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Wyszukujesz frazę "heat of detonation" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
Detonation Performance of Four Groups of Aluminized Explosives
Autorzy:
Xiang, D.-L.
Rong, J.-L.
He, X.
Powiązania:
https://bibliotekanauki.pl/articles/358148.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
aluminized explosive
detonation pressure
detonation velocity
heat of detonation
KHT code
Opis:
The detonation performances of TNT-, RDX-, HMX-, and RDX/AP-based aluminized explosives were examined through detonation experiments. The detonation pressure, velocity, and heat of detonation of the four groups of aluminized explosives were measured. Reliability verification was conducted for the experimental results and for those calculated with an empirical formula and the KHT code. The test results on detonation pressures and velocities were in good agreement with the predicted values when aluminum (Al) particles were considered inert. The experimental heat of detonation values exhibited good consistency with the predicted values when a certain proportion of Al particles was active. Ammonium perchlorate (AP) can effectively reduce the detonation pressure and improve the heat of detonation for the RDX/AP-based aluminized explosive. A comparison of the current test results and literature data shows that errors may exist in early test data. The test data presented in this study allow for an improved understanding of the detonation performance of the four groups of aluminized explosives.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 903-915
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calculation of Thermochemical and Explosive Characteristics of Furoxanes
Autorzy:
Zhukov, I.
Kozak, G. D.
Powiązania:
https://bibliotekanauki.pl/articles/358541.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
furoxanes
benzofuroxanes
high-power energetic materials
heat of detonation
detonation velocity
detonation pressure
Opis:
Search of high-power energetic materials is one primary line of development of chemical physics of combustion and explosion. Yield of such materials is usually very small, and its cost is very high. Calculation of unknown characteristics and properties is the only way out from this situation. There are different methods today that allow calculating unknown detonation performance and some of physicochemical properties. Examination of calculated detonation performance of furoxanes and benzofuroxanes compounds that are not enough investigated is presented in this work. These compounds are new high-power energetic materials. Influence of error in enthalpy of formation of these compounds on their detonation performance is also examined in this work. Furoxanes plays particular part among energetic materials. They are convenient blocks of molecules of high-power energetic materials. Joining of explosiphorus clusters of atoms are lead to obtaining of number of high-performance compounds. It is caused by flatten structure of furoxane ring, that lead to high density of compounds and are characterized by high and positive value of enthalpy of formation. Detonation performance of furoxanes was not study practically. That is why 10 furoxanes have been chosen as object of study (see Nomenclature). 7 of 10 studied furoxanes have anomalous elemental composition, because they are hydrogenfree. In order to evaluate possible error in computational detonation performance, explosive characteristics of 6 hydrogen-free energetic materials with known experimental data have been calculated.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 3-4; 45-54
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nitro Groups vs. N-Oxide Linkages: Effects Upon Some Key Determinants of Detonation Performance
Autorzy:
Politzer, P.
Murray, J. S.
Powiązania:
https://bibliotekanauki.pl/articles/358223.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
C,H,N,O explosives
detonation velocity
detonation pressure
N-oxides
polyazines
polyazoles
detonation heat release
crystal density
heats of formation
gaseous detonation products
Opis:
Increasing the nitrogen/carbon ratios in the molecular frameworks of C,H,N,O explosives has attracted considerable attention because it tends to result in more positive heats of formation and often greater densities. In conjunction with this, there has been a growing interest in N-oxide linkages, N+ → O−, as another source of oxygen in these compounds, in addition to or even possibly replacing NO2 groups. In this study, for a series of polyazines and polyazoles, we have compared the effects of introducing a single N-oxide linkage or NO2 group upon key properties that affect detonation velocity and detonation pressure. We found that: (1) The heats of formation per gram of compound, which is what is relevant for this purpose, are almost always higher for the N-oxides. (2) The nitro derivatives have greater densities and detonation heat releases. In relation to the latter, it must be kept in mind that increasing detonation heat release tends to be accompanied by increasing sensitivity. (3) The N-oxides produce more moles of gaseous detonation products per gram of compound.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 3-25
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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