric experiments and from the cellular atomic model of alloys described by Miedema.
Źródło:
Nukleonika; 2017, 62, 2; 109-115
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A study of thermodynamic properties of dilute Fe-Au alloys by the ⁵⁷Fe Mössbauer spectroscopy
Autorzy:
Konieczny, R.
Idczak, R.
Chojcan, J.
Powiązania:
https://bibliotekanauki.pl/articles/1054974.pdf
Data publikacji:
2017-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
Mössbauer spectroscopy
hyperfine parameters
binding energy
short-range order
enthalpy of solution
enthalpy of mixing
binary alloys
Opis:
The room temperature Mössbauer spectra of ⁵⁷Fe were measured for Fe_{1-x}Au_x with the gold concentration ranging from 1 at.% till 4.8 at.%. They were analysed in terms of hyperfine parameters of their components related to unlike surroundings of the iron probes, determined by different numbers of gold atoms existing in the neighbourhood of iron atoms. Basing on the intensities of the spectrum components we determined binding energy E_b between two gold atoms in the studied materials. The latter was done for properly annealed samples using the extended Hrynkiewicz-Królas idea. It was found that the binding energy is positive or Au atoms interact repulsively. The extrapolated value of E_b for x =0 was used for computation of an enthalpy of solution of Au in Fe. Finally the obtained value of the enthalpy was used to predict the mixing enthalpy for the Fe-Au solid solutions. The results were compared with both the corresponding values resulting from the cellular atomic model of alloys by Miedema and those derived from experimental calorimetric data given in the literature.
Źródło:
Acta Physica Polonica A; 2017, 131, 2; 255-258
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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